2,2-dimethylpropyl-[2-[[6-[[2-(2,2-dimethylpropylazanidyl)phenyl]azanidylmethyl]pyridin-2-yl]methylazanidyl]phenyl]azanide;oxygen(2-);tin(2+) | 1021903-64-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2,2-dimethylpropyl-[2-[[6-[[2-(2,2-dimethylpropylazanidyl)phenyl]azanidylmethyl]pyridin-2-yl]methylazanidyl]phenyl]azanide;oxygen(2-);tin(2+)
• CAS: 1021903-64-9
• 化学式: C₂₉H₃₇N₅OSn₃
• 分子量: 827.776
• InChiKey: JHQFUXUVYNLHFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.33
• 重原子数：
  38
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  17.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-N-(2,2-dimethylpropyl)-1-N-[[6-[[2-(2,2-dimethylpropylamino)anilino]methyl]pyridin-2-yl]methyl]benzene-1,2-diamine 以 not given 为溶剂， 生成 2,2-dimethylpropyl-[2-[[6-[[2-(2,2-dimethylpropylazanidyl)phenyl]azanidylmethyl]pyridin-2-yl]methylazanidyl]phenyl]azanide;oxygen(2-);tin(2+)
  参考文献：
  名称：

  Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene

  摘要：

  The reaction of the benzannulated bisstannylene ligand 2 with Sn = O or Pb = O generated in situ gave the pincer complexes 3 and 4. Both complexes have been characterized by X-ray diffraction and multinuclear NMR spectroscopy. A divalent state has been found by Mossbauer spectroscopy for the tin atoms in complexes 3 and 4.

  DOI：

  10.1021/ja801000b