tetraphenylarsonium dicyanamide | 16566-19-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetraphenylarsonium dicyanamide
• CAS: 16566-19-1
• 化学式: C₂N₃*C₂₄H₂₀As
• 分子量: 449.387
• InChiKey: DXZZBPNYNGQOED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.39
• 重原子数：
  30.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.68
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  tetraphenylarsonium dicyanamide 、 银二氰胺 以 乙腈 为溶剂， 以40-45的产率得到tetraphenylarsonium tris(dicyanamido)argentate(I)
  参考文献：
  名称：

  Koehler, Helmut; Jeschke, Manuela; Kolbe, Alfred, Zeitschrift für Chemie, 1985, vol. 25, p. 340 - 341

  摘要：

  DOI：

文献信息

• Structure and magnetism of anionic dicyanamidometallate extended networks of types (Ph4As)[MII(dca)3] and (Ph4As)2[M2II(dca)6(H2O)]·H2O·xCH3OH, where dca=N(CN)2− and MII=Co, Ni
  作者：Patricia M van der Werff、Stuart R Batten、Paul Jensen、Boujemaa Moubaraki、Keith S Murray、Emily H.-K Tan

  DOI：10.1016/s0277-5387(01)00584-8

  日期：2001.5

  Anionic metal tris-dicyanamide complexes of type (Ph4As)[M(dca)(3)], where M = Co(II) and Ni(II) have been synthesised and characterised by X-ray crystallography, powder diffraction and derailed magnetic measurements. The anions form extended sheets with (4,4) connectivity and octahedral geometry about individual d-block ions. The cations lie in between the sheets and display cation-cation interactions of the pi...pi and 'multiple phenyl embrace' types. The nickel(II) complex, (Ph4As)[Ni(dca)(3)], displays long-range magnetic order, with an ordering temperature of 20.1 K. (Ph4As)[Co(dca)(3)], in contrast, did not show long-range order, but did show unusual field dependence of the magnetic moments at temperatures below 20 K. The syntheses also yield a second, needle-shaped product, (Ph4As)(2)[M-2(dca)(6)(H2O)].H2O . xCH(3)OH, which could be separated. They are isostructural and contain ladder-like 1D polymers which are cross-linked by hydrogen bonding into sheets; these sheets are separated by layers of cations. The cation layers again show multiple phenyl embraces and other supramolecular interactions. Magnetic studies on these hydrate-methanolate species show that they do not display long range order but, rather, very weak coupling. (C) 2001 Elsevier Science Ltd. All rights reserved.
• Koehler, H.; Nefedov, V. I.; Birkner, G., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Koehler, H.、Nefedov, V. I.、Birkner, G.、Jeschke, M.、Kolbe, A.

  DOI：——

  日期：——