2,2’-diamino-4,4’-stilbenedicarboxylic acid | 1202689-45-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 2,2’-diamino-4,4’-stilbenedicarboxylic acid
• 英文别名: 2,2'-diamino-4,4'-stilbenedicarboxylic acid；3-Amino-4-[2-(2-amino-4-carboxyphenyl)ethenyl]benzoic acid
• CAS: 1202689-45-9
• 化学式: C₁₆H₁₄N₂O₄
• 分子量: 298.298
• InChiKey: QEDSDXRFNGAJKN-UHFFFAOYSA-N

物化性质

• 沸点：
  636.2±55.0 °C(Predicted)
• 密度：
  1.474±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  127
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,2’-diamino-4,4’-stilbenedicarboxylic acid 在 亚硝酸特丁酯 、 叠氮基三甲基硅烷 作用下， 以 四氢呋喃 为溶剂， 反应 72.25h， 以59%的产率得到2,2'-diazido-4,4'-stilbenedicarboxylic acid
  参考文献：
  名称：

  Fabrication of Highly Uniform Gel Coatings by the Conversion of Surface-Anchored Metal–Organic Frameworks

  摘要：

  We report the fabrication of 3D, highly porous, covalently bound polymer films of homogeneous thickness. These surface-bound gels combine the advantages of metal organic framework (MOF) materials, namely, the enormous flexibility and the large size of the maximum pore structures and, in particular, the possibility to grow them epitaxially on modified substrates, with those of covalently connected gel materials, namely, the absence of metal ions in the deposited material, a robust framework consisting of covalent bonds, and, most importantly, pronounced stability under biological conditions. The conversion of a SURMOF (surface-mounted MOF) yields a surface-grafted gel. These SURGELs can be loaded with bioactive compounds and applied as bioactive coatings and provide a drug-release platform in in vitro cell culture studies.

  DOI：

  10.1021/ja409205s

文献信息

• Enhancement of visible-light-driven CO₂ reduction performance using an amine-functionalized zirconium metal–organic framework
  作者：Manying Sun、Siyu Yan、Yujia Sun、Xiaohan Yang、Zhifen Guo、Jianfeng Du、Dashu Chen、Peng Chen、Hongzhu Xing

  DOI：10.1039/c7dt04062h

  日期：——

  An amine-functionalized zirconium metal–organic framework for the enhancement of visible-light-driven CO₂ reduction to formate.

  一种胺功能化的锆金属有机框架，用于增强可见光驱动的CO2还原生成甲酸。
• Phospholipid Ether Analogs as Cancer-Targeting Drug Vehicles
  申请人：Cellectar Biosciences, Inc.

  公开号：US20160136190A1

  公开（公告）日：2016-05-19

  The present invention is directed to therapeutic compounds capable of targeting cancer cells and cancer stem cells. The present invention is further directed to compositions comprising these therapeutic compounds and methods of treating cancer comprising administering these therapeutic compounds.

  本发明旨在针对癌细胞和癌干细胞的治疗化合物。本发明进一步涉及包含这些治疗化合物的组合物和治疗癌症的方法，其中包括给予这些治疗化合物。
• Organic semiconductor compound based on 2,7-bis-(vinyl)[1]benzothieno[3,2-b]benzothiophene, organic semiconductor thin film and transistor using the same and methods of forming the same
  申请人：Hong Jong-in

  公开号：US20100006830A1

  公开（公告）日：2010-01-14

  An organic semiconductor compound based on a 2,7-bis-(vinyl)[1]benzothieno[3,2-b]benzothiophene backbone, an organic semiconductor thin film, an organic thin film transistor and methods of forming the same are provided, the organic semiconductor compound including a vinyl group derived from a phosphonate derivative represented by Formula 1 and an aldehyde derivative represented by Formula 2 below:

  提供了一种基于2,7-双-(乙烯基)[1]苯并噻吩[3,2-b]苯并噻吩骨架的有机半导体化合物，有机半导体薄膜，有机薄膜晶体管以及其形成方法，其中有机半导体化合物包括来自以下公式1所代表的膦酸酯衍生物和公式2所代表的醛衍生物的乙烯基基团：
• ORGANOMETALLIC FRAMEWORK
  申请人：TOYOTA JIDOSHA KABUSHIKI KAISHA

  公开号：EP3730496A1

  公开（公告）日：2020-10-28

  The present invention provides a metal-organic framework which can both adsorb water vapor in low relative humidity and reduce the magnitude of the humidity difference between the adsorption humidity and the desorption humidity. A metal organic framework wherein the metal ion is an aluminum ion, a first ligand is an organic compound ion consisting of a first heterocycle having two carboxyl groups, and a heteroatom composing the first heterocycle is present on the minor angle side of the angle created by the two carboxyl groups, a second ligand is different than the first ligand, is an organic compound ion consisting of a second heterocycle having two carboxyl groups, and a heteroatom composing the second heterocycle is present on the major angle side of the angle create by the two carboxyl groups, and a third ligand is different than the first ligand and the second ligand, is an organic compound ion having two carboxyl groups, and the first ligand, second ligand, and third ligand are present in a specific ratio.

  本发明提供了一种金属有机框架，它既能在低相对湿度下吸附水汽，又能减小吸附湿度与解吸湿度之间的湿度差的大小。 一种金属有机框架，其中金属离子是铝离子，第一配体是由具有两个羧基的第一杂环组成的有机化合物离子，组成第一杂环的杂原子存在于两个羧基所成角的小角侧，第二配体与第一配体不同、是由具有两个羧基的第二杂环组成的有机化合物离子，组成第二杂环的杂原子存在于两个羧基所成角度的大角侧，第三配体不同于第一配体和第二配体，是具有两个羧基的有机化合物离子，第一配体、第二配体和第三配体以特定比例存在。
• FLUORORESIN-CONTAINING BAKEABLE POWDER COATING COMPOSITION AND LIQUID COATING COMPOSITION, AND COATING AND COATED BODY COMPRISING THIS BAKEABLE POWDER COATING COMPOSITION OR LIQUID COATING COMPOSITION
  申请人：Nippon Fusso CO., LTD.

  公开号：EP3816245A1

  公开（公告）日：2021-05-05

  The present invention addresses the problem of providing powder paint compositions and liquid paint compositions for baking, which have excellent corrosion resistance and workability as well as high durability and chemical resistance, and form a good lining film free from failures such as cracks; and a coating film and coated objects comprising such powder paint compositions or liquid paint compositions for baking. Powder paint compositions for baking comprise fluororesin where one or more types of porous coordination polymer (PCP) / metal-organic framework (MOF) formed by coordinate bonds between organic ligands and central metals disperse.

  本发明所要解决的问题是提供用于烘烤的粉末涂料组合物和液体涂料组合物，它们具有优异的耐腐蚀性和可加工性以及高耐久性和耐化学性，并能形成无裂纹等故障的良好衬膜；以及包含这种用于烘烤的粉末涂料组合物或液体涂料组合物的涂膜和被涂物。用于烘烤的粉末涂料组合物包括氟树脂，其中分散着一种或多种由有机配体和中心金属之间的配位键形成的多孔配位聚合物（PCP）/金属有机框架（MOF）。