4',4''''-(dithiodi-4,1-phenylene)bis(2,2':6',2''-terpyridine) | 936615-69-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 4',4''''-(dithiodi-4,1-phenylene)bis(2,2':6',2''-terpyridine)
• 英文别名: bis[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]disulfide；4-[4-[[4-(2,6-Dipyridin-2-ylpyridin-4-yl)phenyl]disulfanyl]phenyl]-2,6-dipyridin-2-ylpyridine
• CAS: 936615-69-9
• 化学式: C₄₂H₂₈N₆S₂
• 分子量: 680.857
• InChiKey: GOKITFOELRGHQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  50
• 可旋转键数：
  9
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  128
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4',4''''-(dithiodi-4,1-phenylene)bis(2,2':6',2''-terpyridine) 、 cobalt(II) perchlorate hexahydrate 以 甲醇 为溶剂， 反应 12.0h， 以82%的产率得到({1-[4-(2,2':6',2''-terpyridin-4'-yl)phenyl]} disulfide)cobalt(II) diperchlorate
  参考文献：
  名称：

  含硫三联吡啶衍生物的合成、配位性质和在金表面的吸附

  摘要：

  开发了合成有机亲金配体的方法，即含硫 2,2':6',2'-三联吡啶衍生物。研究了具有苯硫酚、二芳基二硫化物和烷基芳基硫化物片段的三联吡​​啶配体与 Coii、Niii 和 Rhiii 盐的络合反应。基于元素分析数据、密度泛函计算和电子能谱确定了所获得的配位化合物的结构。4'-(4-甲基硫烷基)-2,2':6',2"-三联吡啶与Ni(BF4)2配合物的结构也通过X射线衍射分析确定。提出了制备方法金纳米颗粒二聚体聚集体通过吸附在金纳米颗粒表面的配体与过渡金属离子的配位相互作用。

  DOI：

  10.1007/s11172-012-0322-0
• 作为产物：
  描述：

  4'-(4-mercaptophenyl)-2,2':6',2''-terpyridine 在 sodium hydrogensulfite 作用下， 以 氯仿 为溶剂， 反应 20.0h， 以57%的产率得到4',4''''-(dithiodi-4,1-phenylene)bis(2,2':6',2''-terpyridine)
  参考文献：
  名称：

  Surface Junction Effects on the Electron Conduction of Molecular Wires

  摘要：

  Surface junction effects on the electron conduction of p-phenylene-bridged bis(terpyridine)iron oligomers terminated with a ferrocene moiety were quantitatively analyzed by employing three different surface-anchoring terpyridine ligands. The dependence of the electron-transfer rate constant for oxidation of the ferrocene moiety, on the distance between the electrode surface and the ferrocene moiety, x, showed that the attenuation factor, beta(d), which indicates the degree of reduction of k(et) with x, was similar to 0.018 in all cases. However, the absolute k(et) value depended strongly on both electronic and steric factors of the surface-anchoring ligand.

  DOI：

  10.1021/ja910462x

文献信息

• Enzyme electrode, enzyme electrode producing method, sensor and fuel cell each using enzyme electrode
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP1892529A1

  公开（公告）日：2008-02-27

  An amino acid (1040) capable of coordinately binding to a metallic complex (1020) is introduced to an active site (1030) within the enzyme (1000) or another controlled position near the active site. Therefore, when a mediator is introduced into the enzyme, a mediator-introduced position is controlled to be held at or near the active site.

  能够与金属复合物（1020）配位结合的氨基酸（1040）被引入酶（1000）内的活性位点（1030）或活性位点附近的另一个受控位置。因此，当介质被引入酶中时，介质引入的位置被控制在活性位点或活性位点附近。
• ENZYME ELECTRODE, AND SENSOR AND BIOFUEL CELL USING THE SAME
  申请人：Kubo Wataru

  公开号：US20070122689A1

  公开（公告）日：2007-05-31

  The present invention relates to an enzyme electrode for transporting electric charge formed by an oxidation-reduction reaction in an enzyme to a conductive member at a high speed. The enzyme electrode specifically has a π-conjugated metal complex molecule immobilized on the conductive member and the enzyme immobilized on the conductive member through the π-conjugated metal complex molecule.
• ENZYME ELECTRODE, ENZYME ELECTRODE PRODUCING METHOD, SENSOR AND FUEL CELL EACH USING ENZYME ELECTRODE
  申请人：Kubo Wataru

  公开号：US20080102323A1

  公开（公告）日：2008-05-01

  An amino acid capable of coordinately binding to a metallic complex is introduced to an active site within the enzyme or another controlled position near the active site. Therefore, when a mediator is introduced into the enzyme, a mediator-introduced position is controlled to be held at or near the active site.
• DEVICE WITH pi-CONJUGATED METAL COMPLEX IMMOBILIZED SUBSTRATE IN AQUEOUS ELECTROLYTE
  申请人：Kubo Wataru

  公开号：US20090026071A1

  公开（公告）日：2009-01-29

  A π-conjugated metal complex immobilized substrate, in which π-conjugated metal complex molecules are connected to a substrate via a π-conjugated molecular structure, is adapted for observing an electron transfer (redox reaction) of the π-conjugated metal complex molecules in aqueous electrolytes. An electrochemical device including this π-conjugated metal complex immobilized substrate and an aqueous electrolyte with cations having an ion radius of r (m) that is not less than a radius of a sphere inscribed in a clearance formed between the π-conjugated metal complex molecules. The device utilizes an electron transfer (redox reaction) of the π-conjugated metal complex molecules in the aqueous electrolyte.
• US7816025B2
  申请人：——

  公开号：US7816025B2

  公开（公告）日：2010-10-19