3,9-dimethyl-2,4,8,10-tetrathiaspiro[5.5]undecane | 857546-57-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二噻烷
• 英文名称: 3,9-dimethyl-2,4,8,10-tetrathiaspiro[5.5]undecane
• 英文别名: 3,9-dimethyl-2,4,8,10-tetrathia-spiro[5.5]undecane；3,9-Dimethyl-2,4,8,10-tetrathia-spiro[5.5]undecan；3,9-Dimethyl-2,4,8,10-tetrathiaspiro[5.5]undecane
• CAS: 857546-57-7
• 化学式: C₉H₁₆S₄
• 分子量: 252.49
• InChiKey: ARKIJTONQPFRHE-UHFFFAOYSA-N

物化性质

• 沸点：
  393.9±42.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  101
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,9-dimethyl-2,4,8,10-tetrathiaspiro[5.5]undecane 在 正丁基锂 、 对甲苯磺酸 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 14.5h， 生成
  参考文献：
  名称：

  Conformational Analysis of Spiro-bis-dithiepins:  A Peculiar Case of Axial Chirality

  摘要：

  Spiro-bis-dithiepins are synthesized via dehydrative ring expansion in alpha-hydroxyalkyl spiro-bis-dithianes. Atypical of spiranes possessing axial chirality, the two most stable conformers of substituted spiro-bis-dithiepin have virtually colinear double bonds; i.e., each enantiomer exists in a form of two energy degenerate syn and anti conformations. Because of the high polarizability of the vinyl sulfide moiety, spiro-bis-dithiepins bearing electron-withdrawing substituents offer access to two-state systems possessing large dipole moments, which can be modulated by conformational events.

  DOI：

  10.1021/ol062172s
• 作为产物：
  描述：

  戊赤藓四硫醇 在 盐酸 、 乙醇 、 乙醛 作用下， 生成 3,9-dimethyl-2,4,8,10-tetrathiaspiro[5.5]undecane
  参考文献：
  名称：

  Backer; Evenhuis, Recueil des Travaux Chimiques des Pays-Bas, 1937, vol. 56, p. 681,688

  摘要：

  DOI：

文献信息

• HIGH-FLUIDITY POLYCARBONATE COPOLYMER, PROCESS FOR PRODUCTION HIGHLY POLYMERIZED AROMATIC POLYCARBONATE RESIN AND AROMATIC POLYCARBONATE COMPOUND (AS AMENDED)
  申请人：Isahaya Yoshinori

  公开号：US20140206826A1

  公开（公告）日：2014-07-24

  The present inventions provide a novel polycarbonate copolymer having high fluidity and high molecular weight which is formed of a structural unit derived from an aliphatic diol compound and a structural unit derived from an aromatic dihydroxy compound, having a structure represented by the formula (III): having the content of the structural unit derived from the aliphatic diol compound of 1-30 mol %, having the Q-value (280° C., 160 kg load) in the range from 0.02 to 1.0 ml/s, and having the weight average molecular weight (Mw) of 30,000 to 100,000, and an aromatic polycarbonate compound which is formed of a structural unit derived from an aromatic dihydroxy compound which is suitable for a prepolymer for producing a high fluidity polycarbonate copolymer
• HIGH-FLUIDITY POLYCARBONATE COPOLYMER, PROCESS FOR PRODUCTION HIGHLY POLYMERIZED AROMATIC POLYCARBONATE RESIN AND AROMATIC POLYCARBONATE COMPOUND
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20160264726A1

  公开（公告）日：2016-09-15

  The present inventions provide a novel polycarbonate copolymer having high fluidity and high molecular weight which is formed of a structural unit derived from an aliphatic diol compound and a structural unit derived from an aromatic dihydroxy compound, having a structure represented by the formula (III): having the content of the structural unit derived from the aliphatic diol compound of 1-30 mol %, having the Q-value (280° C., 160 kg load) in the range from 0.02 to 1.0 ml/s, and having the weight average molecular weight (Mw) of 30,000 to 100,000, and an aromatic polycarbonate compound which is formed of a structural unit derived from an aromatic dihydroxy compound which is suitable for a prepolymer for producing a high fluidity polycarbonate copolymer.
• US9353216B2
  申请人：——

  公开号：US9353216B2

  公开（公告）日：2016-05-31
• Conformational Analysis of Spiro-bis-dithiepins:  A Peculiar Case of Axial Chirality
  作者：Edmir O. Wade、Roman A. Valiulin、Leslie A. Ruybal、Andrei G. Kutateladze

  DOI：10.1021/ol062172s

  日期：2006.10.1

  Spiro-bis-dithiepins are synthesized via dehydrative ring expansion in alpha-hydroxyalkyl spiro-bis-dithianes. Atypical of spiranes possessing axial chirality, the two most stable conformers of substituted spiro-bis-dithiepin have virtually colinear double bonds; i.e., each enantiomer exists in a form of two energy degenerate syn and anti conformations. Because of the high polarizability of the vinyl sulfide moiety, spiro-bis-dithiepins bearing electron-withdrawing substituents offer access to two-state systems possessing large dipole moments, which can be modulated by conformational events.
• Backer; Evenhuis, Recueil des Travaux Chimiques des Pays-Bas, 1937, vol. 56, p. 681,688
  作者：Backer、Evenhuis

  DOI：——

  日期：——