6-(allyloxy)naphthalen-2-ol | 111359-66-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-(allyloxy)naphthalen-2-ol
• 英文别名: 6-(2-propenyloxy)naphthalen-2-ol；6-[(Prop-2-en-1-yl)oxy]naphthalen-2-ol；6-prop-2-enoxynaphthalen-2-ol
• CAS: 111359-66-1
• 化学式: C₁₃H₁₂O₂
• 分子量: 200.237
• InChiKey: GJTQNBCIUNVBQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-(allyloxy)naphthalen-2-ol 在 potassium carbonate 、 三乙胺 作用下， 以 丙酮 、 乙腈 为溶剂， 反应 2.25h， 生成 (3-((6-(allyloxy)naphthalen-2-yl)oxy)prop-1-yn-1-yl)silver
  参考文献：
  名称：

  Assembly of organosilver(I) frameworks with terminal ethynide and ethenyl groups on separate pendent arms attached to an aromatic ring

  摘要：

  A series of eight silver(I) trifluoroacetate complexes based on aromatic ligands bearing terminal ethynyl and ethenyl groups on separate pendent arms has been synthesized. Single-crystal X-ray analysis of the complexes provided detailed information on the influence of argentophilicity, ligand disposition and orientation, and the co-existence of three types of silver-carbon bonding (silver-ethynide, silver-ethenyl and silver-aromatic) in coordination network construction, as well as the roles played by weak pi-pi stacking and anion-pi interactions in supramolecular assembly. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.06.082
• 作为产物：
  描述：

  6-Bromo-2-(2-propenyloxy)naphthalene 以50%的产率得到
  参考文献：
  名称：

  MISRA, RAJ N.

  摘要：

  DOI：

文献信息

• Metal-Free Sequential C(sp²)–H/OH and C(sp³)–H Aminations of Nitrosoarenes and <i>N</i>-Heterocycles to Ring-Fused Imidazoles
  作者：Anisha Purkait、Subhra Kanti Roy、Hemant Kumar Srivastava、Chandan K. Jana

  DOI：10.1021/acs.orglett.7b00832

  日期：2017.5.19

  Hydrogen bond assisted ortho-selective C(sp2)–H amination of nitrosoarenes and subsequent α-C(sp3)-H functionalization of aliphatic amines is achieved under metal-free conditions. The annulation of nitrosoarenes and 2-hydroxy-C-nitroso compounds with N-heterocycles provides a facile excess to a wide range of biologically relevant ring-fused benzimidazoles and structurally novel polycyclic imidazoles

  氢键辅助的亚硝基芳烃的邻位选择性C（sp 2）-H氨基化和随后的α-C（sp 3）-H脂肪族胺的官能化在无金属条件下实现。亚硝基芳烃和2-羟基-C-亚硝基化合物与N-杂环的环化分别提供了相对于广泛的生物学相关的环稠合的苯并咪唑和结构上新颖的多环咪唑的简便过量。发现在卤代亚硝基芳烃的C（sp 2）–H胺化过程中，亲核芳香族氢取代（S N ArH）比经典S N Ar反应更可取。
• Synthesis, Resolution, and Absolute Configuration of Chiral Tris(2-pyridylmethyl)amine-Based Hemicryptophane Molecular Cages
  作者：Dawei Zhang、Benjamin Bousquet、Jean-Christophe Mulatier、Delphine Pitrat、Marion Jean、Nicolas Vanthuyne、Laure Guy、Jean-Pierre Dutasta、Alexandre Martinez

  DOI：10.1021/acs.joc.7b00559

  日期：2017.6.16

  racemic mixture of each hemicryptophane host can be readily resolved by chiral HPLC, giving an easy access to the enantiopure molecular cages of which absolute configurations have been assigned by ECD spectroscopy. These new hemicryptophanes are available chemical platforms ready to use for various purposes due to the versatile metal complexation properties of the TPA unit. A Zn(II)@hemicryptophane

  报道了一种新的类半色氨酸笼的合成，表征和手性，该笼结合了环三藜芦烯单元和三（2-吡啶基甲基）胺（TPA）部分。改变这两个单元之间的接头可以改变空腔的尺寸和形状。合成简单有效，提供了克级的笼状化合物。每个半色氨酸宿主的外消旋混合物可通过手性HPLC轻松拆分，可轻松进入对映体纯分子笼，其绝对构型已通过ECD光谱确定。由于TPA装置具有多种金属络合特性，因此这些新的半色氨酸是可用于各种目的的化学平台。
• Organocatalytic Friedel-Crafts Alkylation/Lactonization Reaction of Naphthols with 3-Trifluoroethylidene Oxindoles: The Asymmetric Synthesis of Dihydrocoumarins
  作者：Yun-Long Zhao、Qin-Xin Lou、Long-Sheng Wang、Wen-Hui Hu、Jun-Ling Zhao

  DOI：10.1002/anie.201609390

  日期：2017.1.2

  Naphthols and 3‐trifluoroethylidene oxindoles were found to undergo an asymmetric Friedel–Crafts alkylation/lactonization reaction, catalyzed by only 2.5 mol % of a quinine‐derived squaramide catalyst, to afford the corresponding α‐aryl‐β‐trifluoromethyl dihydrocoumarin derivatives in high yields (up to 99 %) with excellent enantio‐ and diastereoselectivities (up to 98 % ee, >20:1 d.r.). Importantly

  发现萘酚和3-三氟乙叉基吲哚会发生不对称的Friedel-Crafts烷基化/内酯化反应，仅需2.5摩尔％奎宁衍生的方酰胺催化剂即可催化，从而以高收率提供相应的α-芳基-β-三氟甲基二氢香豆素衍生物（高达99％）具有优异的对映异构和非对映异构选择性（高达98％ee，> 20：1 dr）。重要的是，在温和的反应条件下，内酯化是通过在羟吲哚的酰胺基序处萘酚羟基的亲核攻击而进行的。该方案代表了通过有效的分子内酰胺CN键断裂和酯化过程形成二氢香豆素的新策略。
• OXAZINE COMPOUND, COMPOSITION AND CURED PRODUCT
  申请人：DIC Corporation

  公开号：US20180362479A1

  公开（公告）日：2018-12-20

  The present invention provides an oxazine compound which contains a group having an aromatic ring structure and a plurality of specified carbon-carbon double bond structure so as to achieve an object. The present invention further provides a composition containing the oxazine compound of the present invention, a cured product containing the composition, and a laminate having a layer of the cured product. The present invention further still provides a composition for a heat-resistant material and a composition for an electronic material, which contain the composition containing the oxazine compound of the present invention so as to achieve the object.

  本发明提供了一种含有芳香环结构和多个指定碳-碳双键结构的噁嗪化合物，以达到目的。本发明还提供了一种含有本发明的噁嗪化合物的组合物，一种含有该组合物的固化产物以及具有固化产物层的层压板。本发明还进一步提供了一种耐热材料的组合物和一种电子材料的组合物，其中包含本发明的噁嗪化合物组合物以达到目的。
• Oxazine compound, composition and cured product
  申请人：DIC Corporation

  公开号：US10399312B2

  公开（公告）日：2019-09-03

  The present invention provides an oxazine compound which contains a group having an aromatic ring structure and a plurality of specified carbon-carbon double bond structure so as to achieve an object. The present invention further provides a composition containing the oxazine compound of the present invention, a cured product containing the composition, and a laminate having the cured product layer. The present invention further still provides a composition for a heat-resistant material and a composition for an electronic material, which contain the composition containing the oxazine compound of the present invention so as to achieve an object.

  本发明提供了一种含有芳香环结构和多个特定碳-碳双键结构的噁嗪化合物，以达到一定目的。本发明还提供了一种包含本发明的噁嗪化合物的组合物、包含该组合物的固化产物以及具有固化产物层的层压板。本发明还进一步提供了一种用于耐热材料的组合物和用于电子材料的组合物，其中包含本发明的噁嗪化合物组合物，以达到一定目的。