(2-Bromophenyl)imino-methyl-phenyl-phenylimino-lambda6-sulfane | 1449673-46-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Bromophenyl)imino-methyl-phenyl-phenylimino-lambda6-sulfane
• 英文别名: (2-bromophenyl)imino-methyl-phenyl-phenylimino-λ6-sulfane
• CAS: 1449673-46-4
• 化学式: C₁₉H₁₇BrN₂S
• 分子量: 385.327
• InChiKey: YYEJFXRJCGSXKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  33.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-H-N'-phenyl-S-phenyl-S-methyl sulfondiimine 、 2-溴苯基硼酸 在 copper diacetate 作用下， 以 甲醇 为溶剂， 反应 24.0h， 以94%的产率得到(2-Bromophenyl)imino-methyl-phenyl-phenylimino-lambda6-sulfane
  参考文献：
  名称：

  Copper-Catalyzed C–N Cross-Coupling of Sulfondiimines with Boronic Acids

  摘要：

  The copper-catalyzed C-N cross-coupling of sulfondiimines with boronic acids has been developed. The reaction proceeds at room temperature in good to excellent yields and provides access to a variety of N,N'-disubstituted sulfondiimines, including N-(hetero)aryl sulfondiimines and the first reported N-alkenylated sulfondiimine.

  DOI：

  10.1021/ol401642n

文献信息

• Copper-Catalyzed C–N Cross-Coupling of Sulfondiimines with Boronic Acids
  作者：Rebekka Anna Bohmann、Carsten Bolm

  DOI：10.1021/ol401642n

  日期：2013.9.6

  The copper-catalyzed C-N cross-coupling of sulfondiimines with boronic acids has been developed. The reaction proceeds at room temperature in good to excellent yields and provides access to a variety of N,N'-disubstituted sulfondiimines, including N-(hetero)aryl sulfondiimines and the first reported N-alkenylated sulfondiimine.