phenylgallium dichloride | 1073-46-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenylgallium dichloride
• 英文别名: PhGaCl2；dichloro(phenyl)gallane
• CAS: 1073-46-7
• 化学式: C₆H₅Cl₂Ga
• 分子量: 217.735
• InChiKey: BOKSQEQJGGNVKR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.86
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  phenylgallium dichloride 在 (CH₃)3N 作用下， 以 苯 为溶剂， 生成 chloro(phenyl)(propylthio)gallane triethylamine
  参考文献：
  名称：

  Hoffmann, G. G.; Meixner, H., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：

文献信息

• Synthesis of 9‐Gallafluorenes via Group 12 Metal Biphenylenes
  作者：Michael Gast、Julian Anton、Gerald Linti

  DOI：10.1002/ejic.201800364

  日期：2018.9.30

  9‐Gallafluorenes were synthesized from 9‐zincafluorene·tmeda as an alternative to 2,2′‐biphenylenmercury and 2,2′‐dilithiobiphenyl. The zincafluorene was found to be only one possible form of a biphenylene zinc. In dependence of the synthetic conditions a dimeric zinc bridged structure resulted, too. The gallafluorenes obtained were stabilized by nitrogen donors or formed dimers in case of 9‐tert‐butoxygallafluorene

  9-加勒芴是由9-锌芴· tmeda合成的，可替代2,2'-联苯汞和2,2'-二硫代联苯。发现芴芴锌只是联苯锌的一种可能形式。根据合成条件，也产生了二聚体锌桥联结构。在9-叔丁氧基加氢芴的情况下，得到的加氢芴通过氮供体或形成的二聚体来稳定。这意味着，所有这些衍生物在平面杂芴部分中均含有四个配位的镓中心。苯基取代的加勒芴作为tmeda加合物以及分子内稳定的邻苯二甲酸酯对-（二甲基氨基）甲基苯基衍生物的发光性质进行了研究，这两种化合物的发光性质相似，不仅在可见光区域显示荧光，而且显示磷光。所有新的金属芴均已通过X射线晶体学表征。
• Reactions of (Me3SiCH2)2AsSiMe3 with gallium halides; crystal structure and dynamic NMR study of the dimer [[(Me3SiCH2)2As]2GaBr]2
  作者：Andrew P. Purdy、Richard L. Wells、Andrew T. McPhail、Colin G. Pitt

  DOI：10.1021/om00153a012

  日期：1987.10.1
• Bis(dimethylamido) Complexes of Alkyl- and Phenylgallium. Useful Precursors to the RGa²⁺ Synthon
  作者：Jolin A. Jegier、Bing Luo、Carrie E. Buss、Wayne L. Gladfelter

  DOI：10.1021/ic010724r

  日期：2001.11.1

  Alkyl- and phenylbis(dimethylamido)gallium, [RGa(NMe2)(2)](2) [R = Me (1), Et (2), Bu-n (3), (n)Hx (4), and Ph (5)], were synthesized by reactions of LiNMe2 with (RGaCl2)(2). The crystal structure of compound 1 was a disordered mixture of anti and syn isomers, with the ratio of anti/syn being 64:36, which was consistent with the ratio (57:43) found in the H-1 NMR spectrum. The Ga2N2 cores of the anti and syn structures were nonplanar. H-1 NMR spectra indicated the presence of both anti and syn isomers for all of the other substituents. H-1 NMR and mass spectra indicated that a species with the general formula of R3Ga2(NMe2)(3) was formed when these compounds were heated at high temperatures.
• HOFFMANN, G. G.;MEIXNER, H., Z. ANORG. UND ALLG. CHEM., 1985, 523, N 4, 121-134
  作者：HOFFMANN, G. G.、MEIXNER, H.

  DOI：——

  日期：——