双(N-BZ-二硫代氨基甲酸)镍(II) | 82421-73-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 双(N-BZ-二硫代氨基甲酸)镍(II)
• 英文名称: bis(N-Bz-dithiocarbamato)nickel(II)
• CAS: 82421-73-6
• 化学式: C₁₆H₁₆N₂NiS₄
• 分子量: 423.27
• InChiKey: RNJCVKBFKHTKGY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.51
• 重原子数：
  23.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  24.06
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  双(N-BZ-二硫代氨基甲酸)镍(II) 生成 镍
  参考文献：
  名称：

  Kinetic analysis of thermogravimetric data on some nickel(II) N-alkyldithiocarbamates

  摘要：

  DOI：

  10.1007/bf01911905

文献信息

• Carbodithioato derivatives of weak nitrogenous nucleophiles II. Non-direct syntheses and structural studies of Ni(II) N-carbodithioates with substituted ureas, carbamic esters and sulfonamides
  作者：C.C. Hadjikostas、G.A. Katsoulos、M.P. Sigalas、C.A. Tsipis

  DOI：10.1016/s0020-1693(00)83448-9

  日期：1989.9

  Abstract In a sequence to out earlier reports on electrophilic substitution reactions of Ni(II) N -alkyldithio- carbamates, we here report the isolation of nickel(II) complexes of the type Ni[S 2 CN(E)R] 2 , (E = electrophile), and their characterization by chemical analysis, as well as magnetic and spectral studies. A thorough inspection of the spectroscopic and magnetic data of the novel compounds

  摘要在一系列有关Ni（II）N-烷基二硫代氨基甲酸酯的亲电取代反应的早期报道中，我们在此报告了Ni [S 2 CN（E）R] 2型镍（II）配合物的分离，（ E =亲电试剂），并通过化学分析，磁和光谱研究对其进行表征。对新化合物的光谱和磁学数据的彻底检查清楚地表明了该复合物中碳二硫代脲配体的二齿键合模式及其正方形平面构型。因此，所有新化合物都具有大致相似的结构，包括方形NiS 4发色团。
• Convenient, straightforward routes to carbodithioato derivatives of weak nitrogenous nucleophiles
  作者：C.C. Hadjikostas、G.A. Katsoulos、M.P. Sigalas、C.A. Tsipis、N.V. Duffy

  DOI：10.1016/s0277-5387(00)81170-5

  日期：1989.1
• Carbodithioato derivatives of weak nitrogenous nucleophiles
  作者：N.V. Duffy、C.C. Hadjikostas、G.A. Katsoulos、M.P. Sigalas、J.B. Zimmerman

  DOI：10.1016/0040-6031(93)85071-g

  日期：1993.7

  Mass spectral and thermal studies by TG/DTG analysis of Ni[S2CN(E)R]2 complexes (where E is CONHPh, CONPh2, COOEt or ArSO2, and R is Me, Bu(n) or Bz) in dynamic nitrogen atmosphere have been carried out to determine their modes of decomposition. In this respect, fragmentation patterns are given and possible mechanisms are discussed. Reaction orders were estimated employing the Freeman-Carroll equation. A kinetic analysis of the thermogravimetric data was performed using the Coats-Redfern equation to determine the apparent activation energies and the pre-exponential factor of the Arrhenius equation.
• Hadjikostas, C. C.; Katsoulos, G. A.; Sigalas, M. P., Canadian Journal of Chemistry, 1989, vol. 67, p. 902 - 909
  作者：Hadjikostas, C. C.、Katsoulos, G. A.、Sigalas, M. P.、Tsipis, C. A.

  DOI：——

  日期：——