N,N-dibutylthiocarbamic acid | 57442-69-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: N,N-dibutylthiocarbamic acid
• 英文别名: dibutylcarbamothioic S-acid
• CAS: 57442-69-0
• 化学式: C₉H₁₈NOS*H
• 分子量: 189.322
• InChiKey: FFCKSXBQQVKELL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  21.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  银 、 N,N-dibutylthiocarbamic acid 生成 silver(I) dibutylcarbamothioate
  参考文献：
  名称：

  Akerstroem, S., Arkiv foer Kemi, 1965, vol. 24, p. 479 - 490

  摘要：

  DOI：

文献信息

• PRESSURE-SENSITIVE ADHESIVE SHEET WITH IMPROVED WEATHERABILITY
  申请人：NITTO BELGIUM N.V

  公开号：EP3786242A1

  公开（公告）日：2021-03-03

  The disclosure relates to a pressure-sensitive adhesive composition comprising: an acrylic polymer with acrylic acid functional groups; an epoxy-based crosslinking agent at a content of 3 parts per weight or more based on 100 parts per weight of the acrylic polymer; and a UV-absorber at a content of 2 parts per weight or more based on 100 parts per weight of the acrylic polymer. In addition, a surface protection sheet comprising a carrier and a pressure-sensitive adhesive layer formed of the aforementioned pressure-sensitive adhesive composition is described, as well as the use of the aforementioned surface protection sheet for outdoor surface protection. The surface protection sheet exhibits excellent weatherability resistance, adhesion properties on different substrate surfaces, oxidation resistance, advantageous anti-residue properties upon peeling and low surface contaminating properties.

  本公开涉及一种压敏胶组合物，该组合物包括：一种具有丙烯酸官能团的丙烯酸聚合物；一种环氧基交联剂，以每 100 重量份的丙烯酸聚合物为基准，其含量为 3 重量份或以上；以及一种紫外线吸收剂，以每 100 重量份的丙烯酸聚合物为基准，其含量为 2 重量份或以上。此外，还介绍了一种由载体和由上述压敏胶组合物形成的压敏胶层组成的表面保护膜，以及将上述表面保护膜用于户外表面保护的方法。该表面保护膜具有优异的耐候性、在不同基材表面的粘附性、抗氧化性、剥离后的抗残留性以及低表面污染性。
• Pressure sensitive adhesive composition, articles made therewith and method of use
  申请人：3M Innovative Properties Company

  公开号：US20030215630A1

  公开（公告）日：2003-11-20

  A pressure sensitive adhesive composition is described, comprising the reaction product of a copolymer and a bisamide crosslinking agent, (A) the copolymer comprising the reaction product of (i) a (meth)acrylate ester of a non-tertiary alcohol in which the alkyl group contains between 1 and 4 carbon atoms, inclusive, and (ii) a carboxylic acid-functional, ethylenically unsaturated co-monomer, and (B) a bisamide crosslinking agent having the formula: 1 where, R 1 and R 3 independently, are selected from the group consisting of H and C n H 2n+1 , n is an integer ranging from 1 to 5, R 2 is a divalent radical selected from the group consisting of benzeno (—C 6 H 4 —), substituted benzeno, triazine, C m H 2m , and combinations thereof, m is an integer ranging from 1 to 10, and the relative amounts of the carboxylic acid-functional, ethylenically unsaturated co-monomer and the bisamide crosslinking agent providing a ratio of the number of equivalents of amide groups to the number of equivalents of carboxylic acid groups of less than about 0.1. Articles made with the pressure sensitive adhesive composition and methods for its use are also described.

  描述了一种压敏型粘合剂组合物，包括共聚物和双酰胺交联剂的反应产物，(A)共聚物包括(i)非叔醇的(甲基)丙烯酸酯（其中烷基含有 1 至 4 个碳原子（含 4 个））和(ii)具有羧酸官能团的乙烯基不饱和共聚单体，以及(B)具有以下式子的双酰胺交联剂的反应产物： 1 其中 R 1 和 R 3 分别选自 H 和 C 组成的组 n H 2n+1 , n 是 1 至 5 的整数、 R 2 是二价基，选自由苯并[-C 6 H 4 -）、取代的苯并芘、三嗪、C m H 2m 及其组合、 m 是 1-10 之间的整数，以及 羧酸官能团、乙烯基不饱和共聚单体和双酰胺交联剂的相对量，使酰胺基团的当量数与羧酸基团的当量数之比小于约 0.1。此外，还描述了用压敏胶组合物制成的物品及其使用方法。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B7, 1.20.6.1, page 99 - 102
  作者：

  DOI：——

  日期：——