bis(monomethyl phthalate)dimethyltin | 915772-90-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(monomethyl phthalate)dimethyltin
• CAS: 915772-90-6
• 化学式: C₂₀H₂₀O₈Sn
• 分子量: 507.084
• InChiKey: WABHUFMSXNZEKV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  苯酐 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 9.0h， 生成 bis(monomethyl phthalate)dimethyltin
  参考文献：
  名称：

  Diorganotin complexes of carboxylates: synthesis and characterization

  摘要：

  Diorganotin complexes of monoisopropyl and monomethyl nadiate, succinate, and phthalate were synthesized and characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, and Sn-119 NMR spectroscopic techniques. The spectroscopic investigation demonstrated that carboxylate is bidentate in the diorganotin complexes. On the basis of (1)J(Sn-119-C-13) and (2)J(Sn-119-H-1) values, C-Sn-C bond angles were also calculated. The newly synthesized complexes were also screened for their antibacterial activities against Gram-positive and Gram-negative pathogenic strains of bacteria.

  DOI：

  10.1080/00958972.2013.775428

文献信息

• Synthesis characterization and biological study of diorganotin(IV) complexes of monomethyl phthalate
  作者：Wajid Rehman、Musa Kaleem Baloch、Amin Badshah、Saqib Ali

  DOI：10.1016/j.saa.2005.12.031

  日期：2006.11

  coordination compounds of some organotin(IV) chlorides with monomethyl phthalate is reported; the ligand molecules appear to be bound to the tin atom through carbonyl oxygen atoms. Their structures have been characterized by elemental analyses, molar conductance, and bonding in these complexes is discussed in terms of their IR, (1)H, (13)C, (119)Sn NMR and (119 m)Sn Mössbauer spectral studies. The spectroscopic

  报道了一些有机锡（IV）氯化物与邻苯二甲酸单甲酯的合成和表征。配体分子似乎通过羰基氧原子与锡原子结合。它们的结构已通过元素分析，摩尔电导和在这些配合物中的键合进行了表征，分别通过IR，（1）H，（13）C，（119）Sn NMR和（119m）SnMössbauer光谱研究进行了讨论。获得的光谱结果与建议的2：1化学计量完全吻合。已针对多种细菌筛选了可溶于DMSO的复合物，获得的结果非常有希望。还已经在白化病大鼠中确定了LD（50）值。一些复合物还表现出高抗炎活性。