Ru(2,2'-bipyridine)(CH3CN)3Cl(BF4) | 147486-24-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ru(2,2'-bipyridine)(CH3CN)3Cl(BF4)
• CAS: 147486-24-6
• 化学式: BF₄*C₁₆H₁₇ClN₅Ru
• 分子量: 502.672
• InChiKey: DPBKVECHTBQEAW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Ru(bpy)(NCMe)₂Cl₂ 在 乙腈 作用下， 以 乙腈 为溶剂， 生成 Ru(2,2'-bipyridine)(CH3CN)3Cl(BF4)
  参考文献：
  名称：

  Photochemical reactivity of [RuII(L)(CO)2Cl2] and [Me4N] [RuII(L)(CO)Cl3] (L = 2,2′-bipyridine or 4,4′- di(isopropoxycarbonyl)-2,2′-bipyridine) in CH3CN and the redox properties of the resulting new complexes

  摘要：

  Photolysis of acetonitrile solutions of [RuII(LXCO)2Cl2] or [Me4N][RuII(L)(CO)Cl3] (L = 2,2'-bipyridine or 4,4'-di(isopropoxycarbonyl-2,2'-bipyridine) leads to the successive formation of the new complexes [Ru(L)(CO)(CH3CN)Cl2], [Ru(L)(CH3CN)2Cl2], and [Ru(L)(CH3CN)3Cl]+ by photosubstitution processes. However, [Ru(L)(CH3CN)2Cl2], unlike [Ru(L)(CO)(CH3CN)Cl2] and [Ru(L)(CH3CN)3Cl]+, cannot be obtained quantitatively with the complex having the unsubstituted 2,2'-bipyridine ligand. Moreover [Ru(L)(CH3CN)3Cl]+ cannot be produced at a significant rate for complexes with L = 4,4'-isopropoxycarbonyl-2,2'-bipyridine. The redox behaviour of all these compounds was studied by cyclic voltammetry at a platinum electrode, exhaustive electrolysis experiments, and UV-visible absorption spectroscopy.

  DOI：

  10.1016/0022-328x(93)83073-5