N-Allylmonoaza-15-crown-5 | 69978-50-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-Allylmonoaza-15-crown-5
• 英文别名: N-allyl-4-aza-15-crown-5；N-Allylaza-15-crown-5；13-allyl-1,4,7,10-tetraoxa-13-aza-cyclopentadecane；13-Prop-2-enyl-1,4,7,10-tetraoxa-13-azacyclopentadecane
• CAS: 69978-50-3
• 化学式: C₁₃H₂₅NO₄
• 分子量: 259.346
• InChiKey: YLVVBENHVUBDBL-UHFFFAOYSA-N

物化性质

• 沸点：
  364.2±37.0 °C(Predicted)
• 密度：
  0.958±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  N-Allylmonoaza-15-crown-5 在 sodium 作用下， 以 甲醇 、 水 为溶剂， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Lariat ethers. 3. Macrocylic polyethers bearing donor groups on flexible arms attached at a nitrogen pivot point

  摘要：

  DOI：

  10.1016/s0040-4039(01)92953-3
• 作为产物：
  描述：

  9-allyl-3,6,12-trioxa-9-aza-tetradecane-1,14-diol 在 sodium hydroxide 、 对甲苯磺酰氯 作用下， 以 1,4-二氧六环 为溶剂， 生成 N-Allylmonoaza-15-crown-5
  参考文献：
  名称：

  N-烷基单氮杂冠醚的新合成

  摘要：

  DOI：

  10.1016/s0040-4039(01)95200-1

文献信息

• 12-, 15-, and 18-Membered-ring nitrogen-pivot lariat ethers: syntheses, properties, and sodium and ammonium cation binding properties
  作者：Rose Ann Schultz、Banita D. White、Dennis M. Dishong、Kristin A. Arnold、George W. Gokel

  DOI：10.1021/ja00309a039

  日期：1985.11

  Preparation de pres de 50 ethers lariat par cyclisation d'une amine ou d'un diol convenablement substitue. Formation de complexes avec lesions Na et NH 4

  制备 de pres de 50 ethers lariat par cyclisation d'une amine ou d'un diol convenablement substitue。形成复合物 avec 病变 Na et NH 4
• C-Donor lariat ether ‘scorpionates’
  作者：Pious Arya、Asif Channa、Peter J. Cragg、Paul D. Prince、Jonathan W. Steed

  DOI：10.1039/b108522k

  日期：2002.4.2

  Structural studies on a range of Ag+ and Pb2+ complexes of N-allyl and N-butenyl lariat ethers are reported. In the case of smaller ligands with allyl side arms (L=N-allylaza-15-crown-5 and N-azaallyl-18-crown-6), coordination polymers of type [Ag(L)]+∞ exhibiting Ag+⋯π interactions are observed. Increasing the length of the side arm to N-butenylaza-18-crown-6 gives a monomeric ‘scorpionate’ species

  报道了对N-烯丙基和N-丁烯基套索状醚的一系列Ag +和Pb 2+配合物的结构研究。在具有烯丙基侧臂的较小配体的情况下（L = N -allylaza-15-crown-5和N -azaallyl-18-crown-6），[Ag（L）] + ∞类型的配位聚合物显示Ag + ⋯观察到π相互作用。将侧臂的长度增加至N-丁烯氮杂18-冠-6，可得到单体的“蝎形”物质，其中Ag +离子同时与单个配体的大环部分和侧臂结合。NMR滴定结果表明，Ag+ ⋯π相互作用持续存在于溶液中。在Pb 2+配合物的情况下，在任何情况下均未观察到侧臂受累。还报道了新型的质子化复合物（H 3 O）（ N -allylaza-18-crown-6）[Cu 2 I 3 ]。
• Formation of an organometallic coordination polymer from the reaction of silver(I) with a non-complimentary lariat ether
  作者：Paul D. Prince、Jonathan W. Steed、Peter J. Cragg

  DOI：10.1039/a900252i

  日期：——

  The ‘AgI(15-crown-5)’ core moiety is a versatile supramolecular synthon, which is able to satisfy its coordination requirements using a variety of capping ligands; in the presence of the lariat ether N-allylaza-15-crown-5 an infinite organometallic coordination polymer is formed.

  “AgI(15-crown-5)”核心部分是一种多功能超分子合成子，能够使用各种封端配体满足其配位要求；在套索醚 N-allylaza-15-crown-5 存在下，形成无限有机金属配位聚合物。
• Synthesis of azacrown ethers modified with side-chains containing germanium
  作者：Ryoko Suzuki、Takashi Matsumoto、Katsumi Tanaka、Yoshito Takeuchi、Tamotsu Taketomi

  DOI：10.1016/s0022-328x(01)01054-3

  日期：2001.11

  The reaction between ethanolamine (4) and tri- or tetraethylene tosylate (5) and (13) gave 9- and 12-membered monoazacrowns with a -CH2CH2OH residue on nitrogen, A-OH and B-OH, together with 18- and 24-membered diazacrown ethers with the same substituent on nitrogen, E-OH and F-OH. If 2-(2-aminoethoxy)ethanol (12) was used in the reaction described above, instead of 4, the final products, G-OH and H-OH, and K-OH and L-OH, have a longer side chain, -CH2CH2OCH2CH2OH, on nitrogen (Route 1). A series of reactions involving bromoethanol (6) and diethanolamine (9) formed, with 5 or 13, 18- and 24-membered monoazacrowns with the shorter substituent as described above, a 15-membered monoazacrown ether C-OH and an 18-membered D-OH. If 2-(2-chloroethoxy)ethanol (14) is used instead of 6, I-OH and J-OH are obtained (Route 2'). All these hydroxy azacrown ethers were made to react with 3-trimethylgermylpropionic acid (18) to give the corresponding germanium-containing A-L. A preliminary investigation was carried out on the cation transport capability of these germanium-containing azacrown ethers to observe whether germanium might enhance their cation transporting capability. (C) 2001 Published by Elsevier Science B.V.
• KUO P.; MIKI M.; IKEDA I.; OKAHARA M., TETRAHEDRON LETT., 1978, NO 44, 4273-4276
  作者：KUO P.、 MIKI M.、 IKEDA I.、 OKAHARA M.

  DOI：——

  日期：——