chlorothiophosphoric acid O,O'-di-o-tolyl ester | 81532-95-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chlorothiophosphoric acid O,O'-di-o-tolyl ester
• 英文别名: Thiophosphorsaeure-O.O-di-o-tolylester-chlorid；Chlorothiophosphorsaeure-O,O'-di-o-tolylester；Chloro-bis(2-methylphenoxy)-sulfanylidene-lambda5-phosphane；chloro-bis(2-methylphenoxy)-sulfanylidene-λ5-phosphane
• CAS: 81532-95-8
• 化学式: C₁₄H₁₄ClO₂PS
• 分子量: 312.757
• InChiKey: FCISPDLPLUNYKR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  chlorothiophosphoric acid O,O'-di-o-tolyl ester 在 氨 作用下， 以 苯 为溶剂， 反应 2.0h， 生成 Thiophosphoramidic acid O,O'-di-o-tolyl ester
  参考文献：
  名称：

  新型芳基取代二硫代亚氨基膦酸盐作为金属外渗剂的合成与评价

  摘要：

  通过O,O,-二芳基氯硫代磷酸酯2和二芳基硫代膦酰胺在强碱性条件下反应合成了一系列新型O,O',O",O"'-四芳基二硫代亚氨基膦酸酯[(ArO)2PS]2NH4。以硫代磷酰氯和取代酚为原料，在相转移催化条件下首次制备了关键中间体2a~2g。这些四芳基二硫代亚氨基膦酸酯对来自硫酸盐溶液的 Zn 2 + 比 Fe 3 + 显示出高选择性。还讨论了取代基对标题化合物的 31 P NMR 的影响。

  DOI：

  10.1080/104265090968064
• 作为产物：
  描述：

  bis(o-tolyl) chlorophosphite 在 sulfur 作用下， 生成 chlorothiophosphoric acid O,O'-di-o-tolyl ester
  参考文献：
  名称：

  Strecker; Grossmann, Chemische Berichte, 1916, vol. 49, p. 75

  摘要：

  DOI：

文献信息

• Flame retardant, additive compositions, and flame retardant polyurethanes
  申请人：Hussain Saadat

  公开号：US20050113495A1

  公开（公告）日：2005-05-26

  Provided are new flame retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; b) at least one hindered amine antioxidant; and c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of about 6 to about 16 carbon atoms.

  本文提供了用于软质聚氨酯泡沫的新型阻燃剂和低粘度液体阻燃添加剂组合物。新型阻燃剂是至少一种溴化芳香族二酯二醇与至少一种醇反应剂的反应产物。优选的液态阻燃添加剂组合物能够在泡沫生产过程中最大限度地减少可见的焦烧现象。此外，还提供了柔性阻燃聚氨酯泡沫及其生产方法。阻燃添加剂组合物至少由以下物质形成：a) 至少一种溴化芳香族二酯二元醇与醇反应剂的反应产物；b) 至少一种受阻胺抗氧化剂；c) 至少一种酚类抗氧化剂，其中酚环被烷酸烷基酯基团取代，烷酸分子的碳原子数在 2 至约 4 之间，烷基的碳原子数在约 6 至约 16 之间。
• Grossmann, Dissertation <Marburg 1915>, S. 54
  作者：Grossmann

  DOI：——

  日期：——
• FLAME RETARDANT, ADDITIVE COMPOSITIONS, AND FLAME RETARDANT POLYURETHANES
  申请人：ALBEMARLE CORPORATION

  公开号：EP1685176A2

  公开（公告）日：2006-08-02
• US7153901B2
  申请人：——

  公开号：US7153901B2

  公开（公告）日：2006-12-26
• [EN] FLAME RETARDANT, ADDITIVE COMPOSITIONS, AND FLAME RETARDANT POLYURETHANES<br/>[FR] PRODUITS IGNIFUGES, ADDITIFS IGNIFUGES, ET POLYURETHANES IGNIFUGES
  申请人：ALBEMARLE CORP

  公开号：WO2005052018A2

  公开（公告）日：2005-06-09

  Provided are new flames retardants and liquid flame retardant additive compositions of low viscosity for use in flexible polyurethane foams. The new flame retardants are the reaction product of at least one brominated aromatic diester diol with at least one alcohol-reactive agent. Preferred liquid flame retardant additive compositions are capable of minimizing visible scorching of the foam during its production. Flexible flame retardant polyurethane foams and methods for their production are also provided. The flame retardant additive compositions are formed at least from (a) at least one reaction product of a brominated aromatic diester diol and an alcohol-reactive agent; (b) at least one hindered amine antioxidant; and (c) at least one phenolic antioxidant in which the phenolic ring is substituted by an alkanoic acid alkyl ester group in which alkanoic acid moiety has in the range of 2 to about 4 carbon atoms and the alkyl group has in the range of 6 to 16 carbon atoms.