cis-[MoO2(salicylidene salicyloyl acid hydrazide)(water)] | 82308-20-1

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物 - 环庚三烯酮
• 英文名称: cis-[MoO2(salicylidene salicyloyl acid hydrazide)(water)]
• CAS: 82308-20-1
• 化学式: C₁₄H₁₂MoN₂O₆
• 分子量: 400.199
• InChiKey: PMZIIHNZIYVEGR-PGGSIGJZSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[MoO2(salicylidene salicyloyl acid hydrazide)(water)] 在 2,2'-联吡啶 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Syamal, A.; Maurya, M. R., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1984, vol. 23, # 11, p. 950 - 951

  摘要：

  DOI：
• 作为产物：
  描述：

  水 、 bis(acetylacetonato)dioxomolybdenum(VI) 、 (E)-2-hydroxy-N'-(2-hydroxybenzylidene)benzohydrazide 以 水 、 丙酮 为溶剂， 以75%的产率得到cis-[MoO2(salicylidene salicyloyl acid hydrazide)(water)]
  参考文献：
  名称：

  Synthesis, spectral and X-ray structural characterization of [cis-MoO2(L)(solv)] (L=salicylidene salicyloyl hydrazine) and its use as catalytic oxidant

  摘要：

  The synthesis and characterization of cis-[MoO2(L) (solv)] [L = salicylidene salicyloyl hydrazine and solvent=H2O/MeOH) is described. The tridentate Schiff base ligand was obtained by the condensation of salicylaldehyde and salicylic acid hydrazide in 1:1 ratio. The dioxomolybdenum complex was isolated from 1:1 reaction mixture containing the Schiff base ligand and MoO2(acac)(2). The orange colored, non-electrolytic and diamagnetic compound was characterized by elemental analyses, spectroscopic techniques (IR,H-1 NMR and UV-Vis), and cyclic voltammetry. The molecular structure was determined using crystals obtained from methanol, confirmed the formula cis-MoO2(L)(CH3OH) with triclinic P-1 space group. The Mo is coordinated by two cis terminal Os, ONO from the ligand and O of methanol. The oxo-transfer reaction from cis-[MoO2(L)(solv)] to PPh3, is reported. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00139-4