N-o-tolyl-acetimidoyl chloride | 52119-07-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-o-tolyl-acetimidoyl chloride
• 英文别名: N-o-Tolyl-acetimidoylchlorid；N-(o-Tolyl)-acetimidoylchlorid；N-o-Tolyl-acetimidoylchlorid；N-(2-methylphenyl)ethanimidoyl chloride
• CAS: 52119-07-0
• 化学式: C₉H₁₀ClN
• 分子量: 167.638
• InChiKey: ZMVIEQYFAPBAHG-UHFFFAOYSA-N

物化性质

• 沸点：
  95-97 °C(Press: 14 Torr)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-o-tolyl-acetimidoyl chloride 900.0 ℃ 、1.33 Pa 条件下， 生成 喹啉
  参考文献：
  名称：

  闪蒸真空热解形成吲哚和喹啉

  摘要：

  N-（2-甲基苯基）亚氨苄基氯化物的闪光真空热解和，二甲基- N' - （2-甲基苯基）甲脒提供了2-芳基-和2-吲哚未取代的简单路由。的热解，二甲基- （2-甲基苯基）acetamidines给出主要在它揭示一种新颖的3,4-二氢喹啉高温重排反应喹啉。

  DOI：

  10.1016/s0040-4039(00)96779-0
• 作为产物：
  描述：

  2-甲基乙酰苯胺 在 五氯化磷 作用下， 生成 N-o-tolyl-acetimidoyl chloride
  参考文献：
  名称：

  Taxonomic Characterization of New Alkaliphilic and Alkalitolerant Methanotrophs from Soda Lakes of the Southeastern Transbaikal Region and description of Methylomicrobium buryatense sp.nov.

  摘要：

  Five strains of obligate methanotrophic bacteria (4G, 5G, 6G, 7G and 5B) isolated from bottom sediments of Southeastern Transbaikal soda lakes (pH 9.5-10.5) are taxonomically described. These bacteria are aerobic, Gram-negative monotrichous rods having tightly packed cup-shaped structures on the outer cell wall surface (S-layers) and Type I intracytoplasmic membranes. All the isolates possess particulate methane monooxygenase (pMMO) and one strain (5G) also contains soluble methane monooxygenase (sMMO). They assimilate methane and methanol via the ribulose monophosphate pathway (Rump). The isolates are alkalitolerant or facultatively alkaliphilic, able to grow at pH 10.5-11.0 and optimally at pH 8.5-9.5. These organisms are obligately dependent on the presence of sodium ions in the growth medium and tolerate up to 0.9-1.4 M NaCl or 1 M NaHCO3. Although being mesophilic, all the isolates are resistant to heating (80 degreesC, 20 min), freezing and drying. Their cellular fatty acids profiles primarily consist of C-16:1. The major phospholipids are phosphatidylethanolamine and phosphatidylglycerol. The main quinone is Q-8. The DNA G+C content ranges from 49.2-51.5 mol %. Comparative 16S rDNA sequencing showed that the newly isolated methanotrophs are related to membres of the Methylomicrobium genus. However, they differ from the known members of this genus by DNA-DNA relatedness. Based on pheno- and genotypic characteristics, we propose a new species of the genus Methylomicrobium Methylomicrobium buryatense sp. nov.

  DOI：

  10.1078/0723-2020-00028

文献信息

• Barnikow, Guenter; Lehner, Juergen; Martin, Arnim A., Zeitschrift fur Chemie, 1985, vol. 25, # 6, p. 219 - 220
  作者：Barnikow, Guenter、Lehner, Juergen、Martin, Arnim A.

  DOI：——

  日期：——