chlorobis(N-octyl-5-bromosalicylideneaminato)manganese(III) | 86916-20-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chlorobis(N-octyl-5-bromosalicylideneaminato)manganese(III)
• 英文别名: Mn(III)(N-(5-bromosalicylidene)-octylamine(1-))2Cl
• CAS: 86916-20-3
• 化学式: C₃₀H₄₂Br₂ClMnN₂O₂
• 分子量: 712.875
• InChiKey: YVCVVICGECXVQT-JSMUNIHWSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chlorobis(N-octyl-5-bromosalicylideneaminato)manganese(III) 在 hydrochloric acid 作用下， 以 异丙醇 为溶剂， 生成 dichlorobis(N-octyl-5-bromosalicylideneaminato)manganese(IV)
  参考文献：
  名称：

  Preparation and characterization of dichlorobis(N-alkyl-substituted salicylideneaminato)manganese(IV) complexes

  摘要：

  DOI：

  10.1016/s0277-5387(00)81520-x
• 作为产物：
  描述：

  N-(5-bromosalicylidene)octylamine 、 manganese(III) triacetate dihydrate 在 LiCl 作用下， 以 乙醇 为溶剂， 生成 chlorobis(N-octyl-5-bromosalicylideneaminato)manganese(III)
  参考文献：
  名称：

  Preparation and characterization of dichlorobis(N-alkyl-substituted salicylideneaminato)manganese(IV) complexes

  摘要：

  DOI：

  10.1016/s0277-5387(00)81520-x

文献信息

• Effects of chloride ions on electrochemical reactions of manganese(III) complexes
  作者：Megumi Kasuno、Masaki Hayano、Manabu Fujiwara、Takayuki Matsushita

  DOI：10.1016/j.poly.2008.10.073

  日期：2009.2

  Electrochemical reactions of manganese(III) complexes, Mn-III(L)X (L; salen, salpn, 5-NO2-salen or 5-NO2-salpn, X; Cl, Br or NO2) and Mn-III(L')(2)X (L': N-Bu-sal, N-Oct-sal, N-Oct-5-Br-sal or N-Oct-5-NO2-sal, X; Cl or Br), were investigated by voltammetry at a glassy carbon electrode in the absence/presence of Cl- in acetonitrile solution. By the addition of Cl-, oxidation processes of Mn-III(L)X and Mn-III(L')(2)X have been found to be improved from quasi-reversible to reversible, and their oxidation products, [Mn-IV(L)X](+) and [Mn-IV(L')(2)X](+), were stabilized by the combination with Cl- resulting in [Mn-IV(L)Cl-2] and [Mn-IV(L')(2)Cl-2], respectively. On the other hand, the reduction processes of Mn-III(L)X and Mn-III(L')(2)Cl were not so significantly affected by Cl- as those observed for their oxidation. Other types of manganese(III) complexes and iron(III) complex were also investigated. The present Study may clarify the role of Cl- being involved in OEC (oxygen-evolving center) in photosystem II. (C) 2008 Elsevier Ltd. All rights reserved.