2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone | 1292230-81-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone
• 英文别名: 2-Diphenylphosphinobenzaldehyde 2-quinolinylhydrazone；N-[(2-diphenylphosphanylphenyl)methylideneamino]quinolin-2-amine
• CAS: 1292230-81-9
• 化学式: C₂₈H₂₂N₃P
• 分子量: 431.477
• InChiKey: PDAZRVNGXWHHTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone 、 nickel diacetate 以 甲醇 为溶剂， 反应 4.0h， 以45%的产率得到[Ni(2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone-H)(CH3COO)]
  参考文献：
  名称：

  Synthesis and crystal structure of the nickel(II) complex with 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone

  摘要：

  2-Diphenylphosphinobenzaldehyde 2-quinolinylhydrazone (HL) and its nickel(II) complex [Ni(L)(CH3COO)] were synthesized. The structure of the complex was determined by X-ray diffraction. The nickel ion in the molecule of the complex has a square PNN'O donor environment. Owing to C-H...O intermolecular hydrogen bonds, centrosymmetric dimers are formed in the crystal.

  DOI：

  10.1134/s1070328414050108
• 作为产物：
  描述：

  2-肼喹啉 、 2-二苯基膦苯甲醛 以 乙醇 为溶剂， 反应 1.0h， 以65%的产率得到2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone
  参考文献：
  名称：

  Synthesis and crystal structure of the nickel(II) complex with 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone

  摘要：

  2-Diphenylphosphinobenzaldehyde 2-quinolinylhydrazone (HL) and its nickel(II) complex [Ni(L)(CH3COO)] were synthesized. The structure of the complex was determined by X-ray diffraction. The nickel ion in the molecule of the complex has a square PNN'O donor environment. Owing to C-H...O intermolecular hydrogen bonds, centrosymmetric dimers are formed in the crystal.

  DOI：

  10.1134/s1070328414050108

文献信息

• Synthesis and crystal structure of the nickel(II) complex with 2-diphenylphosphinobenzaldehyde 2-quinolinylhydrazone
  作者：L. D. Popov、S. I. Levchenkov、I. N. Shcherbakov、Z. A. Starikova、V. V. Lukov、V. A. Kogan

  DOI：10.1134/s1070328414050108

  日期：2014.5

  2-Diphenylphosphinobenzaldehyde 2-quinolinylhydrazone (HL) and its nickel(II) complex [Ni(L)(CH3COO)] were synthesized. The structure of the complex was determined by X-ray diffraction. The nickel ion in the molecule of the complex has a square PNN'O donor environment. Owing to C-H...O intermolecular hydrogen bonds, centrosymmetric dimers are formed in the crystal.