4-(11-tetrahydropyranyloxyundecyloxy)phenol | 201673-26-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-(11-tetrahydropyranyloxyundecyloxy)phenol
• 英文别名: 4-[11-(Oxan-2-yloxy)undecoxy]phenol
• CAS: 201673-26-9
• 化学式: C₂₂H₃₆O₄
• 分子量: 364.525
• InChiKey: IDJSXBFXFYXTMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  26
• 可旋转键数：
  14
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  47.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(11-tetrahydropyranyloxyundecyloxy)phenol 在 三正丁胺 、 四氯化锡 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 22.0h， 生成 8-(3-(11-tetrahydropyranyloxyundecyloxy)-6-hydroxyphenyl)-2-phenyl-4,7-diazocta-2,7-dien-1-al
  参考文献：
  名称：

  Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking

  摘要：

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.

  DOI：

  10.1080/15421400490436412
• 作为产物：
  描述：

  11-溴-1-十一醇 在 氢氧化钾 、 对甲苯磺酸 作用下， 以 乙醇 、 二氯甲烷 为溶剂， 反应 20.0h， 生成 4-(11-tetrahydropyranyloxyundecyloxy)phenol
  参考文献：
  名称：

  Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking

  摘要：

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.

  DOI：

  10.1080/15421400490436412

文献信息

• Block copolymer
  申请人：LG Chem, Ltd.

  公开号：US11299572B2

  公开（公告）日：2022-04-12

  The present application can provide a block copolymer and a use thereof. The block copolymer of the present application can have excellent self-assembly properties or phase separation characteristics and excellent etching selectivity, and various other functions as required can be freely imparted thereto.

  本申请可提供一种嵌段共聚物及其用途。本申请中的嵌段共聚物可具有优异的自组装性能或相分离特性以及优异的蚀刻选择性，还可根据需要自由赋予其各种其他功能。
• METAL-CONTAINING SIDE CHAIN LIQUID CRYSTAL POLYMERS
  申请人：QinetiQ Limited

  公开号：EP0927155B1

  公开（公告）日：2002-11-20
• Block Copolymer
  申请人：LG Chem, Ltd.

  公开号：US20200131296A1

  公开（公告）日：2020-04-30

  The present application can provide a block copolymer and a use thereof. The block copolymer of the present application can have excellent self-assembly properties or phase separation characteristics and excellent etching selectivity, and various other functions as required can be freely imparted thereto.
• US6184322B1
  申请人：——

  公开号：US6184322B1

  公开（公告）日：2001-02-06
• Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking
  作者：Peter Styring、Isabel Saez

  DOI：10.1080/15421400490436412

  日期：2004.1

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.