1,8-Bis(4-iodophenyl)naphthalene | 288297-94-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,8-Bis(4-iodophenyl)naphthalene
• CAS: 288297-94-9
• 化学式: C₂₂H₁₄I₂
• 分子量: 532.162
• InChiKey: USWDQGQGCOAJRA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,8-Bis(4-iodophenyl)naphthalene 在 正丁基锂 、 三丁基氯化锡 、 copper(II) nitrate 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 生成 1,8-二苯基萘 、 1-Phenyl-8-[4-[4-(8-phenylnaphthalen-1-yl)phenyl]phenyl]naphthalene 、 Nonacyclo[30.2.2.22,5.215,18.219,22.16,10.123,27.014,42.031,37]tetratetraconta-1(34),2(44),3,5(43),6,8,10(42),11,13,15(41),16,18(40),19,21,23,25,27(37),28,30,32,35,38-docosaene
  参考文献：
  名称：

  A Cyclic Oligophenylene Containing Two 1,8-Naphthalene Units Bridged by Two Face-to-Face Biphenyl Linkages Exhibiting Unusual Strain and π−π Interaction

  摘要：

  GRAPHICS1,8-[1,8-Naphthalenediylbis(4',4-biphenyldiyl)]naphthalene, a very stable strained cyclophane, has been synthesized in moderate yield using the copper-catalyzed coupling of 1,8-bis(4-(tributylstannyl)phenyl)naphthalene The X-ray analysis of the titled compound discloses bent p,p'-biphenylylene chains with splayed naphthalene rings, and the p,p'-biphenylylene chains located face to face indicate a fairly strong pi-pi interaction.

  DOI：

  10.1021/ol0001012
• 作为产物：
  描述：

  Trimethyl-[4-[8-(4-trimethylsilylphenyl)naphthalen-1-yl]phenyl]silane 在 一氯化碘 作用下， 以 四氯化碳 为溶剂， 以74%的产率得到1,8-Bis(4-iodophenyl)naphthalene
  参考文献：
  名称：

  A Cyclic Oligophenylene Containing Two 1,8-Naphthalene Units Bridged by Two Face-to-Face Biphenyl Linkages Exhibiting Unusual Strain and π−π Interaction

  摘要：

  GRAPHICS1,8-[1,8-Naphthalenediylbis(4',4-biphenyldiyl)]naphthalene, a very stable strained cyclophane, has been synthesized in moderate yield using the copper-catalyzed coupling of 1,8-bis(4-(tributylstannyl)phenyl)naphthalene The X-ray analysis of the titled compound discloses bent p,p'-biphenylylene chains with splayed naphthalene rings, and the p,p'-biphenylylene chains located face to face indicate a fairly strong pi-pi interaction.

  DOI：

  10.1021/ol0001012