4-(tris(4-iodophenyl)methyl)phenol | 1186383-50-5

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 4-(tris(4-iodophenyl)methyl)phenol
• 英文别名: 4-Hydroxyphenyl[tris(4-iodophenyl)]methane；4-[tris(4-iodophenyl)methyl]phenol
• CAS: 1186383-50-5
• 化学式: C₂₅H₁₇I₃O
• 分子量: 714.123
• InChiKey: GOVXCBHMUMWZJU-UHFFFAOYSA-N

物化性质

• 沸点：
  623.3±55.0 °C(Predicted)
• 密度：
  1.980±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-(tris(4-iodophenyl)methyl)phenol 在 iron(III) oxide 、 copper(l) iodide 、 氨 、 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 192.0h， 以21%的产率得到4-(tris(4-aminophenyl)methyl)phenol
  参考文献：
  名称：

  多孔四苯甲烷树枝状聚合物的发散合成

  摘要：

  基于四苯甲烷乙炔的形状持久树状聚合物是一类具有引人入胜的3D结构的新型纳米物体。我们报告了基于Sonogashira Pd催化的末端炔烃与芳基碘化物的偶联的有效合成策略。作为重复单元，我们制备了带有末端炔基和三个三嗪部分的四苯基甲烷衍生物。该结构单元与四联体（p在三氮烯活化后，生成碘代苯基）甲烷得到十二烷基端基的第一代树枝状大分子，该树枝状大分子通过另一个Sonogashira偶联转变为具有持久球状形状和明确空腔的甲氧基封端的第二代树枝状大分子。这项工作还揭示了三氮烯化学的新方面，即通过将三氮烯与苯酚混合，空前有效地产生了偶氮化合物。

  DOI：

  10.1021/acs.joc.7b02302
• 作为产物：
  描述：

  碱性红 9 在 硫酸 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 7.0h， 生成 4-(tris(4-iodophenyl)methyl)phenol
  参考文献：
  名称：

  Deposition of Ordered Layers of Tetralactam Macrocycles and Ether Rotaxanes on Pyridine-Terminated Self-Assembled Monolayers on Gold

  摘要：

  The deposition of tetralactam macrocycles and the corresponding benzyl ether rotaxanes on gold substrates is investigated for the first time exploiting metallo-supramolecular chemistry. Two pyridine-terminated self-assembled monolayers (SAMs) are developed that are used as well-ordered template layers. The two SAMs differ with respect to the rigidity of the terminal pyridines as shown by angle-resolved near-edge X-ray absorption fine structure (NEXAFS) spectroscopy. The template layers are then used for the metal-mediated self-assembly of macrocylces and rotaxanes on solid supports. The SAM with the more rigid terminal pyridine shows a higher coverage with the macrocycles and is therefore preferable. Angle-resolved NEXAFS spectroscopy also shows the deposited supramolecules to be oriented preferentially upright. This order is only achieved for the macrocycles through the deposition on the more rigid SAM template, whereas rotaxanes form oriented layers on both SAMs. Time-of-flight secondary-ion mass spectrometry analysis was used to determine the deposition time required for the self-assembly process.

  DOI：

  10.1021/ja306212m

文献信息

• TETRAPHENYLMETHANE SKELETON-CONTAINING COMPOUND
  申请人：KUBO Youhei

  公开号：US20090227812A1

  公开（公告）日：2009-09-10

  A compound represented by the formula below is provided. (In the formula, X and Y denote a hydroxy group, an amino group, or a halogen atom, and X and Y are groups that are different from each other.)

  提供了以下式子所代表的化合物。（在式子中，X和Y代表羟基，氨基或卤原子，且X和Y是不同于彼此的基团。）
• Light-Harvesting in Multichromophoric Rotaxanes
  作者：Maria E. Gallina、Bilge Baytekin、Christoph Schalley、Paola Ceroni

  DOI：10.1002/chem.201102981

  日期：2012.1.27

  Two rotaxanes with benzyl ether axles and tetralactam wheels were synthesized through an anion template effect. They carry naphthalene chromophores attached to the stopper groups and a pyrene chromophore attached to the wheel. The difference between the two rotaxanes is represented by the connecting unit of the naphthyl chromophore to the rotaxane axle: a triazole or an alkynyl group. Both rotaxanes

  通过阴离子模板效应合成了两种带有苄基醚轴和四内酰胺轮的轮烷。它们带有连接在塞子基团上的萘发色团和连接在轮子上的a发色团。两种轮烷之间的差异由萘发色团与轮烷轴的连接单元表示：三唑或炔基。两种轮烷均具有出色的光收集性能：在两种情况下，激发萘发色团后，能量转移至pyr单元。这代表了属于机械互锁组件（即轮烷的轮轴和轮）的生色团之间的光收集功能的示例。
• Kinetically Controlled Porosity in a Robust Organic Cage Material
  作者：Antonio Avellaneda、Peter Valente、Alexandre Burgun、Jack D. Evans、Adrian W. Markwell-Heys、Damien Rankine、David J. Nielsen、Matthew R. Hill、Christopher J. Sumby、Christian J. Doonan

  DOI：10.1002/anie.201209922

  日期：2013.3.25

  Won by the hare: A new crystalline microporous solid was prepared that is composed of discrete organic cages made entirely from carbon–carbon bonds. The porosity of this material can be controlled by simple kinetic methods, which afford reproducible access to either a non‐porous or porous polymorph.

  被野兔赢取了：制备了一种新的晶体微孔固体，该固体由完全由碳-碳键制成的离散有机笼组成。可以通过简单的动力学方法控制这种材料的孔隙率，该方法可重现无孔或多孔多晶型物。
• Tetraphenylmethane skeleton-containing compound
  申请人：FUJIFILM Corporation

  公开号：US07799949B2

  公开（公告）日：2010-09-21

  A compound represented by the formula below is provided. (In the formula, X and Y denote a hydroxy group, an amino group, or a halogen atom, and X and Y are groups that are different from each other.)

  提供一个由以下公式表示的化合物。（在公式中，X和Y表示羟基，氨基或卤素原子，而且X和Y是不同于彼此的基团。）
• US7799949B2
  申请人：——

  公开号：US7799949B2

  公开（公告）日：2010-09-21