Au(pentafluorophenyl)3(bis(diphenylphosphino)methane) | 84444-53-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Au(pentafluorophenyl)3(bis(diphenylphosphino)methane)
• 英文别名: diphenylphosphanylmethyl(diphenyl)phosphane;gold(3+);1,2,3,4,5-pentafluorobenzene-6-ide
• CAS: 84444-53-1
• 化学式: C₄₃H₂₂AuF₁₅P₂
• 分子量: 1082.54
• InChiKey: YUQACDUCHWKEGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Au(pentafluorophenyl)3(bis(diphenylphosphino)methane) 以 二氯甲烷 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  与双（二苯基膦基）甲烷配体的单硫属元素或二硫属元素化物的金配合物。[Au（C6F5）2 {（SPPh2）2C（AuAsPh3）2}] ClO4的X射线晶体结构

  摘要：

  摘要硫族化物衍生物[Au（C6F5）3（PPh2CH2PPh2E）]（E = S，O）与[Au（acac）PPh3]或[Au（TfO）PPh3]之间的反应生成双核化合物[Au（C6F5） 3 {PPh2CH（AuPPh3）PPh2E}]（E = S，O）或[Au（C6F5）3 {PPh2CH2PPh2（SAuPPh3）}]。当使用二硫化膦配合物[Au（C6F5），（SPPh2CH2PPh2S）]时，与[Au（acac）PPh3]的反应促进亚甲基质子的双取代。[Au（acac）L]（L = PPh3，AsPh3）与六元金环[Au（C6F5）2 {（SPPh2）2CH2}] ClO4的反应导致两个亚甲基质子被[AuL]双重取代+片段，保持auracycle完好无损。通过X射线衍射研究已经确定了一种这样的产物[Au（C6F5）2 {（SPPh2）2C（AuAsPh3）2}] ClO4的晶体结构。

  DOI：

  10.1016/s0277-5387(97)00473-7
• 作为产物：
  描述：

  pentafluorophenyl(tetrahydrothiophene)gold(I) 以 苯 为溶剂， 生成 Au(pentafluorophenyl)3(bis(diphenylphosphino)methane)
  参考文献：
  名称：

  三（五氟苯基）金（III）络合物

  摘要：

  描述了通过用[Tl（C 6 F 5）2 Cl]氧化[Au（C 6 F 5）（tht）]来制备[Au（C 6 F 5）3（tht）]（tht =四氢噻吩）。。其他中性或阴离子不对称配体取代tht导致合成[Au（C 6 F 5）3 L] [L = NH 3，py，PMePh 2，P（OPh）3，AsPh 3，SbPh 3或CNC 6 H 4 Me- p ]或Q [Au（C 6 F 5）3 X] [Q = NEt 4，NBu 4，PPh 3（CH 2 Ph）或N（PPh 3）2；X ＝ Cl，I，SCN或N 3 ]。化合物[Au（C 6 H 5）3（CNC 6 H 4 Me- p）]加成胺，得到金（III）-卡宾络合物[Au（C 6 F 5）3 {C（NHC 6 H 4 Me - p）（NR 2）}]（NR 2 = NHC 6 H ^ 4ME- p，NET 2，或NHCH 2 CH 2 NH 2）。化合物[Au（C

  DOI：

  10.1039/dt9820001971

文献信息

• Synthesis of heteropolynuclear complexes with 1,1,1-tris(diphenylphosphinomethyl)ethane. Crystal structure of [(OC)₄Mo{(Ph₂PCH₂)₂CMe(CH₂PPh₂)}AuCl]
  作者：Eduardo J. Fernández、M. Concepciön Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、Elena Olmos

  DOI：10.1039/dt9960003603

  日期：——

  Treatment of [M(CO)(4)(Ph(2)PCH(2))(2)CMe(CH(2)PPh(2))}] (M = Mo or W) with neutral or cationic gold-(I) or -(III) derivatives afforded bi- or tri-nuclear complexes containing the triphosphine (Ph(2)PCH(2))(3)CMe (tdppme) acting as a mu-P,P',P '' ligand, a co-ordination mode poorly represented thus far. The binuclear derivative [(OC)(4)Mo(tdppme)AuCl] further reacts with 1 equivalent of Tl(acac) (acac = acetylacetonate) to afford [(OC)(4)Mo(tdppme)Au(acac)]. This complex acts as a deprotonating agent in reactions with various starting materials containing phosphines such as (Ph(2)P)(2)CH2 or (Ph(2)P)(3)CH, leading to the formation of trinuclear methanide complexes. The crystal structure of [(OC)(4)Mo(tdppme)AuCl] has been established by X-ray crystallography.
• Synthesis, Structure, and Reactivity of the Anionic Trinuclear Methanide NBu4[{Au(C6F5)3(PPh2CHPPh2)}2Au]
  作者：Eduardo J. Fernandez、M. Concepcion Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、Jose M. Lopez-de-Luzuriaga

  DOI：10.1021/om00006a041

  日期：1995.6

  The reaction of [Au(tht)(2)]CLO(4) or NBu(4)[Au(acac)(2)] with 2 equiv of [Au(C6F5)(3)PPh(2)CH(2)PPh(2)] affords the cationic [Au(C6F5)(3)PPh(2)CH(2)PPh(2)}Au-2]ClO4 (1) or anionic complex NBu(4)[Au(C6F5)(3)PPh(2)CHPPh(2)}Au-2] (2), respectively, in high yield, The methanide complex 2 can displace tetrahydrothiophene from [AuX(tht)] to give the pentanuclear NBu(4)[AU(C6F6)(3)PPh(2)CH(AuX)PPh(2)}Au-2] (X = Cl, C6F5). The heptanuclear [Au(C6F5)(3)PPh(2)C(AuPPh(3))(2)PPh(2)}Au-2]ClO4 is obtained by reaction of 1 with [Au(acac)PPh(3)] (molar ratio 1:4), The structure of 2 has been determined by a single-crystal X-ray diffraction study, It crystallizes in the space group P (1) over bar with a = 14.213(4) Angstrom, b = 16.067(4) Angstrom, c = 23.840(6) Angstrom, alpha = 88.60(2)degrees, beta = 89.27(2)degrees, gamma = 71.23(2)degrees, Z = 2, and T = -100 degrees C, It does not display gold-gold interactions.
• Tris(pentafluorophenyl)(tetrahydrothiophen)gold(III)
  作者：R. Usón、A. Laguna、M. Laguna、E. Fernandez

  DOI：10.1016/s0020-1693(00)80136-x

  日期：1980.1
• Synthesis and structure of [Tl(C6F5)2Cl{Au(C6F5)3(PPh2CH2PPh2(O))}2]
  作者：Beatriz Alvarez、Eduardo J. Fernández、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna、Mariano Laguna、JoséM. López-de-Luzuriaga

  DOI：10.1016/s0022-328x(96)06506-0

  日期：1996.11

  Two trinuclear gold-thallium-gold complexes, Tl(C6F5)(2)XAu(C6F5)(3)(PPH(2)CH(2)PPh(2)CH(2)PPh(2)(O))}(2)} (X = C6F5, Cl), have been synthesised by reaction of [Au(C6F5)(3)(PPh(2)(O))] with [Tl(C6F5)(2)Cl] or [Tl(C6F5)(3)(diox)], in which the phosphine oxide moiety coordinates to thallium; the crystal structure of the former product has been established by X-ray diffraction.
• Fernandez, Eduardo J.; Gimeno, M. Concepcion; Jones, Peter G., Chemische Berichte, 1995, vol. 128, # 2, p. 121 - 124
  作者：Fernandez, Eduardo J.、Gimeno, M. Concepcion、Jones, Peter G.、Laguna, Antonio、Laguna, Mariano、et al.

  DOI：——

  日期：——