[4-(4-苯氧基苯氧基)苯基]-苯基甲酮 | 106315-29-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: [4-(4-苯氧基苯氧基)苯基]-苯基甲酮
• 英文名称: 4-(4-phenoxyphenoxy) benzophenone
• 英文别名: 4-(4-phenoxyphenoxy)benzophenone；Methanone, [4-(4-phenoxyphenoxy)phenyl]phenyl-；[4-(4-phenoxyphenoxy)phenyl]-phenylmethanone
• CAS: 106315-29-1
• 化学式: C₂₅H₁₈O₃
• 分子量: 366.416
• InChiKey: JKFWKYCRXYOPRC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-氟二苯甲酮 、 4-苯氧基苯酚 在 氢化钾 作用下， 生成 [4-(4-苯氧基苯氧基)苯基]-苯基甲酮
  参考文献：
  名称：

  涉及亲核芳族取代的聚合反应和相关反应。第2部分。取代的4-卤代二苯甲酮与取代的氢醌盐的反应速率

  摘要：

  4-X-4'-氟二苯甲酮与4-Y-4'-羟基二苯醚的碱金属盐在140°C的二苯砜溶液中进行预期的亲核取代反应：X取代基的哈米特ρ值为1.02，并且– Y取代基为0.34。碱金属盐的反应性顺序为Cs> K> Na。在相同条件下，氟二苯甲酮与4-Z-苯酚钾的相关反应得出ρ值为–2.28。该结果已用于计算氢醌单钾盐和二钾盐与氟二苯甲酮反应的相应速率系数。

  DOI：

  10.1039/p29880001735

文献信息

• PARTICULATE AMINE-FUNCTIONALIZED POLYARYLETHERKETONE POLYMER AND COPOLYMERS THEREOF
  申请人：Cytec Industries Inc.

  公开号：US20150337082A1

  公开（公告）日：2015-11-26

  Particles of an amine-functionalised polyaryletherketone polymer or copolymer thereof. The amine-functionalised polyaryletherketone polymer or copolymer thereof is selected from the group consisting of: polyaryletherketone polymer with terminal amine or protected amine functional group(s); polyaryletherketone-imide copoplymer with terminal amine or protected amine functional group(s); and polyaryletherketone-sulphone copolymer with terminal amine or protected amine functional group(s).

  一种氨基官能化聚芳醚酮聚合物或其共聚物的粒子。所述氨基官能化聚芳醚酮聚合物或其共聚物选择自以下组中的一种：具有末端氨基或保护氨基官能团的聚芳醚酮聚合物；具有末端氨基或保护氨基官能团的聚芳醚酮-亚酰亚胺共聚物；以及具有末端氨基或保护氨基官能团的聚芳醚酮-砜共聚物。
• Preparation of poly(arylene ether ketones)
  申请人：RAYCHEM CORPORATION (a Delaware corporation)

  公开号：EP0174207A2

  公开（公告）日：1986-03-12

  The preparation of poly(arylene ether ketones) by Friedel-Crafts polymerization, in the presence of a Lewis acid catalyst and a diluent, is conducted under conditions in which the polymer and/or its complex with the catalyst is suspended in the diluent during at least part of the polyreac- tion mixture if desired. The dispersant may be a polymer or an organic compound containing at least eight carbon atoms and is preferably a Lewis base. The dispersant preferably contains at least one molecular segment substantially compatible with the poly(arylene ether ketone) or its complex with the Lewis acid and substantially incompatible with the diluent and at least one molecular segment substantially compatible with the diluent and substantially incompatible with the poly(arylene ether ketone) or its complex with the Lewis acid.

  在路易斯酸催化剂和稀释剂存在下，通过弗里德尔-卡夫斯聚合法制备聚(芳基醚酮)，如果需要，在至少部分聚合混合物过程中，聚合物和/或其与催化剂的络合物悬浮在稀释剂中。 分散剂可以是聚合物或含有至少八个碳原子的有机化合物，最好是路易斯碱。 分散剂最好含有至少一个与聚(芳基醚酮)或其与路易斯酸的络合物基本相容且与稀释剂基本不相容的分子段，以及至少一个与稀释剂基本相容且与聚(芳基醚酮)或其与路易斯酸的络合物基本不相容的分子段。
• Preparation of aromatic ketone-sulfone copolymers
  申请人：RAYCHEM CORPORATION (a Delaware corporation)

  公开号：EP0178183A2

  公开（公告）日：1986-04-16

  A process for producing aromatic ketone-sulfone copolymers which comprises polymerizing appropriate monomers by a Friedel-Crafts polymerization reaction using a Lewis acid catalyst. A controlling agent such as a Lewis base is added to the reaction medium. The reaction medium comprises, for example, aluminum trichloride as the Lewis acid, an organic Lewis base such as N,N-dimethylformamide or an inorganic Lewis base such as sodium or lithium chloride as the controlling agent, and a diluent such as methylene chloride or 1,2-dichloroethane. The amount of Lewis acid, the amount of Lewis base, the temperature of the reaction and the monomer to diluent molar ratio are varied depending on the monomer system to obtain melt-processable, high molecular weight, substantially linear polymers, for example prepared from copolymerization of p-phenoxybenzoyl chloride and p-phenoxybenzenesulfonyl chloride or of terephthaloyl chloride, 1,4-benzenedisulfonyl chloride and diphenyl ether, or of like monomers.

  一种生产芳香族酮砜共聚物的工艺，包括使用路易斯酸催化剂，通过弗里德尔-卡 夫斯聚合反应使适当的单体聚合。在反应介质中加入路易斯碱等控制剂。例如，反应介质包括作为路易斯酸的三氯化铝、作为控制剂的有机路易斯碱（如 N,N-二甲基甲酰胺）或无机路易斯碱（如氯化钠或氯化锂），以及稀释剂（如二氯甲烷或 1,2-二氯乙烷）。路易斯酸的用量、路易斯碱的用量、反应温度以及单体与稀释剂的摩尔比可根据单体体系的不同而变化，以获得可熔融加工的高分子量、基本为线性的聚合物，例如由对苯氧基苯甲酰氯和对苯氧基苯磺酰氯或对苯二甲酰氯、1,4-苯二磺酰氯和二苯醚或类似单体的共聚物制备的聚合物。
• Novel aromatic polymers
  申请人：RAYCHEM CORPORATION (a Delaware corporation)

  公开号：EP0178185A2

  公开（公告）日：1986-04-16

  Novel aromatic poly(ether ketones) having imide, amide, ester, azo, quinoxaline, benzimidazole, benzoxazoie, or benzothiazole groups, comprising, for example, a repeat unit are prepared by Friedel Crafts polymerization.

  新型芳香族聚醚酮具有酰亚胺、酰胺、酯、偶氮、喹喔啉、苯并咪唑、苯并恶唑或苯并噻唑基团，例如包含一个重复单元，可通过 Friedel Crafts 聚合法制备。
• Preparation of arylene oligomers
  申请人：RAYCHEM LIMITED

  公开号：EP0262920A2

  公开（公告）日：1988-04-06

  Friedel Crafts preparation of arylene ether (especially arylene ether ketone) oligomers with an exceptionally high degree of isomeric purity and freedom from by-products can be achieved by adding to the Lewis acid reaction system a protic controlling agent selected from ROX, water, RCOOX, RSO₃X, and ROY, wherein R is organic, X is hydrogen or metal, and Y is metal. Contrary to conventional expectation, the protic agent does not significantly acylate or alkylate the Friedel Crafts reaction product, and controlling agents of relatively low molecular weight, e.g., benzoic acid, can surprisingly be selected to produce dispersions of the resulting oligomers.

  在路易斯酸反应体系中加入选自 ROX、水、RCOOX、RSO₃X 和 ROY（其中 R 为有机物，X 为氢或金属，Y 为金属）的原质控剂，可实现 Friedel Crafts 芳基醚（尤其是芳基醚酮）低聚物的制备，该低聚物具有极高的同分异构纯度且无副产物。 与传统预期不同的是，质子剂不会使 Friedel Crafts 反应产物发生明显的酰化或烷基化，而且可以选择分子量相对较低的控制剂，如苯甲酸，来生产所得低聚物的分散体。