1,3-二甲基-2,5-二氢-1H-磷杂环戊二烯1-氧化物 | 15450-79-0

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 中文名称: 1,3-二甲基-2,5-二氢-1H-磷杂环戊二烯1-氧化物
• 英文名称: 1,3-dimethyl-3-phospholene 1-oxide
• 英文别名: 1-oxo-1,3-dimethylphosphol-3-ene；1,3-dimethyl-2,5-dihydro-1H-phosphole 1-oxide；1,3-dimethyl-2,5-dihydro-1H-phosphole-1-oxide；1,3-dimethyl-3-phospholene-1-oxide；1,3-dimethyl-3-phospholene oxide；Oxid von 1,3-Dimethyl-3-phospholen-1；1H-Phosphole, 2,5-dihydro-1,3-dimethyl-, 1-oxide；1,3-dimethyl-2,5-dihydro-1λ5-phosphole 1-oxide
• CAS: 15450-79-0
• 化学式: C₆H₁₁OP
• 分子量: 130.126
• InChiKey: IAWDXWMSIQOZTQ-UHFFFAOYSA-N

物化性质

• 沸点：
  277.7±20.0 °C(Predicted)
• 密度：
  1.01±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3-二甲基-2,5-二氢-1H-磷杂环戊二烯1-氧化物 在 potassium carbonate 作用下， 以 叔丁醇 为溶剂， 生成 1,4-Dimethyl-3-methoxycarbonyl-3-phospholen-1-oxid
  参考文献：
  名称：

  Synthesis and spectral characterization of some C-alkylphospholes and phospholecarboxylates

  摘要：

  DOI：

  10.1021/jo00950a018
• 作为产物：
  描述：

  1,3-dimethyl-1-methylsulfanyl-2,5-dihydrophosphol-1-ium;chloride 在 水 作用下， 生成 1,3-二甲基-2,5-二氢-1H-磷杂环戊二烯1-氧化物
  参考文献：
  名称：

  Apitz, Joerg; Grobe, Joseph; Le Van, Duc, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1988, vol. 43, # 3, p. 257 - 260

  摘要：

  DOI：
• 作为试剂：
  描述：

  (S)-(+)-α-(diethoxyphosphonyl)benzyl isocyanate 在 1,3-二甲基-2,5-二氢-1H-磷杂环戊二烯1-氧化物 作用下， 以 甲苯 为溶剂， 反应 2.0h， 以95%的产率得到(SS)-(-)-N,N'-bis<α-(diethoxyphosphonyl)benzyl>carbodiimide
  参考文献：
  名称：

  Kozhushko, B. N.; Lomakina, A. V.; Paliichuk, Yu. A., Journal of general chemistry of the USSR, 1983, vol. 53, # 9, p. 1768 - 1774

  摘要：

  DOI：

文献信息

• Macrocyclic carbodiimides (MC-CDI) and their derivatives, syntheses and applications of the same
  申请人：Dai Shenghong A.

  公开号：US20080161554A1

  公开（公告）日：2008-07-03

  Disclosed are a macrocyclic carbodiimide (MC-CDI) and a process for synthesizing the same through condensation of a molecule with multiple-isocyanate terminal functional groups under high dilution in the presence of a phospholene catalyst such as phospholene or arsenic catalyst. Also disclosed are MC-CDI derivatives, such as MC-urea (MC-U), MC-acylurea (MC-ACU), acid functionalized MC-ACU, and anhydride functionalized MC-ACU, processes for synthesizing the same, and the applications of such derivatives as hydrolysis stabilizers in organic polymeric materials, such as polyurethane (PU) and polyesters, as well as the applications in the syntheses of the amide- and imide-modified polyurethane by ring-opening reaction of the MC-ACU.

  本文披露了一种大环碳二亚胺（MC-CDI）及其合成方法，通过在高稀释条件下，在磷烯或砷催化剂的存在下，将具有多个异氰酸酯末端官能基的分子进行缩合反应来合成MC-CDI。还披露了MC-CDI衍生物，如MC-脲（MC-U）、MC-酰脲（MC-ACU）、酸官能化的MC-ACU和酐官能化的MC-ACU，以及其合成方法，以及这些衍生物作为有机聚合材料（如聚氨酯（PU）和聚酯）中的水解稳定剂的应用，以及在通过MC-ACU的环开反应合成酰胺和亚酰胺改性聚氨酯的合成中的应用。
• Continous solvent-free process for thermoplastic polyamides and polyester amides
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0104381A2

  公开（公告）日：1984-04-04

  A continuous, solvent-free process is described for the preparation of thermoplastic polyamides and polyesteramides by the reaction of the appropriate organic diisocyanate and dicarboxylic acid or difunctional carboxylic acid-terminated polyester.

  描述了一种通过适当的有机二异氰酸酯和二羧酸或双官能团羧酸封端聚酯反应制备热塑性聚酰胺和聚酯酰胺的连续无溶剂工艺。
• Blends of aromatic-aliphatic polyamides and impact modifiers
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0154037A2

  公开（公告）日：1985-09-11

  Blends are provided of (a) certain aromatic-aliphatic polyamides and (b) an impact resistance-enhancing amount of a particulate rubbery impact modifier.

  混合物包括：(a) 某些芳香-脂肪族聚酰胺；(b) 抗冲击性增强型微粒橡胶抗冲击改性剂。
• Polyamide resins with good toughness
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0355718A1

  公开（公告）日：1990-02-28

  Disclosed is a novel class of linear segmented non-elastomeric thermoplastic polyesteramides. The polymers are easily obtained by reacting a carboxylic acid-terminated prepolymer (derived by reacting at least a two-molar proportion of a dicarboxylic acid with a polymeric diol of molecular weight 400 to 6000) with a dicarboxylic acid and a diisocyanate. The polymers so obtained have nylon-like prop­erties, particularly nylon 11 or 12, but are distinguished from these nylons by superior high temperature properties. At the same time, they have excellent toughness and low water absorption characteristics.

  本发明公开了一类新型线性分段非弹性热塑性聚酯酰胺。将羧酸封端预聚物（通过至少二摩尔比例的二羧酸与分子量为 400-6000 的聚合二元醇反应制得）与二羧酸和二异氰酸酯反应，可轻松获得这种聚合物。 这样得到的聚合物具有类似尼龙的特性，特别是尼龙 11 或 12，但与这些尼龙的区别在于其优异的高温特性。同时，它们还具有出色的韧性和低吸水性。
• LIGHT COLOR MODIFIED ISOCYANATE MIXTURE AND PREPARATION METHOD THEREFOR
  申请人：Wanhua Chemical Group Co., Ltd.

  公开号：EP3699169A1

  公开（公告）日：2020-08-26

  Disclosed is a light colored modified isocyanate mixture and a preparation method thereof. The method comprises the following steps: a) reacting isocyanate groups of a raw material isocyanate under the action of a phospholenecatalyst, and finally obtaining a modified isocyanate reaction solution containing carbodiimide and/or uretonimine derivatives; and b) adding a compounded terminator of a halosilane organic and a sulfonic anhydride to the reaction solution obtained in step a so as to terminate the reaction of carbodiimidization. The modified isocyanate prepared by the method has the characteristics of a liquid state at room temperature, being stable in storage at room temperature and high temperature, and low color number.

  本发明公开了一种浅色改性异氰酸酯混合物及其制备方法。该方法包括以下步骤：a) 在磷烯催化剂的作用下，使原料异氰酸酯的异氰酸酯基团发生反应，最终得到含有碳二亚胺和/或脲亚胺衍生物的改性异氰酸酯反应液；b) 在步骤 a 中得到的反应液中加入卤代硅烷有机物和磺酸酐的复合终止剂，以终止碳二亚胺化反应。该方法制备的改性异氰酸酯具有室温下呈液态、在室温和高温下储存稳定、色号低等特点。