2,5,8-Tris-diphenylamino-tri-s-triazin | 106407-81-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5,8-Tris-diphenylamino-tri-s-triazin
• 英文别名: 2,5,8-tris(diphenylamino)-1,3,4,6,7,9,9b-heptaazaphenalene；hexa-N-phenyl-1,3,4,6,7,9,9b-heptaaza-phenalene-2,5,8-triamine；hexaphenylmelem；3-N,3-N,7-N,7-N,11-N,11-N-hexakis-phenyl-2,4,6,8,10,12,13-heptazatricyclo[7.3.1.05,13]trideca-1,3,5,7,9,11-hexaene-3,7,11-triamine
• CAS: 106407-81-2
• 化学式: C₄₂H₃₀N₁₀
• 分子量: 674.767
• InChiKey: AUZRURKFKKRBBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  52
• 可旋转键数：
  9
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.1
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,5,8-三氯-七氮杂非那烯 、 二苯胺 以 xylene 为溶剂， 反应 14.0h， 以69%的产率得到2,5,8-Tris-diphenylamino-tri-s-triazin
  参考文献：
  名称：

  [EN] HEPTAAZAPHENALENE DERIVATIVES AND USE THEREOF IN ORGANIC ELECTROLUMINESCENT DEVICE
  [FR] DÉRIVÉS D'HEPTAAZAPHÉNALÈNE ET LEUR UTILISATION DANS DES DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES

  摘要：

  本发明涉及一种有机电致发光器件，包括形成阳极和阴极的一对电极，以及排列在电极对之间的一个或多个有机化合物层，其中有机化合物层包括式（1）的七氮杂苯衍生物。本发明还涉及该化合物。

  公开号：

  WO2010132953A1

文献信息

• A series of aryl-/alkyl-substituted melems
  作者：Anke Schwarzer、Edwin Kroke

  DOI：10.1039/c0nj00989j

  日期：——

  Four different tri-s-triazines were synthesized bearing one, two or three substituents NEt2 and/or NPh2 by reaction of cyameluric chloride and the corresponding amines. All compounds were characterised comprehensively including single crystal structure analysis, NMR, FT-IR and elemental analysis.

  通过将氰脲酰氯与相应的胺反应，合成了含有一个、两个或三个取代基 NEt2 和/或 NPh2 的四种不同的三-s-三嗪。对所有化合物进行了全面的表征，包括单晶结构分析、核磁共振、傅立叶变换红外光谱和元素分析。
• LIGHT-EMITTING MATERIAL, AND ORGANIC LIGHT-EMITTING ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP2824159A1

  公开（公告）日：2015-01-14

  The compound represented by the following general formula is useful as a light-emitting material for an organic light-emitting device. Z1, Z2 and Z3 in the following general formula each independently represent a substituent.

  以下通式所代表的化合物可用作有机发光器件的发光材料。下式通式中的 Z1、Z2 和 Z3 各自独立地代表一个取代基。
• ORGANIC LIGHT-EMITTING ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP3171421A1

  公开（公告）日：2017-05-24

  An organic light-emitting device containing a host material, a delayed fluorescent material and a light-emitting material satisfying ES1(H)>ES1(F)>ES1(D) has a high light emission efficiency. ES1(H) represents a lowest excited singlet energy level of the host material, ES1(F) represents a lowest excited singlet energy level of the delayed fluorescent material, and ES1(D) represents a lowest excited singlet energy level of the light-emitting material.

  一种含有宿主材料、延迟荧光材料和发光材料的有机发光器件具有很高的光发射效率，该器件满足ES1(H)>ES1(F)>ES1(D)的要求。ES1(H)代表主材料的最低激发单线能级，ES1(F)代表延迟荧光材料的最低激发单线能级，ES1(D)代表发光材料的最低激发单线能级。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Kyushu University National University Corporation

  公开号：EP3706182A1

  公开（公告）日：2020-09-09

  An organic electroluminescent device having an anode (2), a cathode (7), and a light emitting layer (5) between the anode (2) and the cathode (7), in which the light emitting layer (5) contains a first organic compound, a second organic compound, and a third organic compound that satisfy the following expression (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light emitting material, is capable of enhancing the light emission efficiency. ES1(A), ES1(B) and ES1(C) represent a lowest singlet excitation energy level of the first, second and third organic compound, respectively. ES1A>ES1B>ES1C

  一种有机电致发光器件具有阳极（2）、阴极（7）和位于阳极（2）与阴极（7）之间的发光层（5），其中发光层（5）包含满足以下表达式（A）的第一有机化合物、第二有机化合物和第三有机化合物，第二有机化合物是延迟荧光材料，第三有机化合物是发光材料，该器件能够提高光发射效率。ES1(A)、ES1(B) 和 ES1(C) 分别代表第一、第二和第三种有机化合物的最低单激发能级。ES1A>ES1B>ES1C
• Host material for delayed fluorescent materials, organic light-emitting device and compound
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10559757B2

  公开（公告）日：2020-02-11

  A compound represented by (Tr)n-Z is useful as a host material for delayed fluorescent materials. Tr represents a substituted or unsubstituted triphenylenyl group, and plural Tr's existing in the general formula (1) may be the same as or different from each other. Z represents a carbonyl group or a substituted or unsubstituted, n-valent aromatic hydrocarbon group. n represents an integer of 2 to 6, but when Z is a carbonyl group, n is 2.

  (Tr)n-Z 所代表的化合物可用作延迟荧光材料的宿主材料。Tr 代表取代或未取代的三亚苯基，通式（1）中的多个 Tr 可以相同或不同。n 代表 2 至 6 的整数，但当 Z 为羰基时，n 为 2。