((1r,4r)-4-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)cyclohexyl)methanol | 87770-85-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 英文名称: ((1r,4r)-4-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)cyclohexyl)methanol
• 英文别名: 4-[[(tetrahydro-2H-pyran-2-yl)oxy]methyl]cyclohexanemethanol；[4-(oxan-2-yloxymethyl)cyclohexyl]methanol
• CAS: 87770-85-2
• 化学式: C₁₃H₂₄O₃
• 分子量: 228.332
• InChiKey: CRLAWZVUSDCWMZ-UHFFFAOYSA-N

物化性质

• 沸点：
  345.3±27.0 °C(Predicted)
• 密度：
  1.04±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  ((1r,4r)-4-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)cyclohexyl)methanol 在 sodium chloride dihydrate 、 2,2,6,6-四甲基哌啶氧化物 、 碳酸氢钠 、 sodium hydrogensulfite 、 sodium bromide 作用下， 以 二氯甲烷 为溶剂， 反应 0.58h， 以300 g的产率得到(1r,4r)-4-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)cyclohexane-1-carbaldehyde
  参考文献：
  名称：

  一种双烯类负性液晶化合物及其制备方法和应用

  摘要：

  本发明涉及一种双烯类负性液晶化合物及其制备方法和应用。所述负性液晶化合物如所示通式Ⅰ的结构。所述负性液晶化合物如所示通式Ⅰ的结构具有双烯结构及极大的负介电各向异性，可提高液晶组合物的陡度、降低粘度、缩短响应时间。含有该液晶化合物的液晶组合物同时具备良好的低温稳定性及互溶性，较强的抗UV能力和高的VHR及电阻率，适用于VA、MVA、PVA、FFS、PSVA、IPS、TFT等显示模式。

  公开号：

  CN111574405A
• 作为产物：
  描述：

  2-[4-(2-Methoxy-ethoxymethoxymethyl)-cyclohexylmethoxy]-tetrahydro-pyran 在 2-chloro-1,3,2-dithioborolane 作用下， 以 二氯甲烷 为溶剂， 反应 0.75h， 以89%的产率得到((1r,4r)-4-(((tetrahydro-2H-pyran-2-yl)oxy)methyl)cyclohexyl)methanol
  参考文献：
  名称：

  Opportunities for selective removal of methoxyethoxymethyl (mem) ethers

  摘要：

  DOI：

  10.1016/s0040-4039(00)88237-4

文献信息

• Nitrile compound and its use for control of arthropod pest
  申请人：Sumitomo Chemical Company, Limited

  公开号：US08344163B2

  公开（公告）日：2013-01-01

  There is provided a nitrile compound having an excellent controlling effect on arthropod pests represented by the formula (I): wherein m represents in integer of 0 to 4; n represents an integer of 1 to 4; q represents an integer of 0 to 4; Q represents a C1-C4 fluoroalkyl group; Z represents an optionally substituted C2-C6 alkynyl group or a ═N—OR3 group; R1 and R2 independently represent a monovalent C1-C4 chain hydrocarbon group optionally substituted with a halogen atom, etc.; and A represents an optionally substituted monovalent C1-C6 chain hydrocarbon group, etc.

  提供了一种具有优异节肢动物害虫控制效果的腈化合物，其化学式表示为(I)：其中m表示0至4的整数；n表示1至4的整数；q表示0至4的整数；Q表示C1-C4氟烷基；Z表示可选取代的C2-C6炔基或═N—OR3基团；R1和R2分别表示可选取代的单价C1-C4链烃基，其中含有卤素原子等；A表示可选取代的单价C1-C6链烃基等。
• NITRILE COMPOUND AND ITS USE FOR CONTROL OF ARTHROPOD PEST
  申请人：Mitsudera Hiromasa

  公开号：US20110021627A1

  公开（公告）日：2011-01-27

  There is provided a nitrile compound having an excellent controlling effect on arthropod pests represented by the formula (I): wherein m represents in integer of 0 to 4; n represents an integer of 1 to 4; q represents an integer of 0 to 4; Q represents a C1-C4 fluoroalkyl group; Z represents an optionally substituted C2-C6 alkynyl group or a ═N—OR 3 group; R 1 and R 2 independently represent a monovalent C1-C4 chain hydrocarbon group optionally substituted with a halogen atom, etc.; and A represents an optionally substituted monovalent C1-C6 chain hydrocarbon group, etc.

  提供了一种具有对节肢动物害虫具有优异控制作用的腈化合物，其化学式表示为(I)：其中，m表示0至4的整数；n表示1至4的整数；q表示0至4的整数；Q表示C1-C4氟烷基；Z表示可选取代的C2-C6炔基或═N—OR3基团；R1和R2分别独立表示可选取代的单价C1-C4链烃基，其中烃基可用卤原子等取代；A表示可选取代的单价C1-C6链烃基等。
• Selective Monotetrahydropyranylation of Symmetrical Diols Catalyzed by Ion-Exchange Resins
  作者：Takeshi Nishiguchi、Shizuo Fujisaki、Masahumi Kuroda、Kohtaro Kajisaki、Masahiko Saitoh

  DOI：10.1021/jo980659b

  日期：1998.11.1

  Primary and secondary symmetrical diols with 2-10 carbon atoms gave selectively monotetrahydropyranyl ethers in the reaction catalyzed by wet sulfonic acid-type ion-exchange resins in 3,4-dihydro-2H-pyran (DI-IP)/toluene or DHP/hexane. The yields of the monoethers were higher than 80% while those of the corresponding diethers were lower than 5%. In these reactions the rate of the formation of the diethers did not increase much even after most of the diols had been consumed. In the reaction of 1,10-decanediol in DHP/hexane, the yields of the monoether were increased by the addition of DMF or DMSO. Each diol was found to have a particular DHP/hydrocarbon ratio that gave the highest selectivity for the monoether. Generally, the larger the number of carbon atoms of the diols, the smaller the ratio of DHP in the solvents to give high selectivity for the monoether. This method of the selective etherification is quite simple and practical.
• [EN] NITRILE COMPOUND AND ITS USE FOR CONTROL OF ARTHROPOD PEST<br/>[FR] COMPOSÉ NITRILE ET SON UTILISATION POUR LA LUTTE CONTRE LES ARTHROPODES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2009116687A3

  公开（公告）日：2009-12-10
• WILLIAMS, D. R.;SAKDARAT, S., TETRAHEDRON LETT., 1983, 24, N 37, 3965-3968
  作者：WILLIAMS, D. R.、SAKDARAT, S.

  DOI：——

  日期：——