(1H,1H-heptafluoro-butyl)-vinyl ether | 356-00-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: (1H,1H-heptafluoro-butyl)-vinyl ether
• 英文别名: 1H,1H-Heptafluor-1-vinyloxy-butan；(1H,1H-Heptafluor-butyl)-vinyl-aether；4-(Ethenyloxy)-1,1,1,2,2,3,3-heptafluorobutane；4-ethenoxy-1,1,1,2,2,3,3-heptafluorobutane
• CAS: 356-00-3
• 化学式: C₆H₅F₇O
• 分子量: 226.094
• InChiKey: UDAAMHMYEJUEDJ-UHFFFAOYSA-N

物化性质

• 沸点：
  36 °C(Press: 140 Torr)
• 密度：
  1.343 g/cm3(Temp: 26 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  8

安全信息

• 海关编码：
  2909199090

反应信息

• 作为产物：
  描述：

  4-(2-chloro-ethoxy)-1,1,1,2,2,3,3-heptafluoro-butane 在 丙醇 、 氢氧化钾 作用下， 生成 (1H,1H-heptafluoro-butyl)-vinyl ether
  参考文献：
  名称：

  Brey; Tarrant, Journal of the American Chemical Society, 1957, vol. 79, p. 6533,6534,6536

  摘要：

  DOI：

文献信息

• Fluorine-containing polymer for paints and paint composition containing the polymer
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP0459369A1

  公开（公告）日：1991-12-04

  A fluorine-containing copolymer for paints, having Mn of 5000 to 50000 and Mw/Mn of 2 to 10, which consists essentially of 30 to 70 % by mole of the fluoroolefin unit, 15 to 45 % by mole of the vinyl ether or vinyl ester unit, 1 to 30 % by mole of the hydroxyalkyl vinyl ether unit, and 4 to 30 % by mole of the carboxyl-containing unit wherein the carboxyl group is neutralized in an amount of 30 % or more with ammonia or a tertiary amine. This copolymer can give a good coating film without water spot and dewetting as well as with a good levelling property, while maintaining the excellent properties which a fluorine resin has by nature.

  一种用于涂料的含氟共聚物，其 Mn 为 5000 至 50000，Mw/Mn 为 2 至 10，主要由 30% 至 70% （以摩尔计）的氟烯烃单元、15% 至 45% （以摩尔计）的乙烯基醚或乙烯基酯单元、1% 至 30% （以摩尔计）的羟基烷基乙烯基醚单元和 4% 至 30% （以摩尔计）的含羧基单元组成，其中羧基用氨或叔胺中和的量为 30% 或更多。这种共聚物可以形成良好的涂膜，不会产生水斑和露点，并具有良好的流平性，同时还能保持氟树脂所具有的优良特性。
• Process for production of unsaturated ether and catalyst used for production of unsaturated ether
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0701986A1

  公开（公告）日：1996-03-20

  A process for producing an unsaturated ether comprises subjecting a glycol ether to intramolecular dehydration in the gas phase in the presence of a catalyst to convert the glycol ether into an unsaturated ether directly in a one-step reaction. As the catalyst, an oxide containing, for example, silicon and an alkali metal is used. The process, which uses no auxiliary raw material, can produce an unsaturated ether (a vinyl ether and/or an allyl ether) simply and safely without generating any waste material derived from the auxiliary raw material.

  一种生产不饱和醚的工艺包括在催化剂存在下，使乙二醇醚在气相中进行分子内脱水，从而在一步反应中直接将乙二醇醚转化为不饱和醚。催化剂是一种含有硅和碱金属的氧化物。该工艺不使用辅助原料，可以简单安全地生产出不饱和醚（乙烯基醚和/或烯丙基醚），而不会产生任何来自辅助原料的废料。
• FLUORINE-ATOM-CONTAINING POLYMERIZABLE UNSATURATED-MONOMER, FLUORINE-ATOM-CONTAINING POLYMERIC COMPOUND AND PHOTORESIST RESIN COMPOSITION
  申请人：Koyama Hiroshi

  公开号：US20050282985A1

  公开（公告）日：2005-12-22

  A fluorine-atom-containing polymerizable unsaturated-monomer of the present invention is represented by the following formula (1a) or (1b): wherein each of a ring Z 1 and a ring Z 2 is an alicyclic carbon ring; when the alicyclic carbon ring is multi-cyclic, a part of atoms constituting the ring may be substituted by an oxygen atom, a sulfur atom or a nitrogen atom; an atom constituting the ring Z 1 and the ring Z 2 may have a substituent; each of R 1 , R 2 and R 3 is an alkyl group or a fluoroalkyl group; R is an specific unsaturated acyl group; provided that at least one of R 1 and R 2 is a fluorine atom or a fluoroalkyl group in the formula (1a), and in the formula (1b) (i) the ring Z 2 is bonded by a fluorine atom or a fluoroalkyl group, or (ii) R 3 is a fluoroalkyl group.

  本发明的含氟原子可聚合不饱和单体由下式(1a)或(1b)表示： 其中每个环 Z 1 和环 Z 2 为脂环碳环；当脂环碳环为多环时，构成环的部分原子可被氧原子、硫原子或氮原子取代；构成环 Z 1 和环 Z 2 中的每个 R 1 , R 2 和 R 3 是烷基或氟烷基； R 是特定的不饱和酰基；条件是 R 1 和 R 2 在式(1a)中至少有一个是氟原子或氟烷基，在式(1b)中 (i) 环 Z 2 由氟原子或氟烷基键合，或 (ii) R 3 是氟烷基。
• US2732370
  申请人：——

  公开号：——

  公开（公告）日：——
• Fluoro ethers and method of preparation
  申请人：AIR REDUCTION

  公开号：US02781405A1

  公开（公告）日：1957-02-12