N-(3,4-dimethylphenyl)-N-(4-methoxyphenyl)-3,4-dimethylaniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(3,4-dimethylphenyl)-N-(4-methoxyphenyl)-3,4-dimethylaniline
• 英文别名: bis(3,4-dimethylphenyl)-4-methoxphenyl amine
• 化学式: C₂₃H₂₅NO
• 分子量: 331.458
• InChiKey: ASDZZPONWVFALG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(3,4-dimethylphenyl)-N-(4-methoxyphenyl)-3,4-dimethylaniline 、 五甲基二硅氧烷 在 三(五氟苯基)硼烷 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以95%的产率得到N-(3,4-dimethylphenyl)-N-[4-[dimethyl(trimethylsilyloxy)silyl]oxyphenyl]-3,4-dimethylaniline
  参考文献：
  名称：

  Siloxane−Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers−Rubinsztajn Reaction

  摘要：

  A series of room temperature liquid siloxane triarylamine hybrids were synthesized using the Piers-Rubinsztajn reaction. These materials displayed well behaved electrochemical oxidation and low T(g)'s and were free-flowing liquids. The interaction between the Lewis acidic tris(pentafluorophenyl)borane catalyst and the Lewis basic starting triarylamine substrate was also investigated by steady state UV-vis spectroscopy and (19)F NMR.

  DOI：

  10.1021/ol102607v
• 作为产物：
  描述：

  4-溴苯甲醚 、 双(3,4-二甲苯基)胺 生成 N-(3,4-dimethylphenyl)-N-(4-methoxyphenyl)-3,4-dimethylaniline
  参考文献：
  名称：

  Siloxane−Triarylamine Hybrids: Discrete Room Temperature Liquid Triarylamines via the Piers−Rubinsztajn Reaction

  摘要：

  A series of room temperature liquid siloxane triarylamine hybrids were synthesized using the Piers-Rubinsztajn reaction. These materials displayed well behaved electrochemical oxidation and low T(g)'s and were free-flowing liquids. The interaction between the Lewis acidic tris(pentafluorophenyl)borane catalyst and the Lewis basic starting triarylamine substrate was also investigated by steady state UV-vis spectroscopy and (19)F NMR.

  DOI：

  10.1021/ol102607v

文献信息

• Facile <i>N</i>-Arylation of Amines and Sulfonamides and <i>O</i>-Arylation of Phenols and Arenecarboxylic Acids
  作者：Zhijian Liu、Richard C. Larock

  DOI：10.1021/jo0602221

  日期：2006.4.1

  An efficient, transition-metal-free procedure for the N-arylation of amines, sulfonamides, and carbamates and O-arylation of phenols and carboxylic acids has been achieved by allowing these substrates to react with a variety of o-silylaryl triflates in the presence of CsF. Good to excellent yields of arylated products are obtained under very mild reaction conditions. This chemistry readily tolerates

  通过使这些底物在存在下与多种邻甲硅烷基芳基三氟甲磺酸酯反应，已实现了一种有效的，无过渡金属的胺，磺酰胺和氨基甲酸酯的N-芳基化以及酚和羧酸的O-芳基化方法。的CsF。在非常温和的反应条件下，芳基化产物的收率好至极好。这种化学反应易于耐受各种官能团。
• Photoconductive members
  申请人：Duff McConnell James

  公开号：US20070134572A1

  公开（公告）日：2007-06-14

  A compound comprising a bisbenzamidazoleperinone of the following formula wherein each of R 1 , R 2 , R 3 , and R 4 are the same or different and are independently selected from the group consisting of hydrogen, alkyl, aryl, hydrocarbon, which may be optionally substituted or arranged in such a way as to form a cyclic ring which can be either saturated or unsaturated and halogen.

  一种化合物，包括以下结构的双苯二酰咪唑喹啉，其中R1、R2、R3和R4中的每一个均相同或不同，并且可独立地选择自氢、烷基、芳基、烃基，它们可以是可选择地取代或排列成可以是饱和或不饱和的环，并且卤素。
• Multicyclic benzimidazole derivatives useful as photoconductive members
  申请人：Xerox Corporation

  公开号：EP1795532B1

  公开（公告）日：2009-03-11
• US7473785B2
  申请人：——

  公开号：US7473785B2

  公开（公告）日：2009-01-06