(2,3,4,7-四甲氧基-9,10-二氢-[9]菲基)-甲醇 | 855618-82-5

• 分子结构分类: 有机化合物 - 苯类化合物
• 中文名称: (2,3,4,7-四甲氧基-9,10-二氢-[9]菲基)-甲醇
• 英文名称: (2,3,4,7-Tetramethoxy-9,10-dihydro-[9]phenanthryl)-methanol
• CAS: 855618-82-5
• 化学式: C₁₉H₂₂O₅
• 分子量: 330.381
• InChiKey: IWUVFVDYZQVWRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.02
• 重原子数：
  24.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  57.15
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  (2,3,4,7-四甲氧基-9,10-二氢-[9]菲基)-甲醇 在 phosphorus pentoxide 、 xylene 作用下， 生成 deaminocolchinol methyl ether
  参考文献：
  名称：

  Cook et al., Journal of the Chemical Society, 1952, p. 607,610

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3,4,7-tetramethoxy-9,10-dihydro-phenanthrene-9-carboxylic acid methyl ester 在 lithium aluminium tetrahydride 、 乙醚 作用下， 生成 (2,3,4,7-四甲氧基-9,10-二氢-[9]菲基)-甲醇
  参考文献：
  名称：

  Cook et al., Journal of the Chemical Society, 1952, p. 607,610

  摘要：

  DOI：

文献信息

• Oxidation of Gas Mixtures Containing Dimethyl Sulfide, Hydrogen Sulfide, and Methanethiol Using a Two-Stage Biotrickling Filter
  作者：Arja Ruokojärvi、Juhani Ruuskanen、Pertti J. Martikainen、Minna Olkkonen

  DOI：10.1080/10473289.2001.10464260

  日期：2001.1

  A biofiltration technique was developed for removing a mixture of hydrogen sulfide (H2S), methanethiol (MeSH), and dimethyl sulfide (Me2S) from waste gases. Since H2S, especially at high concentrations, disturbs the removal of Me2S, two biotrickling filters with different microbes and operating pH levels were connected in series to create a two-stage system. Different loads of these gases were studied in order to determine their impact on the removal capacity of the system. The microbial consortia for these filters were enriched from the sludge of a Finnish refinery with bubbling H2S or Me2S. Acclimation for Me2S took 2 weeks, though no acclimation time was needed for the other gases. The first filter, at a pH of 2, removed most of the H2S and some of the MeSH and Me2S. The second filter, at a pH of similar to6.5, removed the rest of the MeSH and most of the Me2S. The total maximum loads of the whole two-stage biotrickling filter were 1150 g/m(3)/day for H2S-S (suffix S indicates the results are counted as sulfur amounts), 879 g/m(3)/day for Me2S-S, and 66 g/m(3)/day for MeSH-S treated in a gas mixture. The average removal efficiencies for all gases tested were 99% or higher.
• 35. Colchicine and related compounds. Part I. Some observations on the structure of colchicine
  作者：A. Cohen、J. W. Cook、E. M. F. Roe

  DOI：10.1039/jr9400000194

  日期：——