(diisopropylamino)bisphosphanylborane | 147875-80-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (diisopropylamino)bisphosphanylborane
• 英文别名: N-bis(phosphanyl)boranyl-N-propan-2-ylpropan-2-amine
• CAS: 147875-80-7
• 化学式: C₆H₁₈BNP₂
• 分子量: 176.974
• InChiKey: ZCDCTUOSFQBKFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.84
• 重原子数：
  10.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  二氯(二异丙基氨基)硼烷 、 LiPH₂*DME 以 not given 为溶剂， 生成 (diisopropylamino)phosphanylboron chloride 、 (diisopropylamino)bisphosphanylborane
  参考文献：
  名称：

  Dou, Danan; Westerhausen, Matthias; Wood, Gary L., Chemische Berichte, 1993, vol. 126, # 2, p. 379 - 398

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Coordination Chemistry of Aminophosphanylboranes
  作者：Danan Dou、Gerald W. Linti、Tuqiang Chen、Eileen N. Duesler、Robert T. Paine、Heinrich Nöth

  DOI：10.1021/ic9514399

  日期：1996.1.1

  Syntheses for the diphosphadiboretane ((Pr2NBPH)-Pr-i)(2), the triphosphatriborinane ((Pr2NBPH)-Pr-i)(3), and the aminodiphosphanylborane (Pr2NB)-Pr-i(PH2)(2) are reported. Reaction of these ligands with Cr(CO)(5) . NMe(3) results in the formation of the complexes ((Pr2NBPH)-Pr-i)(2) . Cr(CO)(5) and (Pr2NB)-Pr-i(PH2)(2) . 2Cr(CO)(5). Molecular structure determinations for the diphosphadiboretane, the triphosphatriborinane, and the two coordination complexes have been completed by use of single crystal X-ray diffraction techniques: ((Pr2NBPH)-Pr-i)(2) (C6H15BNP) crystallizes in the monoclinic space group P2(1)/n with a = 7.7200(10) Angstrom, b = 10.514(2) Angstrom, c = 11.231(2) Angstrom, beta = 101.100(10)degrees, and Z = 4; ((Pr2NBPH)-Pr-i)(3) (C18H45B3N3P3) crystallizes in the monoclinic space group P2(1)/n with a = 20.217(16) Angstrom, b = 13.764(11) Angstrom, c = 20.494(16) Angstrom, beta = 104.40(5)degrees, and Z = 8; ((Pr2NBPH)-Pr-i)(2) . Cr(CO)(5) (C17H30B2N2O5P2Cr) crystallizes in the monoclinic space group P2(1)/n with a 11.284(3) Angstrom, b = 14.583(6) Angstrom, c = 16.515(4) Angstrom, beta = 105.97(2)degrees, and Z = 4; (Pr2NB)-Pr-i(PH2)(2) .[Cr(CO)(5)](2) (C16H18BNO10P2Cr2) crystallizes in the orthorhombic space group Fdd2 with a = 23.214(8) Angstrom, b = 11.914(5) Angstrom, c = 18.359(5) Angstrom, and Z = 8.