-phenylphosphinoxyd | 29865-25-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: -phenylphosphinoxyd
• 英文别名: (m-Chlorphenyl)-phenyl-phosphinoxid；Phenyl(m-chlorphenyl)phosphin-oxid；(m-Chlor-phenyl)-phenylphosphinoxyd
• CAS: 29865-25-6
• 化学式: C₁₂H₁₀ClOP
• 分子量: 236.638
• InChiKey: VKWQTTSSDAXXIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.85
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  1,2,3-噻唑(1,5-a)吡啶 、 -phenylphosphinoxyd 在 copper diacetate 作用下， 以 1,4-二氧六环 为溶剂， 反应 6.0h， 以85%的产率得到(3-chlorophenyl)(phenyl)(pyridin-2-ylmethyl)phosphine oxide
  参考文献：
  名称：

  乙酸铜（II）催化的吡啶并三唑与P（O）H化合物的脱氮C-P偶联合成磷酸化的吡啶

  摘要：

  吡啶三唑与P（O）H化合物的新型廉价铜催化脱氮C-P偶联反应已得到开发。该反应通过铜催化的P（O）-H插入由吡啶三唑原位生成的吡啶基卡宾中间体的过程进行。该反应为合成各种2-picolylphosphoryl化合物提供了一种新的有效方法。

  DOI：

  10.1002/adsc.201800909

文献信息

• Phosphinyl Guanidine Compounds, Metal Salt Complexes, Catalyst Systems, and Their Use to Oligomerize or Polymerize Olefins
  申请人：SYDORA Orson J.

  公开号：US20130331629A1

  公开（公告）日：2013-12-12

  The present application relates to N 2 -phosphinyl guanidine metal salt complexes. The present application also relates to catalyst systems comprising N 2 -phosphinyl guanidine metal salt complexes and processes for making catalyst systems comprising N 2 -phosphinyl guanidine metal salt complexes. The present application also relates to utilizing N 2 -phosphinyl guanidine metal salt complexes in processes of oligomerizing or polymerizing olefins.

  本申请涉及N2-磷酰亚胺基胍金属盐配合物。本申请还涉及包含N2-磷酰亚胺基胍金属盐配合物的催化剂体系以及制备包含N2-磷酰亚胺基胍金属盐配合物的催化剂体系的方法。本申请还涉及在烯烃的齐聚或聚合过程中利用N2-磷酰亚胺基胍金属盐配合物。
• Ph₃P-mediated highly selective C(α)–P coupling of quinone monoacetals with R₂P(O)H: convenient and practical synthesis of <i>ortho</i>-phosphinyl phenols
  作者：Ruwei Shen、Ming Zhang、Jing Xiao、Chao Dong、Li-Biao Han

  DOI：10.1039/c8gc02918k

  日期：——

  A highly selective Ph3P-mediated C(α)–P coupling reaction of quinone monoacetals with secondary phosphine oxides is developed to provide an effective method for the synthesis of a wide array of ortho-phosphinylphenols in good to excellent yields. This protocol can be adopted for scale-up synthesis directly from cheap and abundant phenols, and the products can be easily obtained in high yields by simple

  已开发出一种高选择性的Ph 3 P介导的醌单缩醛与仲氧化膦的C（α）-P偶联反应，为合成多种正膦基苯酚提供了一种有效的方法，收率好至极好。该方案可直接用于由廉价和丰富的苯酚进行大规模合成，并且无需使用有机萃取或色谱法即可通过简单的过滤轻松轻松地以高收率获得产物。
• Three‐Component Reaction of <i>p</i> ‐Quinone Monoacetals, Amines and Diarylphosphine Oxides to Afford <i>m‐</i> (Phosphinyl)anilides
  作者：Ruwei Shen、Xin Wang、Shunlin Zhang、Chao Dong、Dunru Zhu、Li‐Biao Han

  DOI：10.1002/adsc.201901421

  日期：2020.2.21

  The three‐component reaction of p‐quinone monoacetals, amines and diarylphosphine oxides is developed to afford m‐(diarylphosphinyl)anilides in moderate to high yields. The reaction may proceed via a process involving phospha‐nucleophilic addition to an iminoquinone acetal intermediate and/or carbonyl‐amine condensation with a phosphinyl enone intermediate.

  对苯二酚单缩醛，胺和二芳基膦氧化物的三组分反应得以发展，从而以中等至高收率提供了间二芳基膦基苯胺。该反应可以通过以下过程进行：将膦酰基亲核试剂加至亚氨基醌缩醛中间体和/或羰基胺与次膦酰基烯酮中间体的缩合反应。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• [EN] PHOSPHINYL FORMAMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS PHOSPHINYL FORMAMIDINE, COMPLEXES MÉTALLIQUES, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2015094207A1

  公开（公告）日：2015-06-25

  N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are described. Methods for making N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds and N2- phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物。还公开了制备N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物的方法。还公开了利用N2-磷酰基甲酰胺金属盐配合物的催化剂体系，以及利用N2-磷酰基胺化合物和N2-磷酰基胺金属盐配合物进行烯烃的寡聚和/或聚合的用途。