6-Benzoyloxy-[2]naphthol | 173368-58-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-Benzoyloxy-[2]naphthol
• 英文别名: 6-benzoyloxy-2-hydroxynaphthalene；6-hydroxy-2-naphthyl benzoate；(6-hydroxynaphthalen-2-yl) benzoate
• CAS: 173368-58-6
• 化学式: C₁₇H₁₂O₃
• 分子量: 264.28
• InChiKey: YEUFARHMFRFKRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6-Benzoyloxy-[2]naphthol 在 甲醇 、 氢氧化钾 、 palladium on activated charcoal 、 二氧化硫 、 potassium carbonate 、 溶剂黄146 、 丙酮 、 sodium nitrite 作用下， 生成 5,6-Dimethoxy-1-nitroso-[2]naphthol
  参考文献：
  名称：

  The Synthesis of Ring Systems Related to Morphine. III. 5,6-Dimethoxy-4-cyanomethyl-1,2-naphthoquinone and its Condensation with Dienes

  摘要：

  DOI：

  10.1021/ja01157a064
• 作为产物：
  描述：

  2,6-萘二酚 、 苯甲酰氯 在 吡啶 作用下， 生成 6-Benzoyloxy-[2]naphthol
  参考文献：
  名称：

  The Synthesis of Ring Systems Related to Morphine. III. 5,6-Dimethoxy-4-cyanomethyl-1,2-naphthoquinone and its Condensation with Dienes

  摘要：

  DOI：

  10.1021/ja01157a064

文献信息

• LIQUID CRYSTAL MOLECULE, LIQUID CRYSTAL DISPLAY DEVICE AND LIQUID CRYSTAL OPTICAL SPATIAL MODULATION DEVICE
  申请人：Kotake Rika

  公开号：US20100085530A1

  公开（公告）日：2010-04-08

  A liquid crystal molecule is disclosed, having a structure represented by the following general formula (1): wherein X 1 is a group selected among groups represented by the following formula (2): X 2 is represented by the following formula (3): R 1 represents a linear or branched hydrocarbon group or an alkoxy group each having from 4 to 16 carbon atoms; R 2 represents an optionally branched organosiloxane or organosilane having from 1 to 6 silicon atoms; R 3 and R 4 are different from each other and each represents H, F, Cl, Br, CN, CH 3 , CF 3 or OCH 3 ; Y 1 represents -, —COO—, —CH 2 —, —CH 2 O—, —C 2 H 2 —, —C 2 — or —CF 2 O—; Z 1 to Z 4 each represents H, F, Cl, Br, OH, NO 2 , CN, CF 3 , CH 3 , C 2 H 5 , OCH 3 or OC 2 H 5 ; Z 5 to Z 7 each represents H, F, Cl, Br, OH, NO 2 , CN or CF 3 , provided that Z 5 , Z 6 and Z 7 do not represent H at the same time; n represents an integer of from 1 to 6; * represents a chiral center; and - means a connecting group.

  揭示了一种液晶分子，其结构由以下通式（1）表示：其中X1是在以下通式（2）表示的群中选择的群；X2由以下通式（3）表示；R1表示具有4至16个碳原子的线性或支链烃基或烷氧基；R2表示具有1至6个硅原子的可选支链有机硅氧烷或有机硅烷；R3和R4不同且分别表示H、F、Cl、Br、CN、CH3、CF3或OCH3；Y1表示-、—COO—、—CH2—、—CH2O—、—C2H2—、—C2—或—CF2O—；Z1至Z4各自表示H、F、Cl、Br、OH、NO2、CN、CF3、CH3、C2H5、OCH3或OC2H5；Z5至Z7各自表示H、F、Cl、Br、OH、NO2、CN或CF3，但要求Z5、Z6和Z7不同时表示H；n表示1至6的整数；*表示手性中心；-表示连接基。
• Antiproliferative Compositions Comprising Aryl Substituted Xylopyranoside Derivatives
  申请人：Ellervik Ulf

  公开号：US20080027023A1

  公开（公告）日：2008-01-31

  Novel xylose based glycoside compounds that have xylose linked O-, S- or C-glycosidically to an aglycone containing several aromatic rings, and compositions that comprise the novel xylose based glycosides and non-xylose-based anti-tumor agents, pharmaceuticals or dietary supplements. The compounds or compositions are administered to treat proliferative diseases, including various forms of cancer.

  本发明涉及一种新型木糖基糖苷化合物，其将木糖与一个含有多个芳香环的无糖基连接，其中连接方式为O-, S-或C-糖苷化。此外，还提供了包含这种新型木糖基糖苷化合物和非木糖基抗肿瘤药物、药品或膳食补充剂的组合物。这些化合物或组合物可用于治疗增殖性疾病，包括各种癌症。
• Liquid crystal molecule, liquid crystal display device and liquid crystal optical spatial modulation device
  申请人：Sony Corporation

  公开号：US07935395B2

  公开（公告）日：2011-05-03

  A liquid crystal molecule is disclosed, having a structure represented by the following general formula (1): wherein X1 is a group selected among groups represented by the following formula (2): X2 is represented by the following formula (3): R1 represents a linear or branched hydrocarbon group or an alkoxy group each having from 4 to 16 carbon atoms; R2 represents an optionally branched organosiloxane or organosilane having from 1 to 6 silicon atoms; other variables in formulae are defined therein.

  本发明涉及一种液晶分子，其结构由以下通式（1）表示：其中X1是从以下通式（2）表示的群中选择的群；X2由以下通式（3）表示；R1代表线性或支链烃基或具有4至16个碳原子的烷氧基；R2代表可选的分支有机硅氧烷或有机硅烷，其具有1至6个硅原子；公式中的其他变量在其中定义。
• Synthesis of Spiro Compounds through Tandem Oxidative Coupling and a Framework Rearrangement Reaction
  作者：Daisuke Sue、Takeo Kawabata、Takahiro Sasamori、Nobuhiro Tokitoh、Kazunori Tsubaki

  DOI：10.1021/ol902571p

  日期：2010.1.15

  A highly efficient oxidative coupling of 2-naphthols and a rearrangement tandem reaction to afford unique spiro compounds in the presence of FeCl3 center dot 6H(2)O In up to 88% yield have been developed.
• NEW COMPOSITIONS
  申请人：GLUCOGENE MEDICAL HFM AB

  公开号：EP1765363A2

  公开（公告）日：2007-03-28