(C5H3N)(CH2(C6H4N2Sn)CH2tBu)2 | 1021903-62-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (C5H3N)(CH2(C6H4N2Sn)CH2tBu)2
• CAS: 1021903-62-7
• 化学式: C₂₉H₃₇N₅Sn₂
• 分子量: 693.066
• InChiKey: GGSIAFLZUHCTQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (C5H3N)(CH2(C6H4N2Sn)CH2tBu)2 、 水 以 not given 为溶剂， 以28%的产率得到2,2-dimethylpropyl-[2-[[6-[[2-(2,2-dimethylpropylazanidyl)phenyl]azanidylmethyl]pyridin-2-yl]methylazanidyl]phenyl]azanide;oxygen(2-);tin(2+)
  参考文献：
  名称：

  Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene

  摘要：

  The reaction of the benzannulated bisstannylene ligand 2 with Sn = O or Pb = O generated in situ gave the pincer complexes 3 and 4. Both complexes have been characterized by X-ray diffraction and multinuclear NMR spectroscopy. A divalent state has been found by Mossbauer spectroscopy for the tin atoms in complexes 3 and 4.

  DOI：

  10.1021/ja801000b
• 作为产物：
  描述：

  2-N-(2,2-dimethylpropyl)-1-N-[[6-[[2-(2,2-dimethylpropylamino)anilino]methyl]pyridin-2-yl]methyl]benzene-1,2-diamine 、 bis(bis(trimethylsilyl)amido)tin(II) 以 not given 为溶剂， 生成 (C5H3N)(CH2(C6H4N2Sn)CH2tBu)2
  参考文献：
  名称：

  Trapping of Tin(II) and Lead(II) Homologues of Carbon Monoxide by a Benzannulated Lutidine-Bridged Bisstannylene

  摘要：

  The reaction of the benzannulated bisstannylene ligand 2 with Sn = O or Pb = O generated in situ gave the pincer complexes 3 and 4. Both complexes have been characterized by X-ray diffraction and multinuclear NMR spectroscopy. A divalent state has been found by Mossbauer spectroscopy for the tin atoms in complexes 3 and 4.

  DOI：

  10.1021/ja801000b

文献信息

• Mono‐ and Bidentate Benzannulated N‐Heterocyclic Germylenes, Stannylenes and Plumbylenes
  作者：Alexander V. Zabula、F. Ekkehardt Hahn

  DOI：10.1002/ejic.200800866

  日期：2008.11

  of mono- and bidentate N-heterocyclic germylenes, stannylenes, plumbylenes, and related compounds is reviewed with special emphasis placed on benzannulated derivatives. The preparation, electronic structure, aggregation behaviour, and the coordination chemistry of the free benzannulated carbene analogues and their adducts with Lewis bases and complexes with transition metals are discussed. (© Wiley-VCH

  回顾了单齿和双齿 N-杂环亚锗烯、亚锡、亚铅和相关化合物的化学现状，特别强调了苯并环化衍生物。讨论了游离的苯并环化卡宾类似物及其与路易斯碱和过渡金属配合物的加合物的制备、电子结构、聚集行为和配位化学。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)