2-(2-vinyloxy-ethylamino)-ethanol | 13985-52-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(2-vinyloxy-ethylamino)-ethanol
• 英文别名: 2-(2-Vinyloxy-aethylamino)-aethanol；(2-Hydroxy-aethyl)-(2-vinyloxy-aethyl)-amin；2-Hydroxy-2'-vinyloxy-diaethylamin；<2-Hydroxy-ethyl>-<2-vinyloxy-ethyl>-amin；2-(2-Ethenoxyethylamino)ethanol
• CAS: 13985-52-9
• 化学式: C₆H₁₃NO₂
• mdl: MFCD19216976
• 分子量: 131.175
• InChiKey: VFWJIRZNZHAGOS-UHFFFAOYSA-N

物化性质

• 沸点：
  95 °C(Press: 4 Torr)
• 密度：
  1.007 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  9
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  41.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(2-vinyloxy-ethylamino)-ethanol 在 镍 作用下， 生成 2-(2-ethoxy-ethylamino)-ethanol
  参考文献：
  名称：

  Schostakowskii; Tschekulaewa, Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1954, p. 1111,1115;engl.Ausg.S.971,974

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙醇胺 、 乙炔 生成 2-(2-vinyloxy-ethylamino)-ethanol
  参考文献：
  名称：

  Synthesis and transformations of vinyl ethers of ethanolamines

  摘要：

  DOI：

  10.1007/bf00844408

文献信息

• Aqueous coating compositions
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0322188A1

  公开（公告）日：1989-06-28

  Aqueous coating compositions include an anionic species-scavenging system. The scavenging system includes an aqueous dispersion of water-insoluble, weak base-functional polymer particles. The particles are polymerized from monomer including a weak base-functional monomer such as 2-(diethylamino)ethyl methacrylate or 2-(t-butylamino)-ethyl methacrylate. A two stage process may be employed to prepare the particles and 2-(dimethylamino)-ethyl methacrylate may be included only in the initial stage. Alternatively, a single stage process may be employed using 2-(t-butylamino)methacrylate. The system also includes a volatile base such as ammonia to maintain the pH of the composition above the pKa of the weak base prior to and during application of the composition. As the volatile base is lost, the weak base is protonated and forms ion pairs with anionic species such as anionic surfactant. The compositions form coatings having good water resistance, and may be used as paints, paper coatings, caulking materials, adhesives, binders for non-woven products and for floor polishes and printing inks.

  水性涂料组合物包括阴离子物种清除系统。清除系统包括不溶于水的弱碱功能聚合物颗粒的水性分散体。这些微粒由单体聚合而成，单体包括弱碱官能团单体，如 2-(二乙基氨基)乙基甲基丙烯酸酯或 2-(叔丁基氨基)-乙基甲基丙烯酸酯。制备颗粒时可采用两阶段工艺，2-(二甲基氨基)-乙基甲基丙烯酸酯可仅用于初始阶段。另外，也可以使用 2-（叔丁氨基）甲基丙烯酸乙酯进行单阶段制备。该系统还包括挥发性碱（如氨），以便在使用组合物之前和使用期间将组合物的 pH 值保持在弱碱的 pKa 以上。随着挥发性碱的流失，弱碱被质子化，并与阴离子物质（如阴离子表面活性剂）形成离子对。这种组合物形成的涂料具有良好的耐水性，可用作油漆、纸张涂料、填缝剂、粘合剂、无纺布产品粘合剂以及地板抛光剂和印刷油墨。
• Cationic latex paint compositions
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0407085A2

  公开（公告）日：1991-01-09

  A paint composition comprising cationic latex polymeric binder, pigment and selective cationic pigment dispersant is disclosed. The paint compositions, which demonstrate the advantages of a water-­based system, also exhibit excellent stain blocking, corrosion resistance, water sensitivity resistance and adhesion to wood and alkyd surfaces which are competitive in performance with conventional solvent based alkyd primers.

  本发明公开了一种由阳离子乳胶聚合物粘合剂、颜料和选择性阳离子颜料分散剂组成的涂料组合物。这种涂料组合物展示了水性体系的优点，同时还具有优异的防污、耐腐蚀、耐水敏感性以及对木材和醇酸树脂表面的附着力，其性能与传统的溶剂型醇酸树脂底漆相比具有竞争力。
• Coating method, method for improving the scrub resistance and the adhesion to a substrate, lowering the minimum film formation temperature
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1234840A2

  公开（公告）日：2002-08-28

  A method for providing a coated substrate including: forming an aqueous coating composition including an aqueous emulsion polymer, the polymer having a glass transition temperature (Tg) from -60 °C to 80 °C, formed by the free radical polymerization of at least one ethylenically unsaturated nonionic acrylic monomer, 0.1-50%, by weight based on the total weight of the polymer, ethylenically unsaturated aldehyde reactive group-containing monomer, and 0-7.5%, by weight based on the total weight of the polymer, ethylenically unsaturated acid monomer in the presence of 0.01-1.0 %, by weight based on the total weight of the polymer, t-alkyl hydroperoxide, t-alkyl peroxide, or t-alkyl perester wherein the t-alkyl group includes at least 5 Carbon atoms; applying the aqueous coating composition to the substrate; and drying, or allowing to dry, the aqueous composition is provided. Also provided are a method for improving the scrub resistance of a coating, a method for lowering the minimum film formation temperature of an aqueous coating composition, and a method for improving the adhesion of a coating to a substrate.

  一种提供涂层基材的方法，包括：形成包括水性乳液聚合物的水性涂层组合物，该聚合物的玻璃化转变温度（Tg）为-60 °C至80 °C，由至少一种乙烯基不饱和非离子丙烯酸单体、0.1-50%（重量百分比）含乙烯基不饱和醛活性基团单体（基于聚合物总重量）和0-7.5%（以聚合物总重量为基准）的乙烯基不饱和酸单体，其中t-烷基包括至少5个碳原子；将水性涂料组合物涂到基材上；以及干燥或使水性组合物干燥。还提供了一种改善涂层耐擦洗性的方法、一种降低水性涂层组合物最低成膜温度的方法和一种改善涂层与底材附着力的方法。
• Improved coating and coating composition
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1245587A1

  公开（公告）日：2002-10-02

  Provided are improved coatings, polymeric dispersions, and polymeric composites, which include PNPs. Also provided are methods for forming improved coatings, polymeric dispersions, and polymeric composites, which include PNPs. The PNPs have polymerized units of at least one multi-ethylenically-unsaturated monomer have a mean diameter of from 1 to 50 nanometers. PNPs having polymerized units of at least one multi-ethylenically-unsaturated monomer and at least one surface-active monomer are also provided.

  本文提供了包括 PNPs 的改进型涂料、聚合物分散体和聚合物复合材料。此外，还提供了形成包括 PNPs 的改良涂层、聚合物分散体和聚合物复合材料的方法。PNPs 具有至少一种多乙烯不饱和单体的聚合单元，其平均直径为 1 至 50 纳米。此外，还提供具有至少一种多乙烯不饱和单体和至少一种表面活性单体聚合单元的 PNP。
• Aqueous polymer blend composition
  申请人：ROHM AND HAAS COMPANY

  公开号：EP1352924A1

  公开（公告）日：2003-10-15

  An aqueous polymer blend composition including a predominant amount of soft polymer particles and a minor amount of hard polymer particles is provided. The soft polymer particles contain, as copolymerized units, 70 to 99.7% by weight monoethylenically unsaturated (meth)acrylic monomer and from 0.3 to 10% by weight monoethylenically unsaturated acid monomer, based on weight of soft polymer particles. The soft polymer particles are made by a select process including redox polymerization or polymerization in the presence of excess unreacted monomer. The aqueous polymer blend composition is useful for preparing dry coatings having improved dirt pickup resistance and acceptable scrub resistance. A method is provided for preparing a dry coating from the aqueous polymer blend composition.

  本发明提供了一种水性聚合物混合物组合物，其中包括大量软聚合物颗粒和少量硬聚合物颗粒。软质聚合物颗粒含有 70%至 99.7%（按重量计）的单乙烯基不饱和（甲基）丙烯酸单体和 0.3%至 10%（按重量计）的单乙烯基不饱和酸单体（以软质聚合物颗粒的重量为基准）作为共聚单元。软聚合物颗粒是通过选择性工艺制成的，包括氧化还原聚合或在过量未反应单体存在下的聚合。水性聚合物混合物组合物可用于制备具有更好的抗污性和可接受的耐擦洗性的干涂层。提供了一种用含水聚合物共混组合物制备干涂层的方法。