[3-[[1-[2-[[3-(hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol | 865716-93-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [3-[[1-[2-[[3-(hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol
• CAS: 865716-93-4
• 化学式: C₃₆H₃₀O₄
• 分子量: 526.632
• InChiKey: BUKJTQXASQFHKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  58.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [3-[[1-[2-[[3-(hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol 在 三溴化磷 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 反应 124.0h， 生成
  参考文献：
  名称：

  Synthesis and structural characterization of chiral dicationic imidazolophanes

  摘要：

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.06.159
• 作为产物：
  描述：

  S-1,1'-联-2-萘酚 在 lithium aluminium tetrahydride 、 potassium carbonate 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 54.0h， 生成 [3-[[1-[2-[[3-(hydroxymethyl)phenyl]methoxy]naphthalen-1-yl]naphthalen-2-yl]oxymethyl]phenyl]methanol
  参考文献：
  名称：

  Synthesis and structural characterization of chiral dicationic imidazolophanes

  摘要：

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.06.159

文献信息

• Synthesis, complexation, and photoisomerization studies on some chiral monocyclic stilbenophanes and bis-cyclophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam

  DOI：10.1016/j.tet.2007.06.015

  日期：2007.9

  Various chiral stilbenophanes with small and large rigid cavities have been synthesized. Bis-cyclophanes with a stilbene-bridging unit have also been synthesized. Some of the stilbenophanes form charge transfer complexes with either TCNQ or TCNE. Photoisomerization of the bis-cyclophanes has also been studied.

  已经合成了具有小的和大的刚性腔的各种手性丁苯橡胶。具有二苯乙烯桥连单元的双环环烷也已经合成。某些芪甲酚与TCNQ或TCNE形成电荷转移络合物。还已经研究了双环烷的光异构化。
• Synthesis and structural characterization of chiral dicationic imidazolophanes
  作者：Perumal Rajakumar、Subramaniyan Selvam、Manickam Dhanasekaran

  DOI：10.1016/j.tetlet.2005.06.159

  日期：2005.9

  Various chiral dicationic benzimidazolophanes were obtained from optically pure (S)-BINOL, benzimidazole and a suitable aryl alkyl dibromide. (c) 2005 Elsevier Ltd. All rights reserved.