1-溴-12-氟十二烷 | 353-29-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 中文名称: 1-溴-12-氟十二烷
• 英文名称: 1-bromo-12-fluoro-dodecane
• 英文别名: 1-Brom-12-fluor-dodecan；1-Bromo-12-fluorododecane
• CAS: 353-29-7
• 化学式: C₁₂H₂₄BrF
• 分子量: 267.225
• InChiKey: ODTDDHSZGZDGLM-UHFFFAOYSA-N

物化性质

• 沸点：
  85-86 °C(Press: 0.15 Torr)
• 密度：
  1.0993 (rough estimate)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  14
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-溴-12-氟十二烷 在 lithium aluminium tetrahydride 作用下， 以 乙醚 、 乙醇 为溶剂， 反应 3.5h， 生成 12-fluorododecane-1-thiol
  参考文献：
  名称：

  10.1021/jacs.4c05544

  摘要：

  DOI：

  10.1021/jacs.4c05544
• 作为产物：
  描述：

  12-氟十二烷-1-醇 在 三溴化磷 作用下， 生成 1-溴-12-氟十二烷
  参考文献：
  名称：

  Physical and Mechanical Properties of Pea-Protein-based Edible Films

  摘要：

  ABSTRACT: Edible films produced from denatured pea protein concentrate (PPC) solution possessed the strength and elasticity to resist handling. Increasing the concentration of the plasticizer (glycerol) in the film decreased tensile strength and elastic modulus, and increased elongation and water vapor permeability (WVP). Very strong and stretch‐able films were obtained from 70/30 and 60/40 of PPC/glycerol composition, respectively. The low WVP value was maintained over a range of glycerol concentration from 20% to 40%, in the dry film. Film solubility was not affected significantly by the amount of the plasticizer. The physical and mechanical properties of the PPC films were comparable with those of soy protein and whey protein films.

  DOI：

  10.1111/j.1365-2621.2001.tb11339.x

文献信息

• Attractant termiticidal compounds, compositions and methods of use therefor
  申请人：THE RESEARCH FOUNDATION OF STATE UNIVERSITY OF NEW YORK

  公开号：EP0104880A2

  公开（公告）日：1984-04-04

  Alpha - fluoro- omega - hydroxy straight chain hydrocarbons are utilized to form attractant termiticidal compositions which are safe and economical for the combatting of termites and related pests.

  α-氟-ω-羟基直链碳氢化合物可用于形成白蚁诱杀剂组合物，这种组合物在防治白蚁和相关害虫方面既安全又经济。
• Compound, photocurable composition, cured product of same, printing ink, and printed matter curing the printing ink
  申请人：DIC Corporation

  公开号：US11079675B2

  公开（公告）日：2021-08-03

  A novel compound is used as a novel photopolymerization initiator, the novel compound having a molecular structure represented by general formula 1 below [R1 represents an alkyl group having 1 to 10 carbon atoms, R2 represents an alkyl group having 1 to 12 carbon atoms or the like, R3 represents an alkyl group having 1 to 12 carbon atoms or the like, R4 to R7 each independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or the like, Y1 represents an alkyl group having 3 to 19 carbon atoms or the like, Y2 represents an organic linking group, X1 represents an ethylene group or the like, X2 and X3 each represent an ethylene group or the like, Y3 represents a single bond or an alkylidene group, and n represents an integer of 1 to 3].

  一种新型化合物被用作新型光聚合引发剂，该新型化合物的分子结构如下通式 1 所示 [R1 代表具有 1 至 10 个碳原子的烷基，R2 代表具有 1 至 12 个碳原子的烷基或类似物，R3 代表具有 1 至 12 个碳原子的烷基或类似物，R4 至 R7 各自独立地代表氢原子、具有 1 至 8 个碳原子的烷基或类似物、Y1 代表具有 3 至 19 个碳原子的烷基或类似基团，Y2 代表有机连接基团，X1 代表乙烯基或类似基团，X2 和 X3 各自代表乙烯基或类似基团，Y3 代表单键或亚烷基，n 代表 1 至 3 的整数]。
• NOVEL COMPOUND, PHOTOCURABLE COMPOSITION, CURED PRODUCT OF SAME, PRINTING INK, AND PRINTED MATTER SURING THE PRINTING INK
  申请人：DIC Corporation

  公开号：US20190137872A1

  公开（公告）日：2019-05-09

  A novel compound is used as a novel photopolymerization initiator, the novel compound having a molecular structure represented by general formula 1 below [R 1 represents an alkyl group having 1 to 10 carbon atoms, R 2 represents an alkyl group having 1 to 12 carbon atoms or the like, R 3 represents an alkyl group having 1 to 12 carbon atoms or the like, R 4 to R 7 each independently represent a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or the like, Y 1 represents an alkyl group having 3 to 19 carbon atoms or the like, Y 2 represents an organic linking group, X 1 represents an ethylene group or the like, X 2 and X 3 each represent an ethylene group or the like, Y 3 represents a single bond or an alkylidene group, and n represents an integer of 1 to 3].
• US4455441A
  申请人：——

  公开号：US4455441A

  公开（公告）日：1984-06-19
• [EN] PHOTOSENSITIVE RESIN COMPOSITION, CURED PRODUCT, INSULATING MATERIAL, RESIN MATERIAL FOR SOLDER RESISTS AND RESIST MEMBER<br/>[FR] COMPOSITION DE RÉSINE PHOTOSENSIBLE, OBJET DURCI, MATÉRIAU ISOLANT, MATÉRIAU DE RÉSINE POUR RÉSERVE DE SOUDURE, ET ÉLÉMENT DE SOUDURE<br/>[JA] 感光性樹脂組成物、硬化物、絶縁材料、ソルダーレジスト用樹脂材料及びレジスト部材
  申请人：DAINIPPON INK & CHEMICALS

  公开号：WO2019198490A1

  公开（公告）日：2019-10-17

  本発明は、酸基含有（メタ）アクリレート樹脂（Ａ）と、光重合開始剤（Ｂ）とを含有する感光性樹脂組成物であって、前記光重合開始剤（Ｂ）が、一般式（１）で表される化合物であることを特徴とする感光性樹脂組成物、前記感光性樹脂組成物の硬化反応物である硬化物、絶縁材料、ソルダーレジスト用樹脂材料及びレジスト部材を提供する。この感光性樹脂組成物は、高い光感度を有しており、耐熱性に優れ、かつアウトガスが生じにくい硬化物を形成することができる。