申请人:FUJI PHOTO FILM CO., LTD.
公开号:EP0177033A2
公开(公告)日:1986-04-09
A heat-developable light-sensitive material is described, containing a compound represented by formula (1)
wherein R, represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted cycloalkylene group, a substituted or unsubstituted alkenylene group, a substituted or uasubstituted alkynylene group, a substituted or unsubstituted aralkylene group, a substituted or unsubstituted arylene group, or a substituted or unsubstituted divalent heterocyclic group; R2 represents a hydrogen atom, a substituted or unsubstituted alkyl group; R3 represents an alkyl group, an alkoxyl group, a halogen atom, an acylamino group, a sulfonylamino group, an alkylamino group, a dialkylamino group, an alkylsulfonyl group, an arylsulfonyl group, a cyano group, a substituted or unsubstituted carbamoyl group, a substituted or unsubstituted sulfamoyl group or an alkoxycarbonyl group; X represents a divalent group selected from
(wherein R4 represents a hydrogen atom, a substituted or unsubstituted alkyl group),
(wherein R5 represents a substituted or unsubstituted alkyl group), and
M represents an alkali metal, an alkaline earth metal, a quaternary ammonium group, or an ammonium group represented by BH (wherein B represents an organic base); is an integer of 0 to 3; and m and n are each an integer of 1 or 2, such that the electric charge of carboxylate anion is equivalent to that of M.
This material is improved in activity and storage stability. That is, the material providing an image of high density and decreased fog, and which even when stored under high temperature high humidity conditions, maintained good photographic performance.
所述的一种热显影光敏材料含有由式(1)代表的化合物
其中 R 代表氢原子、取代或未取代的烷基、取代或未取代的环烷基、取代或未取代的烯基、取代或未取代的炔基、取代或未取代的芳基、取代或未取代的芳基、取代或未取代的杂环基、取代或未取代的亚烷基、取代或未取代的环亚烷基、取代或未取代的烯基、取代或未 取代的炔基、取代或未取代的芳基、取代或未取代的二价杂环基;R2 代表氢原子、取代或未取代的烷基; R3 代表烷基、烷氧基、卤素原子、酰氨基、磺酰氨基、烷基氨基、二烷基氨基、烷基磺酰基、芳基磺酰基、氰基、取代或未取代的氨基甲酰基、取代或未取代的氨基磺酰基或烷氧羰基; X 代表选自以下各项的二价基团: 1.
(其中 R4 代表氢原子、取代或未取代的烷基)、
(其中 R5 代表取代或未取代的烷基),以及
M 代表碱金属、碱土金属、季铵基团或由 BH 代表的铵基团(其中 B 代表有机碱);是 0 至 3 的整数;m 和 n 分别是 1 或 2 的整数,从而使羧酸阴离子的电荷与 M 的电荷相等。
这种材料在活性和储存稳定性方面都有所改进。也就是说,这种材料能提供高密度图像,减少雾气,即使在高温高湿条件下储存,也能保持良好的照相性能。