2,6-Bis-hydroxymethyl-4-methoxy-toluol | 14542-72-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-Bis-hydroxymethyl-4-methoxy-toluol
• 英文别名: [3-(Hydroxymethyl)-5-methoxy-2-methylphenyl]methanol
• CAS: 14542-72-4
• 化学式: C₁₀H₁₄O₃
• 分子量: 182.219
• InChiKey: MNSHIYLDHKJOJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,6-Bis-hydroxymethyl-4-methoxy-toluol 在 三溴化磷 、 sodium iodide 作用下， 生成 2,6-Bis-iodmethyl-4-methoxy-toluol
  参考文献：
  名称：

  Aromatic Molecules Bearing Substituents within the Cavity of the π-Electron Cloud. Synthesis of trans-15,16-Dimethyldihydropyrene

  摘要：

  DOI：

  10.1021/ja00983a028
• 作为产物：
  描述：

  2,6-Dicyano-4-methoxy-toluol 在 盐酸 、 氢氧化钾 、 lithium aluminium tetrahydride 作用下， 生成 2,6-Bis-hydroxymethyl-4-methoxy-toluol
  参考文献：
  名称：

  Aromatic Molecules Bearing Substituents within the Cavity of the π-Electron Cloud. Synthesis of trans-15,16-Dimethyldihydropyrene

  摘要：

  DOI：

  10.1021/ja00983a028

文献信息

• METHOD FOR PRODUCING CYANOACETIC ACID, METHOD FOR PRODUCING CYANOACETIC ACID DERIVATIVE AND METHOD FOR PRODUCING METAL CONTAINING COMPOUND
  申请人：IKEMIZU Dai

  公开号：US20130253213A1

  公开（公告）日：2013-09-26

  Provided is a method for producing cyanoacetic acid in a hydrolysis reaction of a predetermined cyanoacetate in the presence of an acid catalyst. Further, are provided methods for producing a cyanoacetic acid derivative and a metal containing compound by using the produced cyanoacetic acid as a staring material. Herein, the method for producing cyanoacetic acid enables the content of a malonic acid byproduct generated in the hydrolysis reaction to be greatly lowered, allowing the produced cyanoacetic acid to be used as a starting material without any purification treatments. Those advantageous effects result in the great improvement in the purity and yields of the cyanoacetic acid derivative and the metal containing compound produced by said cyanoacetic acid. Accordingly, the above mentioned methods make it possible to produce cyanoacetic acid, the cyanoacetic acid derivative and the metal containing compound, as excellent in the productivity and economical efficiency.

  提供了一种在酸催化剂存在下，通过水解预定的氰乙酸盐生成氰乙酸的方法。此外，提供了利用生成的氰乙酸作为起始物质来生产氰乙酸衍生物和含金属化合物的方法。在这种生产氰乙酸的方法中，使得在水解反应中生成的丙二酸副产物的含量大大降低，使得生成的氰乙酸可以作为起始物质而无需任何纯化处理。这些有利效果导致了通过该氰乙酸生成的氰乙酸衍生物和含金属化合物的纯度和产量显著提高。因此，上述方法使得能够以高生产率和经济效益生产氰乙酸、氰乙酸衍生物和含金属化合物。
• HIGHLY BASIC IONOMERS AND MEMBRANES AND ANION/HYDROXIDE EXCHANGE FUEL CELLS COMPRISING THE IONOMERS AND MEMBRANES
  申请人：Yan Yushan

  公开号：US20110237690A1

  公开（公告）日：2011-09-29

  This invention provides a family of functionalized polymers capable of forming membranes having exceptional OH − ionic conductivity as well as advantageous mechanical properties. The invention also provides membranes including the provided polymers and AEMFC/HEMFC fuel cells including such membranes. In a preferred embodiment, preferred function groups include a quaternary phosphonium, and in a more preferred embodiment the provided polymer is (tris(2,4,6-trimethoxyphenyl) phosphine) 3 functionalized phosphonium polysulfone hydroxide.
• US8641949B2
  申请人：——

  公开号：US8641949B2

  公开（公告）日：2014-02-04
• Aromatic Molecules Bearing Substituents within the Cavity of the π-Electron Cloud. Synthesis of <i>trans</i>-15,16-Dimethyldihydropyrene
  作者：V. Boekelheide、Joseph B. Phillips

  DOI：10.1021/ja00983a028

  日期：1967.3