(4-Bromophenyl)-[10-[(4-bromophenyl)diazenyl]-9,10-dihydrophenanthren-9-yl]diazene | 136271-51-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: (4-Bromophenyl)-[10-[(4-bromophenyl)diazenyl]-9,10-dihydrophenanthren-9-yl]diazene
• CAS: 136271-51-7
• 化学式: C₂₆H₁₈Br₂N₄
• 分子量: 546.264
• InChiKey: USJNUMKBGARTOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (4-Bromophenyl)-[10-[(4-bromophenyl)diazenyl]-9,10-dihydrophenanthren-9-yl]diazene 在 lead(IV) acetate 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 2-(4-Bromophenyl)phenanthro[9,10-d]triazole
  参考文献：
  名称：

  Tricyclic phenanthrene systems: substituted phenanthro[9,10-e]-1,2,3-triazines and fused phenanthro-azolo-1,2,3-triazoles from cycloaddition—rearrangement sequences of 9,10-bisarylazophenanthrenes with 2π-dipolarophiles. Azolium 1,3-dipoles

  摘要：

  A range of new fused ring systems based on phenanthrene were obtained from cycloaddition-rearrangement reactions of 9, 10-bisarylazophenanthrenes with alkyne and alkene dipolarophilles. These new rings include substituted phenanthro[9,10-e]-1,2,3-triazines, the tricyclic systems, substituted 3a,6a-(biphen-2,2'-yl)hexahydropyrrolo[2, 3-d]-1,2,3-triazoles and substituted 3a,6a-(biphen-2,2'-yl)hexahydroimidazo[4,5-d]-1,2,3-triazoles. X-Ray crystal structures are reported on 2-(p-bromophenyl)-4 -methoxycarbonyl-4-(p-bromophenyliminomethoxalyl)-3,4-dihydrophenanthro[9,10-e]-1,2,3-triazin-2-ium-3-ide 6b, and 2,4-diphenyl-3a,6a-(biphen-2,2'-yl)-5,6-hexahydropyrrolo[2,3-d]-1,2, 3-triazol-2-ium-1-ide 11a.

  DOI：

  10.1039/p19960001623
• 作为产物：
  描述：

  4-bromo-N-[[2-[2-[[(4-bromophenyl)hydrazinylidene]methyl]phenyl]phenyl]methylideneamino]aniline 在 lead dioxide 作用下， 以 甲苯 为溶剂， 以88%的产率得到(4-Bromophenyl)-[10-[(4-bromophenyl)diazenyl]-9,10-dihydrophenanthren-9-yl]diazene
  参考文献：
  名称：

  Tricyclic phenanthrene systems: substituted phenanthro[9,10-e]-1,2,3-triazines and fused phenanthro-azolo-1,2,3-triazoles from cycloaddition—rearrangement sequences of 9,10-bisarylazophenanthrenes with 2π-dipolarophiles. Azolium 1,3-dipoles

  摘要：

  A range of new fused ring systems based on phenanthrene were obtained from cycloaddition-rearrangement reactions of 9, 10-bisarylazophenanthrenes with alkyne and alkene dipolarophilles. These new rings include substituted phenanthro[9,10-e]-1,2,3-triazines, the tricyclic systems, substituted 3a,6a-(biphen-2,2'-yl)hexahydropyrrolo[2, 3-d]-1,2,3-triazoles and substituted 3a,6a-(biphen-2,2'-yl)hexahydroimidazo[4,5-d]-1,2,3-triazoles. X-Ray crystal structures are reported on 2-(p-bromophenyl)-4 -methoxycarbonyl-4-(p-bromophenyliminomethoxalyl)-3,4-dihydrophenanthro[9,10-e]-1,2,3-triazin-2-ium-3-ide 6b, and 2,4-diphenyl-3a,6a-(biphen-2,2'-yl)-5,6-hexahydropyrrolo[2,3-d]-1,2, 3-triazol-2-ium-1-ide 11a.

  DOI：

  10.1039/p19960001623