[4-(2-Methylpropanoyloxy)phenyl] 2-methylpropanoate | 153195-63-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: [4-(2-Methylpropanoyloxy)phenyl] 2-methylpropanoate
• 英文别名: [4-(2-methylpropanoyloxy)phenyl] 2-methylpropanoate
• CAS: 153195-63-2
• 化学式: C₁₄H₁₈O₄
• 分子量: 250.295
• InChiKey: AZKUNDXJFPTQQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [4-(2-Methylpropanoyloxy)phenyl] 2-methylpropanoate 在 三氯化铝 作用下， 生成
  参考文献：
  名称：

  Suzuki, Tsuneo; Tanemura, Kiyoshi; Horaguchi, Takaaki, Journal of Chemical Research, Miniprint, 1996, # 3, p. 735 - 784

  摘要：

  DOI：
• 作为产物：
  描述：

  异丁酸酐 、 对苯二酚 在 硫酸 作用下， 以34.6%的产率得到[4-(2-Methylpropanoyloxy)phenyl] 2-methylpropanoate
  参考文献：
  名称：

  Suzuki, Tsuneo; Tanemura, Kiyoshi; Horaguchi, Takaaki, Journal of Chemical Research, Miniprint, 1996, # 3, p. 735 - 784

  摘要：

  DOI：

文献信息

• Aldol polymerization as a novel polyaddition based on Mukaiyama aldol reaction and its application to the synthesis of optically active polymer
  作者：Kenichi Komura、Shinichi Itsuno、Koichi Ito

  DOI：10.1039/a808357f

  日期：——

  Repetitive Mukaiyama aldol reaction between bis(silyl ketene acetal) and dialdehyde proceeded in the presence of Lewis acid to afford poly(hydroxy ester).

  双(甲硅烷基乙烯酮缩醛)和二醛在路易斯酸存在下进行重复Mukaiyama羟醛反应，得到聚(羟基酯)。
• Liquid crystal photoalignment agent and liquid crystal display including the same
  申请人：Samsung Display Co., Ltd.

  公开号：US11156874B2

  公开（公告）日：2021-10-26

  A liquid crystal photoalignment agent includes: a copolymer of diamine and dianhydride; and a compound Formula 1 below, wherein an amount of the compound of Formula 1 is less than about 10 weight %, based on a total weight of the liquid crystal photoalignment agent: R1 is a substituted or unsubstituted tetravalent organic group derived from an acid dianhydride, wherein the acid dianhydride is at least one of an aliphatic cyclic acid dianhydride or an aromatic acid dianhydride, R2 is a substituted or unsubstituted trivalent organic group derived from an aromatic diamine, at least one of R1 and R2 is substituted with CF3 or a silyl group, R3 is a residue of a compound including a substituted or unsubstituted aromatic group with a carbon number that is equal to or greater than 6, n is 1 to 5, and * represents a point of attachment.

  一种液晶光配向剂包括：二胺和二酐的共聚物；以及下式 1 化合物，其中式 1 化合物的用量占液晶光配向剂总重量的比例小于约 10%： R1 是衍生自酸二酐的取代或未取代的四价有机基团，其中酸二酐是脂肪族环状酸二 酐或芳香族酸二酐中的至少一种，R2 是衍生自芳香族二胺的取代或未取代的三价有机基团、R1 和 R2 中至少有一个被 CF3 或硅烷基取代，R3 是包括碳原子数等于或大于 6 的取代或未取代芳香基团的化合物残基，n 为 1 至 5，* 代表连接点。
• LIQUID CRYSTAL PHOTOALIGNMENT AGENT AND LIQUID CRYSTAL DISPLAY INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20200073182A1

  公开（公告）日：2020-03-05

  A liquid crystal photoalignment agent includes: a copolymer of diamine and dianhydride; and a compound Formula 1 below, wherein an amount of the compound of Formula 1 is less than about 10 weight %, based on a total weight of the liquid crystal photoalignment agent: R 1 is a substituted or unsubstituted tetravalent organic group derived from an acid dianhydride, wherein the acid dianhydride is at least one of an aliphatic cyclic acid dianhydride or an aromatic acid dianhydride, R 2 is a substituted or unsubstituted trivalent organic group derived from an aromatic diamine, at least one of R 1 and R 2 is substituted with CF 3 or a silyl group, R 3 is a residue of a compound including a substituted or unsubstituted aromatic group with a carbon number that is equal to or greater than 6, n is 1 to 5, and * represents a point of attachment.
• Suzuki, Tsuneo; Tanemura, Kiyoshi; Horaguchi, Takaaki, Journal of Chemical Research, Miniprint, 1996, # 3, p. 735 - 784
  作者：Suzuki, Tsuneo、Tanemura, Kiyoshi、Horaguchi, Takaaki、Shimizu, Takahachi

  DOI：——

  日期：——