4-己基环己烷-1-胺 | 46235-08-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4-己基环己烷-1-胺
• 英文名称: 4-hexylcyclohexan-1-amine
• 英文别名: 4-Hexylcyclohexylamin；4-Hexylcyclohexylamine
• CAS: 46235-08-9
• 化学式: C₁₂H₂₅N
• 分子量: 183.337
• InChiKey: FFJNGIHLJPVTBK-UHFFFAOYSA-N

物化性质

• 沸点：
  136-137 °C(Press: 22.6 Torr)
• 密度：
  0.842±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-己基环己烷-1-胺 在 potassium permanganate 作用下， 生成 4-己基环己酮
  参考文献：
  名称：

  Relative molecular mass information from aliphatic nitro compounds: A chemical ionization study

  摘要：

  AbstractThe mass spectra of a number of aliphatic nitro compounds have been studied using electron Ionization (EI) and a variety of chemical Ionization (CI) techniques in attempts to obtain relative molecular mass information. The use of positive ion ammonia chemical Ionization techniques gave very satisfactory results, providing abundant [M + NH4]+ ions, not only from both primary and secondary nitro compounds, but also from the much more labile tertiary nitro compounds. However, the use of methane and isobutane positive ion CI or EI conditions resulted in facile fragmentation with little relative molecular mass information being made available. Negative ion CI using methane, isobutane or ammonia as moderating gases all gave abundant [M − 1]− ions with primary and secondary nitro compounds but at much reduced sensitivity.

  DOI：

  10.1002/oms.1210230102
• 作为产物：
  描述：

  4-己基苯胺 在 palladium on activated charcoal 氢气 作用下， 生成 4-己基环己烷-1-胺
  参考文献：
  名称：

  Relative molecular mass information from aliphatic nitro compounds: A chemical ionization study

  摘要：

  AbstractThe mass spectra of a number of aliphatic nitro compounds have been studied using electron Ionization (EI) and a variety of chemical Ionization (CI) techniques in attempts to obtain relative molecular mass information. The use of positive ion ammonia chemical Ionization techniques gave very satisfactory results, providing abundant [M + NH4]+ ions, not only from both primary and secondary nitro compounds, but also from the much more labile tertiary nitro compounds. However, the use of methane and isobutane positive ion CI or EI conditions resulted in facile fragmentation with little relative molecular mass information being made available. Negative ion CI using methane, isobutane or ammonia as moderating gases all gave abundant [M − 1]− ions with primary and secondary nitro compounds but at much reduced sensitivity.

  DOI：

  10.1002/oms.1210230102

文献信息

• Crystalline polypropylene resin composition and amide compounds
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0557721A2

  公开（公告）日：1993-09-01

  Disclosed are a crystalline polypropylene resin composition comprising a crystalline polyproplylene resin and a β-nucleating agent, and a method of increasing the proportion of β-form crystals in a crystalline polypropylene resin molding comprising molding the composition, the β-nucleating agent being a diamide compound.

  本发明公开了一种结晶聚丙烯树脂组合物，该组合物由结晶聚丙烯树脂和 β 成核剂组成；还公开了一种增加结晶聚丙烯树脂模塑中 β 形晶体比例的方法，该方法包括模塑该组合物，β 成核剂为二酰胺化合物。
• Porous stretched article of polypropylene-based resin and process for its preparation
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0632095A2

  公开（公告）日：1995-01-04

  Disclosed are a process for producing a porous stretched article of β-crystalline polypropylene-based resin, the process comprising the steps of crystallizing a melt of a polypropylene-based resin composition at a temperature of 15 to 140°C to form a solidified product containing β-form crystals and stretching the resulting solidified product at a temprature which is higher than 20 °C but lower than the melting point of the β-form crystals in said solidified product, the polypropylene-based resin composition comprising a polypropylene-based resin and 0.0001 to 5 parts by weight, per 100 parts by weight of the polypropylene-based resin, of at least one specific amide compound; and a porous stretched article produced by the process.

  本发明公开了一种用β-结晶聚丙烯基树脂生产多孔拉伸制品的工艺，该工艺包括以下步骤：在15至140℃的温度下使聚丙烯基树脂组合物的熔体结晶，形成含有β-结晶的固化物，并在高于20℃但低于所述固化物中β-结晶的熔点的温度下拉伸所得固化物，所述聚丙烯基树脂组合物包括聚丙烯基树脂和0.0001至5份（按每100份聚丙烯基树脂的重量计）的至少一种特定酰胺化合物；以及由该工艺生产的多孔拉伸制品。
• PROPYLENE-ETHYLENE COPOLYMER COMPOSITIONS AND PROCESS FOR THE PRODUCTION THEREOF
  申请人：CHISSO CORPORATION

  公开号：EP0790262A1

  公开（公告）日：1997-08-20

  A propylene-ethylene copolymer composition is obtained which has a good moldability and is excellent in the balance of rigidity, toughness, and impact-strength. A propylene-ethylene copolymer composition having a melt flow rate of 10 to 300 g/10 minutes and obtained by producing 60 to 95 % by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D-1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112°C, and a temperature of 112°C or higher, respectively, which is an index of the stereoregurality in molecules and molecular weight distribution, when the amounts of the propylene polymer dissolved therein at each of the temperatures were determined by raising the temperature of the o-dichlorobenzene continuously or stepwise, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40 % by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer produced in the polymerization step (I) to react so that the content of ethylene becomes 30 to 80 % by weight, in a polymerization step (II); and a propylene-ethylene copolymer composition comprising the composition mentioned above and a α-crystal and/or β-crystal nucleator added therewith.

  一种丙烯-乙烯共聚物组合物具有良好的成型性，并且在刚性、韧性和冲击强度的平衡方面表现优异。 一种熔体流动速率为 10 至 300 克/10 分钟的丙烯-乙烯共聚物组合物，通过以下方法获得 以整个聚合物的重量为基准，生产 60% 至 95% 重量百分比的丙烯聚合物，其熔体流动速率（ASTM D-1238）在 100 至 1,000 克/10 分钟范围内，在温度低于 112°C、和 112°C 或更高温度下溶解在邻二氯苯中的丙烯聚合物的综合值之比 (Cf)，这分别是分子立体性和分子量分布的指标，当通过连续或逐步提高邻二氯苯的温度 0.5 或更低，在聚合步骤 (I) 中，在高度立体配位催化剂和氢的存在下进行丙烯聚合，然后 在聚合步骤(II)中，通过向聚合步骤(I)中生成的丙烯聚合物中加入乙烯和丙烯进行反应，使乙烯的含量达到 30% 至 80%（以整个聚合物的重量计），生成 5% 至 40%（以重量计）的乙烯-丙烯共聚物；以及丙烯-乙烯共聚物组合物，该组合物包括上述组合物和加入其中的 α 结晶和/或 β 结晶成核剂。
• PREFOAMED PARTICLES OF POLYPROPYLENE RESIN AND PROCESS FOR PRODUCING THE SAME
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0790275A1

  公开（公告）日：1997-08-20

  Heat temperature at the expansion molding of a finished expanded article is decreased by lowering the melting peak temperature of the pre-expanded particles of a polypropylene resin. Comprising the polypropylene resin and a β-crystalline-nucleating agent, the percentage of the β-form in the whole crystalline region is 5 to 100 parts by weight.

  通过降低聚丙烯树脂预膨化颗粒的熔融峰值温度，可降低成品膨化物膨化成型时的热温度。由聚丙烯树脂和β-结晶成核剂组成，β-形式在整个结晶区域中的百分比为 5 至 100 重量份。
• POROUS POLYPROPYLENE FILM, PROCESS FOR PRODUCING THE SAME, AND ABSORBENT ARTICLE EMPLOYING THE FILM
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1291380A1

  公开（公告）日：2003-03-12

  Disclosed is a porous film made of a resin composition containing (I) (i) a propylene-ethylene copolymer or (ii) a polypropylene-based resin mixture containing a propylene-ethylene copolymer, each having an ethylene content of 3.0 to 7.0 wt.% and an MFR measured at 230°C of 2.0 to 4.0 g/10 min and (II) a β-crystal nucleating agent; the film having a porosity of 20 to 80%, a Gurley air permeability of 5,000 sec/100 cc or lower as measured according to JIS P-8117, a water vapor permeability of 2,000 g/m2·24h or higher as measured according to JIS Z-0208 and a water pressure resistance of 75 kPa or higher as measured according to JIS L-1092 using an aqueous surfactant solution; a process for producing the same; and an absorbent article employing the porous film as a backsheet.

  本发明公开了一种由树脂组合物制成的多孔薄膜，该树脂组合物含有(I)(i)丙烯-乙烯共聚物或(ii)含有丙烯-乙烯共聚物的聚丙烯基树脂混合物，每种树脂的乙烯含量为 3.0 至 7.0 wt.%，在 230°C 时测得的 MFR 为 2.0 至 4.0克/10分钟和(II)β-晶体成核剂；该薄膜的孔隙率为20%至80%，根据JIS P-8117测定的Gurley透气性为5,000秒/100毫升或更低，根据JIS Z-0208测定的水蒸气渗透性为2,000克/平方米-24小时或更高，根据JIS L-1092使用表面活性剂水溶液测定的耐水压性为75千帕或更高；生产该多孔膜的工艺；以及使用该多孔膜作为背膜的吸附制品。