dichlorotetrakis(methyldiphenylphosphine)ruthenium(II) | 81704-54-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dichlorotetrakis(methyldiphenylphosphine)ruthenium(II)
• 英文别名: RuCl2(PMePh2)4；dichlororuthenium;methyl(diphenyl)phosphane
• CAS: 81704-54-3；49695-05-8
• 化学式: C₅₂H₅₂Cl₂P₄Ru
• 分子量: 972.856
• InChiKey: KJRHVZYQBXSMLF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  12.37
• 重原子数：
  59.0
• 可旋转键数：
  12.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  dichlorotetrakis(methyldiphenylphosphine)ruthenium(II) 、 1-(2-methylpyridyl)-1,4,7-triazacyclononane 以 甲苯 为溶剂， 以84%的产率得到[chloro(methyldiphenylphosphine)(κ4-1-(2-methylpyridyl)-1,4,7-triazacyclononane)ruthenium(II)]chloride
  参考文献：
  名称：

  Formation and structural studies of iron(III) and ruthenium(II) complexes of 1,4,7-triazacyclononane and N-monofunctionalised 1,4,7-triazacyclononane

  摘要：

  A series of 1,4,7-triazacyclononane derivatives of Fe(III) and Ru(II) have been investigated. The objective of this work was to investigate the effect of changing the functionality of a pendant group in order to create different Ru(II) and Fe(III) environments. From these studies, some interesting features are elucidated and different stacking properties arise due to the intra- and intermolecular X-(HCl)-Cl-... (X = O, N) interactions for the Fe(III) and Ru(II) complexes. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.07.002

文献信息

• Facile δ-hydrogen abstraction from a ruthenium complex; possible 1–4η-bonding of the o-xylylene ligand
  作者：S. David Chappell、David J. Cole-Hamilton

  DOI：10.1039/c39810000319

  日期：——

  RuCl2L4(L = PMe2Ph or PMePh2) with o-MeC6H4CH2MgBr in diethyl ether at room temperature leads to R[graphic omitted]H2)L3, whose spectroscopic and chemical characteristics suggest a possible 1–4η-bonding of the o-xylylene ligand.

  室温下，RuCl 2 L 4（L = PMe 2 Ph或PMePh 2）与邻-MeC 6 H 4 CH 2 MgBr在乙醚中的反应导致R [H 2）L 3的光谱和化学特性提供一个可能的1-4 η η-键接的Ó -xylylene配体。
• Teixidor, Francesc; Ayllón, José A.; Viñas, Clara, Organometallics, 1994, vol. 13, # 7, p. 2751 - 2760
  作者：Teixidor, Francesc、Ayllón, José A.、Viñas, Clara、Kivekäs, Raikko、Sillanpää, Reijo、Casabó, Jaume

  DOI：——

  日期：——
• Naphthoquinodimethane complexes of ruthenium(O)
  作者：Nigel J. Simpson、David J. Cole-Hamilton

  DOI：10.1016/s0277-5387(00)80709-3

  日期：1988.1
• Simpson, Nigel J.; Cole-Hamilton, David J., Journal of the Chemical Society, Dalton Transactions
  作者：Simpson, Nigel J.、Cole-Hamilton, David J.

  DOI：——

  日期：——
• Chappell, S. David; Cole-Hamilton, David J.; Galas, Anita M.R., Journal of the Chemical Society, Dalton Transactions, 1982, p. 1867 - 1872
  作者：Chappell, S. David、Cole-Hamilton, David J.、Galas, Anita M.R.、Hursthouse, Michael B.

  DOI：——

  日期：——