1,1-Dianilinocyclopropane | 6246-99-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,1-Dianilinocyclopropane
• 英文别名: 1,1-Dianilinocyclopropan；(1-Anilinocyclopropyl)-phenyl-amine；1-N,1-N'-diphenylcyclopropane-1,1-diamine
• CAS: 6246-99-7
• 化学式: C₁₅H₁₆N₂
• 分子量: 224.305
• InChiKey: UGKVYZSYQUKLMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-乙氧基-1-环丙醇 、 苯胺 生成 1,1-Dianilinocyclopropane
  参考文献：
  名称：

  Cyclopropanone Reactions of 1-Ethoxycyclopropyl Alcohol and Acetate¹

  摘要：

  DOI：

  10.1021/ja00974a088

文献信息

• Practical Synthesis of<i>N</i>-Cyclopropylanilines via Direct Condensation of Anilines with [(1-Ethoxycyclopropyl)oxy]trimethylsilane
  作者：Yasuo Yoshida、Kazuto Umezu、Yusuke Hamada、Naoya Atsumi、Fumiya Tabuchi

  DOI：10.1055/s-2003-42072

  日期：——

  N-Cyclopropylanilines were obtained in high yield through the condensation reaction of anilines with [(1-ethoxycyclopropyl)oxy]trimethylsilane by a simple two-steps operating process, without purification of the intermediate, 1-alkoxy-1-anilinocyclopropane.

  N-环丙基苯胺通过苯胺与[(1-乙氧基环丙基)氧]三甲基硅烷的缩合反应，以高产率获得，采用简单的两步操作过程，无需对中间体1-烷氧基-1-苯胺环丙烷进行纯化。
• Aryl azide-allene cycloaddition. The contrasting behavior of two simple allenes, 1,2-cyclononadiene and 1,2-propadiene
  作者：Donald K. Wedegaertner、Rangin K. Kattak、Isom Harrison、Sharon K. Cristie

  DOI：10.1021/jo00014a026

  日期：1991.7

  1,2-Cyclononadiene (1) reacts with phenyl azide (2a) and 4-bromophenyl azide (2b) to give conjugated triazoline adducts 3a and 3b, respectively. (R)-(+)-1 and 2a react to give (S)-(+)-3a, which is consistent with a concerted cycloaddition mechanism. The reaction of 1,2-propadiene (6) and 2a gives triazoles 8 and 10 plus compound 18 in nearly equal amounts. The formation of these products is rationalized by a scheme involving initial formation of triazolines 7 and 9. Triazoline 3a is slowly isomerized by sodium ethoxide or N,N-dimethylaniline to triazole 20.
• WEDEGAERTHER, DONALD K.;KATTAK, RANGIN K.;HARRISON, ISOM;CRISTIE, SHARON +, J. ORG. CHEM., 56,(1991) N4, C. 4463-4467
  作者：WEDEGAERTHER, DONALD K.、KATTAK, RANGIN K.、HARRISON, ISOM、CRISTIE, SHARON +

  DOI：——

  日期：——