6,13-dichloro-benzo[5,6][1,4]thiazino[2,3-b]phenothiazine | 32616-49-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 6,13-dichloro-benzo[5,6][1,4]thiazino[2,3-b]phenothiazine
• 英文别名: 6,13-Dichlortriphenodithiazin；6,13-Dichlor-triphenothiazin；6,13-Dichloro-[1,4]benzothiazino[2,3-b]phenothiazine
• CAS: 32616-49-2
• 化学式: C₁₈H₈Cl₂N₂S₂
• 分子量: 387.313
• InChiKey: XMXOJQNZLAZTPV-UHFFFAOYSA-N

物化性质

• 熔点：
  426 °C
• 沸点：
  412.9±45.0 °C(Predicted)
• 密度：
  1.63±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  75.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6,13-dichloro-benzo[5,6][1,4]thiazino[2,3-b]phenothiazine 以52%的产率得到
  参考文献：
  名称：

  NISHI HISAO; MURAYAMA MASATOSHI, NIXON KAGAKU KAJSI, NIRRON KAGAKU KAISNI, J. CHEM. SOS. JAR., CHEM. AND I+

  摘要：

  DOI：
• 作为产物：
  描述：

  3H-苯并噻嗪-3-酮,1,2,4-三氯- 以46%的产率得到
  参考文献：
  名称：

  NISHI HISAO; KUBO MASAO; TOKITA SUMIO; EJIMA AKIO; MURAYAMA MASATOSHI, NIXON KAGAKU KAJSI, NIRRON KAGAKU

  摘要：

  DOI：

文献信息

• Synthesis of [1,4]benzoxazino[2,3-b]phenoxazines and [1,4]benzothiazino[2,3-b]phenothiazines
  作者：R. L. Mital、S. K. Jain

  DOI：10.1039/j39710001875

  日期：——

  A number of substituted 6,13-dihalogenotriphenodioxazines have been synthesised (a) by condensing halogeno-p-benzoquinones with arylamines followed by cyclisation of the resulting bisarylamino-quinones with benzoyl chloride in nitrobenzene and (b) by condensing halogeno-p-benzoquinones with o-aminophenols in the presence of anhydrous sodium acetate in an alcoholic medium. A few triphenodithiazines

  已经合成了许多取代的6,13-​​二卤代三苯并二恶嗪（a）通过将卤代对苯甲醌与芳胺缩合，然后将生成的双芳基氨基苯醌与苯甲酰氯在硝基苯中环化，以及（b）通过将卤代对苯甲醌与苯甲酰氯缩合而合成。在无水乙酸钠存在下，在酒精介质中邻氨基苯酚。已经通过将邻氨基苯硫醇锌锌与卤代对苯醌醌缩合制备了一些三苯并二噻嗪。
• NISHI, HISAO;FURUKAWA, TADAHIRO;KITAHARA, KIYOSHI, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1984, N 3, 522-524
  作者：NISHI, HISAO、FURUKAWA, TADAHIRO、KITAHARA, KIYOSHI

  DOI：——

  日期：——
• NEW ABSORBER FOR ORGANIC HETEROJUNCTION SOLAR CELLS
  申请人：BASF SE

  公开号：EP3036782B1

  公开（公告）日：2019-10-09
• [EN] NEW ABSORBER FOR ORGANIC HETEROJUNCTION SOLAR CELLS<br/>[FR] NOUVEL ABSORBEUR POUR CELLULES SOLAIRES ORGANIQUES À HÉTÉROJONCTION
  申请人：BASF SE

  公开号：WO2015024851A1

  公开（公告）日：2015-02-26

  The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described below, or the acceptor substance comprises or consists of one or more compounds of formula (I) described below, or the donor substance comprises or consists of a first compound of formula (I) described below and the acceptor substance comprises a second compound of formula (I) described below with the proviso that the first and second compound are not the same, as well as to an organic solar cell or photodetector comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described below for use as donor substance or as acceptor substance in a photoactive material.