[Ag(PPh3)4](perchlorate) | 60185-35-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(PPh3)4](perchlorate)
• 英文别名: tetrakis(triphenylphosphine)silver(I) perchlorate；[Ag(PPh₃)₄](perchlorate)
• CAS: 60185-35-5
• 化学式: C₇₂H₆₀AgP₄*ClO₄
• 分子量: 1256.48
• InChiKey: YFILUVDEEMMZGQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ag(PPh3)4](perchlorate) 、 (Et4N)3[Fe3S4(1,3,5-tris((4,6-dimethyl-3-mercapto-phenyl)thio)-2,4,6-tris(p-tolylthio)benzene(-3H))] 在 PPh₃ 、 Ag(ClO₄) 作用下， 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  包含长方体 [Fe3S4]0 核的簇 [Fe3S4(LS3)]3- 的金属离子掺入反应

  摘要：

  立方体簇[Fe3S4(S·Cys)3]在多种蛋白质中的频繁出现促使对其化学和生物学特性的广泛研究。生物功能仍然存在问题，但已知该簇可维持两种反应：（i）电子转移和（ii）异金属离子掺入。[Fe3S4(LS3)]3-(3)[Zhou, J.; 胡志；蒙克，E。霍尔姆，RHJ 上午。化学 社会。1996, 118, 1966] 允许对立方 [Fe3S4]0 氧化态 (LS3 = 1,3,5-tris((4,6-dimethyl-3-mercaptophenyl)thio)-进行详细的结构、电子和反应性表征2,4,6-tris(p-tolylthio)benzo(3−). 氧化还原特性 (i) 之前已经报道过：这里的反应类型 (ii) 导致了立方烷型 MFe3S4 簇的形成，已被研究。3 与 [M(PPh3)4]1+ 反应得到 [(Ph3P)MFe3S4(LS3)]2- (M = Cu (6),

  DOI：

  10.1021/ja9704186
• 作为产物：
  描述：

  {AgS2CN(C2H5)2(triphenylphosphine)2} 以 乙醇 、 苯 为溶剂， 生成 [Ag(PPh3)4](perchlorate)
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B7, 1.23.3, page 208 - 220

  摘要：

  DOI：

文献信息

• Dinuclear Copper(I) and Copper(I)/Silver(I) Complexes with Condensed Dithiolato Ligands¹
  作者：José Vicente、Pablo González-Herrero、Yolanda García-Sánchez、Delia Bautista

  DOI：10.1021/ic8014139

  日期：2008.11.17

  The Cu(III) complex Pr 4N[CuS 2C=( t-Bu-fy)} 2] ( 1) ( t-Bu-fy = 2,7-di- tert-butylfluoren-9-ylidene) reacts with [Cu(PR 3) 4]ClO 4 in 1:1 molar ratio in MeCN to give the dinuclear complexes [Cu 2[SC=( t-Bu-fy)] 2S}(PR 3) n ] [ n = 2, R = Ph ( 2a); n = 3, R = To ( 3b); To = p-tolyl]. The analogue of 2a with R = To ( 2b) can be obtained from the reaction of 3b with 1/8 equiv of S 8. Compound 2b establishes

  Cu（III）络合物Pr 4N [Cu S 2C =（t-Bu-fy）} 2]（1）（t-Bu-fy = 2,7-二叔丁基芴-9-亚烷基）与[Cu（PR 3）4] ClO 4在MeCN中的摩尔比为1：1，得到双核络合物[Cu 2 [SC =（t-Bu-fy）] 2S}（PR 3）n] [n = 2 ，R = Ph（2a）; n = 3，R = To（3b）; To =对甲苯基]。R = To（2b）的2a的类似物可以从3b与1/8当量的S 8的反应中获得。化合物2b在溶液中建立了硫酮烯交换平衡，从而导致[Cu 4 S 2C = （t-Bu-fy）} 2（PTo 3）4]（4b）和[Cu 2 [SC =（t-Bu-fy）] 3S}（PTo 3）2]（5b）。当使用MeCN尝试沉淀2b时，可以得到不同比例的4b和5b的固体混合物。1与AgClO 4和PPh 3，PTo 3或PCy 3
• Synthesis and structural systematics of mixed triphenylphosphine/imidazole base adducts of silver(I) oxyanion salts †
  作者：Augusto Cingolani、Effendy、Fabio Marchetti、Claudio Pettinari、Brian W. Skelton、Allan H. White

  DOI：10.1039/a906624a

  日期：——

  From the interaction between imidazole-type ligands B and [Ag(PPh3)4]X (X = NO3, BF4, ClO4 or CF3CO2), [Ag(PCy3)2(NO3)] and [Ag(PPh3)X)] (X = NO2 or CH3SO3), new ionic mononuclear [Ag(PR3)4–n(B)n]+[X]– (R = Ph or Cy) and neutral mono- ([Ag(PR3)3–n(B)n(X)]) and di-nuclear ([Ag(PPh3)(B)(µ-X)}2]) complexes have been obtained which have been characterized through elemental analysis, IR and far-IR, conductivity, 1H NMR and in some cases also by vaporimetric molecular weight measurements and 31P NMR. Stoichiometries and molecular structures are dependent on the nature of the azole (steric hindrance and basicity), of the counter ion, and on the number of the P-donor ligands in the starting reactants. Solution data are consistent with a partial dissociation of complexes, occurring through breaking of both Ag–N and Ag–P bonds. The majority of the possible Ph3P/imidazole base combinations have been characterized structurally by room-temperature single crystal X-ray studies, thus: [Ag(PPh3)3(4-Ph-im)]NO3 (4-Ph-im = 4-phenylimidazole), [Ag(PPh3)2B2]NO3 for B = imidazole (Him) or 2-methyl-imidazole (2-Me-im), [Ag(PPh3)(2-Me-im)3][CF3CO2], [Ag(PPh3)2(2-Me-im)(O2NO)], [Ag(PPh3)(1-Me-im)(µ-OSOCH3O)}2] and [Ag(PPh3)(Him)(µ-ONO)}2]; the latter is a mixture of isomers in which one or both oxygen atoms of the anions interact with silver atoms. In the methanesulfonate complex the interactions of the anions with the silver may be regarded as a perturbation on a proto-linear P–Ag–N array (Ag–P,N 2.3662(6), 2.189(1) Å; P–Ag–N 144.28(6)°).

  来自咪唑型配体 B 和 [Ag(PPh3)4]X（X=NO3、BF4、ClO4 或 CF3CO2）、[Ag(PCy3)2( )] 和 [Ag(PPh3)X)] 之间的相互作用(X=NO2 或 CH3SO3)、新离子单核 [Ag(PR3)4−n(B)n]+[X]−（R=Ph 或 Cy）和中性单核 ([Ag(PR3) )3→n(B)n(X)]) 和双核 ([Ag(PPh3)(B)(µ-X)}2]) 配合物已获得，并通过元素分析、红外光谱进行了表征以及远红外、电导率、1H NMR，在某些情况下还通过蒸气分子量测量和 31P NMR。化学计量和分子结构取决于唑的性质（空间位阻和碱性）、抗衡离子的性质以及起始反应物中P-供体配体的数量。溶液数据与复合物的部分解离一致，这是通过 Ag-N 和 Ag-P 键的断裂而发生的。大多数可能的 Ph3P/咪唑碱组合已通过室温单晶 X 射线研究进行了结构表征，因此： [Ag(PPh3)3(4-Ph-im)] (4-Ph-im =) 4-苯基咪唑), [Ag(PPh3)2B2] for B = 咪唑 (Him) 或 2-甲基咪唑 (2-Me-​​im), [Ag(PPh3)(2-Me-​​im)3][ CF3CO2]、[Ag(PPh3)2(2-Me-​​im)(O2NO)]、[Ag(PPh3)(1-Me-im)(µ-OSOCH3O)}2] 和 [Ag(PPh3)(他)(µ-ONO)}2];后者是异构体的混合物，其中阴离子的一个或两个氧原子与银原子相互作用。在甲磺酸盐配合物中，阴离子与银的相互作用可被视为对原始线性 P−Ag−N 阵列的扰动 (Ag−P,N 2.3662(6), 2.189(1) ×; Pâ Ag-N 144.28(6)°)。
• Spectroscopic and Phosphorescent Modulation in Triphosphine-Supported PtAg₂Heterotrinuclear Alkynyl Complexes
  作者：Li-Yi Zhang、Liang-Jin Xu、Xu Zhang、Jin-Yun Wang、Jia Li、Zhong-Ning Chen

  DOI：10.1021/ic4000457

  日期：2013.5.6

  A series of highly phosphorescent PtAg2 heterotrinuclear alkynyl complexes with bis(diphenylphosphinomethyl)-phenylphosphine (dpmp) were prepared and characterized structurally. The solution phosphorescence with various emitting colors is systematically modulated by modifying substituents as well as pi-conjugated systems in aromatic acetylides. The crystals, powders, or films exhibit reversible stimuli-responsive phosphorescence changes upon exposure to vapor of MeCN, pyridine, DMF, etc., resulting from perturbation of d(8)-d(10) metallophilic interaction in the excited states as a consequence of the formation/disruption of Ag-solvent bonds. Both experimental and time-dependent density functional theory (TD-DFT) studies demonstrate that d(8)-d(10) metallophilic interaction exerts a crucial role on phosphorescent characteristics due to the PtAg2 cluster-based (3)[d -> p] state. This study affords a paradigm for phosphorescence modulation in d(8)-d(10) heteronuclear complexes.
• Bell, Andrew; Edwards, Dennis A., Journal of the Chemical Society, Dalton Transactions, 1984, p. 1317 - 1322
  作者：Bell, Andrew、Edwards, Dennis A.

  DOI：——

  日期：——
• Cotton, F. A.; Goodgame, D. M. L., Journal of the Chemical Society
  作者：Cotton, F. A.、Goodgame, D. M. L.

  DOI：——

  日期：——