chlorotris(triphenylarsine)Cu(I) | 31240-78-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chlorotris(triphenylarsine)Cu(I)
• 英文别名: chlorotris(triphenylarsine)copper(I)；chlorocopper;triphenylarsane
• CAS: 31240-78-5
• 化学式: C₅₄H₄₅As₃ClCu
• 分子量: 1017.72
• InChiKey: SLCYUSGDRYXXDD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chlorotris(triphenylarsine)Cu(I) 、 N-(Ethoxycarbonyl)-4-chlorobenzenethiocarboxamide 以 苯 为溶剂， 以55%的产率得到[CuCl(N-carboethoxy-4-chlorobenzene thioamide)(AsPh3)2]
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF COPPER(I) COMPLEXES OF N-CARBOETHOXY-4-CHLOROBENZENE AND N-CARBOETHOXY-4-BROMOBENZENE THIOAMIDES (Hcct AND Hcbt)

  摘要：

  Reactions of [Cu(EPh3)(3)X] with the title ligands yield [Cu(EPh3)(2)(LH)X] (LH = Hcct and Hcbt). Twelve complexes have been prepared and characterized on the basis of analytical, IR, electronic and NMR spectral and magnetic measurements. These complexes have a tetrahedral structure with the aromatic ligand bonded to copper(l) through sulfur.

  DOI：

  10.1081/sim-120016465
• 作为产物：
  描述：

  三苯胂 、 copper(l) chloride 以 氯仿 为溶剂， 生成 chlorotris(triphenylarsine)Cu(I)
  参考文献：
  名称：

  Synthesis and study of mixed ligand monomer Cu(I) compounds with CuAs bonds. Crystal and molecular structure of bis(triphenylarsine)-(2-thioxohexamethyleneimine)copper(I) bromide

  摘要：

  A new series of mixed ligand coordination compounds with Cu-As bonds is synthesized by the reaction of Cu(AsPh3)3X, where X = Cl, Br, or [Cu(AsPh3)I]4 with 2-thioxohexamethyleneimine (omega-thiocaprolactam, tclH) in acetone or by the addition of triphenylarsine to Cu(tclH)2X in methanol/chloroform. The products of both reactions are formulated as Cu(tclH)(AsPh3)2X, on the basis of their elemental analyses, IR, H-1 NMR and UV-Vis spectral data. The crystal structure of the bromo compound is reported and discussed with respect to that of Cu(tclH)2(AsPh3)Br. The compound crystallizes in the monoclinic space group C2/c, with a = 41.981(8), b = 9.961(2), c = 19.087(2), angstrom, beta = 101.09(1)-degrees, 8 discrete molecules being present in the unit cell. The copper environment is a distorted tetrahedron, with two inequal Cu-As bonds, which are 2.411(2) and 2.372(2) angstrom, respectively. The Cu-Br and Cu-S bond lengths are equal to 2.456(3) and 2.313(4) angstrom, respectively, while the bond angles around copper vary from 104.4(0)-degrees for As1-Cu-S to 116.1(1)-degrees for As1-Cu-As2.

  DOI：

  10.1016/s0020-1693(00)80921-4

文献信息

• Lewis-Base Adducts of Group 11 Metal(I) Compounds. LXV Synthesis, Spectroscopy and Structural Systematics of Some 1 : 3 Adducts of Copper(I) Compounds with Triphenylarsine, [(Ph3As)3CuX], X = Cl, Br, I, ONO2
  作者：Robert D. Hart、Graham A. Bowmaker、Eban N. de Silva、Brian W. Skelton、Allan H. White

  DOI：10.1071/c96032

  日期：——

  Crystallization of some copper(I) salts, CuX, with triphenylarsine in 1 : 3 stoichiometry from acetonitrile has yielded an array of adducts, [(Ph3As)3CuX], characterized by room-temperature single crystal X-ray structure determinations. [(Ph3As)3CuCl] (1) has been characterized in two unsolvated phases, α and β, the second form previously recorded as monoclinic, P21/n, Z = 8. The ‘α’ phase, like the bromide (2) and iodide (3), adopts the trigonal P3 array, widespread among many [(Ph3E)3MX] adducts with a ≈ 19, c ≈ 11 Å; conventional R on F was 0·037, 0·041, 0·056 for No 3458, 3259, 3434 independent ‘observed’ (I > 3σ(I)) reflections for these three adducts respectively. A further form, γ, is a toluene hemisolvate, monoclinic, P21/c, a 21·490(5), b 10·218(7), c 24·901(6) Å, β 117·53(2)°, Z = 4, R 0·057 for No 7207. The nitrate (4), obtained as a monosolvate from methanol, is monoclinic, P21/n, a 15 ·115(9), b 23·201(9), c 14·170(14) Å, β 92·56(7)°, Z = 4, R 0·049 for No 5476. In all compounds, the copper atom is four-coordinate, E3CuX, the nitrate in (4) being -ONO2 unidentate. The CuX bond lengthsr(CuX) in [(Ph3E)3CuX] (X = Cl, Br, I) show a decrease from the Ph3P to the corre3sponding Ph3As compound, and this is consistent with the observed increase in the v(CuX) wavenumbers in the far-infrared spectra. These trends are both consistent with an increase in the CuX bond strength from the Ph3P to the Ph3As complexes, and possible reasons for this are discussed.

  一些铜（I）盐 CuX 与三苯基胂以 1 : 3 的配比从乙腈中结晶出一系列加合物 从乙腈中以 1 : 3 的比例结晶出一系列加合物、 (Ph3As)3CuX]、 室温单晶 X 射线结构测定。 的特征。 (Ph3As)3CuCl]（1）在两种未溶解状态下进行了表征。 α和β两种未溶解相的特征，第二种未溶解相以前记录为单斜晶体。 第二种形态以前记录为单斜、 P21/n、 Z=8。 溴化物 (2) 和碘化物 (3)一样，采用三棱 P3 阵列，在许多 (Ph3E)3MX]加合物，其 a ≈ 19，c ≈ 11 Å； F 上的常规 R 为 0-037、0-041、0-056、 3259、3434 个独立的 "观察到的"（I > 3σ(I)）反射。 分别为这三种加合物。另一种形式 γ 是一种甲苯 半溶胶，单斜、 P21/c、 a 21-490(5)，b 10-218(7), c 24-901(6) Å, β 117-53(2)°, Z = 4, R 0-057 代表 No 7207。硝酸盐 硝酸盐 (4) 从甲醇中以单溶剂形式获得，呈单斜型、 P21/n、 a 15 -115(9), b 23-201(9), c 14-170(14) Å, β 92-56(7)°, Z = 4, R 0-049 表示 No 5476。在所有 在所有化合物中，铜原子都是四配位的，即 E3CuX、 (4)中的硝酸根为 -ONO2 非同位。CuX 键 在 [(Ph3E)3CuX]（X = Cl、Br、I）中的 CuX 键长度r(CuX)从 Ph3P 下降到 相应的 Ph3As 化合物中的减少，这与观察到的 与观测到的远红外光谱中 v(CuX) 波数的增加相一致。 与远红外光谱中观察到的 v(CuX) 波数的增加相一致。这些趋势都与 CuX 键强度从 Ph3P 到 Ph3As 复合物的 CuX 键强度增加，并讨论了可能的原因。 讨论。
• Substitution reactions of [CuI(AsPh3)3X] (X = Cl, Br or I) with 3-phenyl-2-thioxoimidazolidin-4-one (ptiH) and 5-mercapto-1-phenyl-1,2,3-4-tetrazole (mptH)
  作者：Ramsharan Singh、S.K. Dikshit

  DOI：10.1016/s0277-5387(00)81756-8

  日期：1993.4

  Reactions of [Cu(AsPh3)3X] with the title ligands yield [Cu(AsPh3)2(LH)X][GRAPHICS]These complexes have been characterized on the basis of analytical, IR, electronic (UV-vis), H-1 NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment around copper(I), and the ligands (LH) bind through the thione sulphur atom to copper(I).