2,4,6,8-Tetracyanoazulene | 209049-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6,8-Tetracyanoazulene
• 英文别名: Azulene-2,4,6,8-tetracarbonitrile
• CAS: 209049-76-3
• 化学式: C₁₄H₄N₄
• 分子量: 228.213
• InChiKey: LGODFJFAEWDETA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  95.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4,6,8-Tetracyanoazulene 在 potassium iodide 作用下， 以 乙腈 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  Schmitt, Stefan; Baumgarten, Martin; Simon, Joachim, Angewandte Chemie - International Edition, 1998, vol. 37, # 8, p. 1078 - 1081

  摘要：

  DOI：
• 作为产物：
  描述：

  2-Cyanoazulene 生成 2,4,6,8-Tetracyanoazulene
  参考文献：
  名称：

  Schmitt, Stefan; Baumgarten, Martin; Simon, Joachim, Angewandte Chemie - International Edition, 1998, vol. 37, # 8, p. 1078 - 1081

  摘要：

  DOI：

文献信息

• Voltammetric ion-selective biosensor
  申请人：——

  公开号：US20040251133A1

  公开（公告）日：2004-12-16

  A method for the quantitative determination of an ion in a fluid is described which comprises subjecting the fluid to voltammetry using an electrode which comprises an electrically conducting support possessing a coating of a solid capable of selecting ions when electrochemically induced during operation.

  描述了一种定量测定流体中离子的方法，该方法包括使用电极对流体进行伏安法测定，该电极由导电支架组成，支架上有一层固体涂层，在操作过程中电化学诱导时能够选择离子。
• Novel CT Complexes Derived from 4-Alkylamino-TEMPO and 2,4,6,8-Tetracyanoazulene
  作者：Shin'Ichi Nakatsuji、Masako Mizumoto、Atsushi Takai、Hiroki Akutsu、Jun-Ichi Yamada、Haruki Kawamura、Stefan Schmitt、Klaus Hafner

  DOI：10.1080/10587250008024790

  日期：2000.8.1

  Novel CT complexes derived from 4-alkylamino-TEMPO radical and 2,4,6,8-tetracyanoazulene have been prepared. Curie-Weiss behavior has been observed in the magnetic susceptibility of each complex with antiferromagnetic spin-spin interactions in the low temperature region on one hand and rather high conductivity has been found in the electrical conductivity of each complex with semiconducting behavior on the other hand.
• VOLTAMMETRIC ION-SELECTIVE BIOSENSOR
  申请人：Oxford Biosensors Limited

  公开号：EP1421374A2

  公开（公告）日：2004-05-26
• VOLTAMMETRIC ION SENSOR
  申请人：Oxford Biosensors Limited

  公开号：EP1800116A1

  公开（公告）日：2007-06-27
• Voltammetric Ion Sensor
  申请人：Zhang Jie

  公开号：US20080011606A1

  公开（公告）日：2008-01-17

  A method for the quantitative determination of an ion in a fluid which comprises subjecting the fluid to voltammetry using a sensing electrode which comprises an electrically conducting support having a surface which is coated with a support matrix, the support matrix containing an electroactive species capable of being oxidised or reduced to form a charged species, and an ionophore.