4-(8-bromodibenzothiophen-2-yl)-N,N-diphenylaniline | 1422184-05-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(8-bromodibenzothiophen-2-yl)-N,N-diphenylaniline
• CAS: 1422184-05-1
• 化学式: C₃₀H₂₀BrNS
• 分子量: 506.466
• InChiKey: PRWZTIWRMOAWCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  31.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(8-bromodibenzothiophen-2-yl)-N,N-diphenylaniline 在 哌啶 、 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 9.0h， 生成
  参考文献：
  名称：

  Efficient organic dyes containing dibenzo heterocycles as conjugated linker part for dye-sensitized solar cells

  摘要：

  Six new organic dyes, TBS1-TBS6, have been synthesized and characterized by optical, electrochemical, and theoretical studies. Among these dyes, DSSCs based on a dye containing N-hexylcarbazole and furan moieties (TBS4) showed the best performance, with light-to-electricity conversion efficiency up to 5.91% under AM 1.5 solar simulator, much higher than the reference dye TPS (4.24%). The high V-oc contributed to the good performance for TBS4, which may be ascribed to the combined effects of twisted structure and hexyl chain. Additionally, for TBS4 based DSSCs, under optimized conditions, the light-to-electricity conversion efficiency was enhanced up to 7.09%. The results suggest that dibenzo heterocycles containing dyes are promising candidates for application in DSSCs. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.12.074
• 作为产物：
  描述：

  三苯胺 在 盐酸 、 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 四氯化碳 、 正己烷 、 水 为溶剂， 反应 11.5h， 生成 4-(8-bromodibenzothiophen-2-yl)-N,N-diphenylaniline
  参考文献：
  名称：

  Efficient organic dyes containing dibenzo heterocycles as conjugated linker part for dye-sensitized solar cells

  摘要：

  Six new organic dyes, TBS1-TBS6, have been synthesized and characterized by optical, electrochemical, and theoretical studies. Among these dyes, DSSCs based on a dye containing N-hexylcarbazole and furan moieties (TBS4) showed the best performance, with light-to-electricity conversion efficiency up to 5.91% under AM 1.5 solar simulator, much higher than the reference dye TPS (4.24%). The high V-oc contributed to the good performance for TBS4, which may be ascribed to the combined effects of twisted structure and hexyl chain. Additionally, for TBS4 based DSSCs, under optimized conditions, the light-to-electricity conversion efficiency was enhanced up to 7.09%. The results suggest that dibenzo heterocycles containing dyes are promising candidates for application in DSSCs. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.12.074

文献信息

• 含有杂原子桥联咔唑结构单元的化合物及其制 备方法与应用
  申请人：石家庄诚志永华显示材料有限公司

  公开号：CN103936749B

  公开（公告）日：2016-06-22

  本发明公开了含有杂原子桥联咔唑结构单元的化合物及其制备方法与应用。该类化合物，其结构通式如式I所示。该式I所示化合物，核磁检测正确，基于现阶段蓝光材料研究较少，存在着缺乏高效率、高稳定性的蓝光发光材料，提供了一系列含有螺芴结构的OLED蓝光发光材料。该类化合物，而且原料易得，制备简便，总体收率高，对于研究蓝光材料的进展与应用，具有重要的应用价值。
• [EN] COMPOUND FOR ORGANIC ELECTRIC DEVICE, ORGANIC ELECTRIC DEVICE USING SAME, AND ELECTRONIC DEVICE<br/>[FR] COMPOSÉ POUR DISPOSITIF ÉLECTRIQUE ORGANIQUE, DISPOSITIF ÉLECTRIQUE ORGANIQUE L'UTILISANT, ET DISPOSITIF ÉLECTRONIQUE ASSOCIÉ<br/>[KO] 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2017095075A1

  公开（公告）日：2017-06-08

  본 발명은 소자의 발광효율, 안정성 및 수명을 향상시킬 수 있는 신규 화합물 및 이를 이용한 유기전기소자, 그 전자 장치를 제공한다.