cis-[(2,2':6',2''-terpyridine)(Cl)2nitridoosmium(VI)] | 127571-47-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: cis-[(2,2':6',2''-terpyridine)(Cl)2nitridoosmium(VI)]
• 英文别名: cis-[Os(VI)(2,2':6',2''-terpyridine)(Cl)2(N)](1+)；cis-[Os(IV)(2,2':6,2''-terpyridine)(Cl)2(N)](1+)；cis-[Os(2,2':6',2''-terpyridine)(N)Cl2](1+)；cis-Os(2,2'-6',2''-terpyridine)(N)Cl2(1+)；cis-[Os(VI)(terpyridine)(Cl)2(N)](1+)；mer-[Os(2,2':6',2''-terpyridine)NCl2](1+)；trans-[(2,2':6',2''-terpyridine)(Cl)2nitridoosmium(VI)]；trans-[Os(VI)(2,2':6',2''-terpyridine)(Cl)2(N)](1+)；trans-[Os(VI)(2,2':6',2''-terpyridine)(Cl)2(N)](+)；trans-Os(2,2':6',2''-terpyridine)(N)Cl2(1+)；trans-[Os(VI)(terpyridine)(Cl)2(N)](1+)
• CAS: 127571-47-5；159248-16-5
• 化学式: C₁₅H₁₁Cl₂N₄Os
• 分子量: 508.385
• InChiKey: FYAJUOZTRZCNHK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-[(2,2':6',2''-terpyridine)(Cl)2nitridoosmium(VI)] 在 HCl 作用下， 以 水 为溶剂， 以44.5%的产率得到{osmiumnitrido(chloro)2(η3-2,2':6',2''-terpyridine)}chloride*H2O
  参考文献：
  名称：

  Ware, David C.; Taube, Henry, Inorganic Chemistry, 1991, vol. 30, # 24, p. 4598 - 4605

  摘要：

  DOI：

文献信息

• Isolation and Characterization of the Osmium(V)–Imido Complex [OsV(Tp)(Cl)2(NH)] We are grateful to the National Science Foundation under Grant number CHE-9503738, the Los Alamos National Laboratory (DOE) under Grant Number 10730-001-00-2C, and the Laboratory Directed Research and Development Program for support of this research. M. H. V. Huynh gratefully acknowledges postdoctoral fellowship support from the Directorapos;s Office of Los Alamos National Laboratory. Los Alamos National Laboratory is operated by the University of California for the U.S. Department of Energy under Contract W-7405-ENG-36. We also thank Dr. Paul R. Sharp (Professor of Chemistry, University of Missouri, Columbia, MO, 65211) for the information on transition metal parent imido complexes.
  作者：My Hang V. Huynh、Peter S. White、Kevin D. John、Thomas J. Meyer

  DOI：10.1002/1521-3773(20011105)40:21<4049::aid-anie4049>3.0.co;2-w

  日期：2001.11.5

  Trapped by a proton: In the formation of OsII -N2 -OsII dimers, an OsV ≡N complex has been invoked as a transient intermediate but not isolated. Herein conditions are reported that allow OsV ≡N species to be trapped either in acidic, aqueous solutions as a neutral osmium(V) imido complex (OsV =NH, see structure) or in non-aqueous solvents, with high concentrations of added reductant, by N- ion transfer

  通过质子捕获：在O的形成II -N 2 -OS II二聚体，一OS V ≡N复杂已被调用作为瞬时中间但不分离。本文条件报告，其允许锇V ≡N物种对酸性，水溶液或者被俘获作为中性锇（V）亚氨基配合物（OS V = NH，见结构），或在非水溶剂中，用高浓度的加入还原剂，用N -离子转移之前，可能会发生耦合。
• Demadis, Konstantinos; El-Samanody, El-Sayed; Meyer, Thomas J., Inorganic Chemistry, 1998, vol. 37, p. 838 - 839
  作者：Demadis, Konstantinos、El-Samanody, El-Sayed、Meyer, Thomas J.、White, Peter S.

  DOI：——

  日期：——
• [OsIII(tpy)(Cl)(NCCH3)(NSAr)]: Reversible Reduction of Acetonitrile by OsIII–Sulfilimido Complexes
  作者：My Hang V. Huynh、R. Thomas Baker、David E. Morris、Peter S. White、Thomas J. Meyer

  DOI：10.1002/1521-3773(20021018)41:20<3870::aid-anie3870>3.0.co;2-q

  日期：2002.10.18
• Formation and O-Atom Reactivity of the Os(IV)−Sulfilimido and Os(IV)−Sulfoximido Complexes, <i>cis</i>-/<i>trans</i>-[Os^IV(tpy)(Cl)₂(NSC₆H₃Me₂)] and <i>cis</i>-/<i>trans</i>-[Os^IV(tpy)(Cl)₂(NS(O)C₆H₃Me₂)]
  作者：My Hang V. Huynh、Peter S. White、Thomas J. Meyer

  DOI：10.1021/ja002874r

  日期：2001.9.1
• Localization in <i>trans,trans</i>-[(tpy)(Cl)₂Os^III(N₂)Os^II(Cl)₂(tpy)]⁺ (tpy = 2,2‘:6‘,2‘‘-Terpyridine)
  作者：Konstantinos D. Demadis、Thomas J. Meyer、Peter S. White

  DOI：10.1021/ic970885o

  日期：1997.12.1