μ-[2,3,5,6-tetra(2-pyridyl)pyrazine]-bis[bis(acetato)aquanickel(II)]-formaldehyde (1/1) | 214266-23-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: μ-[2,3,5,6-tetra(2-pyridyl)pyrazine]-bis[bis(acetato)aquanickel(II)]-formaldehyde (1/1)
• CAS: 214266-23-6
• 化学式: CH₂O*C₃₂H₃₂N₆Ni₂O₁₀
• 分子量: 808.047
• InChiKey: NMFHPYQNFYURBQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四-2-吡啶基吡嗪 、 nickel(II) acetate tetrahydrate 以 N,N-二甲基甲酰胺 为溶剂， 生成 μ-[2,3,5,6-tetra(2-pyridyl)pyrazine]-bis[bis(acetato)aquanickel(II)]-formaldehyde (1/1)
  参考文献：
  名称：

  Structural Investigation of Nickel(II) Complexes. XIII. μ-[2,3,5,6-Tetra-(2-pyridyl)pyrazine]-bis-[bis(acetato)aquanickel(II)]–Formaldehyde (1/1)

  摘要：

  In the title compound, [Ni-2(C2H3O2)(4)(C24H16N6)(H2O)(2)].CH2O, the coordination polyhedron of each Ni-II centre is a distorted octahedron formed by three N-atom donors from a tetra(2-pyridyl)pyrazine molecule and an aqua O atom in the equatorial positions, and by two O atoms from different acetate anions in the axial positions. The formaldehyde molecule is not coordinated; it is disordered over two sites related by a crystallographic twofold axis.

  DOI：

  10.1107/s0108270198003631